Unusual Structures and Physical Properties in Organometallic Chemistry

Marcel Gielen (Edited by), M Gielen (Author), Rudolph Willem (Edited by), Bernd Wrackmeyer (Edited by)

9780471496359, Wiley

Hardback, published 10 September 2002

446 pages
23.8 x 15.8 x 3.1 cm, 0.765 kg

"...This book is valuable..." (Chemistry & Industry, 17 March 2003)

"...chemists will benefit from this broad survey volume..." (Journal of the American Chemical Society, Vol. 125, No. 25, 2003)

- extreme Bindungssituationen in der Organometallchemie sind interessant, weil sie sich in extremen physikalischen Eigenschaften äußern
- sie sind Testfälle für theoretische Modelle und computerchemische Algorithmen
- der Band enthält Beiträge zu verschiedenen derartigen Verbindungen, insbesondere zu ihrer physikochemischen Charakterisierung (NMR- und Mössbauerspektroskopie).

Contributors.

Series Preface.

Preface.

1. Structure and Electrochemistry of Transition Metal Carbonyl Clusters with Interstitial or Semi-Interstitial Atoms: Contrast between Nitrides or Phosphides and Carbides (Piero Zanello).

2. Unusual Nuclear Magnetic Shielding and Coupling Constants Related to Unusual Bonding Situations (Bernd Wrackmeyer).

3. Deuterium Spin-Lattice Relaxation and Deuterium Quadrupole Coupling Constants. A Novel Strategy for Characterization of Transition Metal Hydrides and Dihydrogen Complexes in Solution (Vladimir I. Bakhmutov).

4. NMR Studies of Ligand Nuclei in Organometallic Compounds--New Information from Solid-State NMR Techniques (Guy M. Bernard and Roderick E. Wasylishen).

5. Metal Atom Motion in Some Iron Organometallics (Rolfe H. Herber).

6. Magnetic Communication in Binuclear Organometallic Complexes Mediated by Carbon-Rich Bridges (Frédéric Paul and Claude Lapinte).

7. Molecular Cluster Complexes with Facial Arene Ligands (Herbert Wadepohl).

8. Cobaltafulvenes and Cobaltapentalenes: Highly Polar Metallacyclic II-Systems with Unusual Properties (Herbert Wadepohl).

9. Novel Highly Nucleophilic Ylidic Ligands for the Preparation of Unusually Stable Metal Complexes (Norbert Kuhn, Martin Göhner, Gernot Frenking and Yu Chen).

10. Supramolecular Interactions in Structures of Organic Antimony and Bismuth Compounds (Gabor Balázs and Hans Joachim Breunig).

Index.

Subject Areas: Chemistry [PN]