Understanding Organic Reaction Mechanisms

First/second year text in chemistry.

Adam Jacobs (Author)

9780521467766, Cambridge University Press

Paperback, published 17 July 1997

324 pages, 546 b/w illus. 70 exercises
24.6 x 18.9 x 1.7 cm, 0.58 kg

' … can be recommended unreservedly … The text impresses one immediately by its special combination of succinctness, pragmatism, and humor'. Henning Hopf, Angewandte Chemie

An understanding of organic reaction mechanisms is an essential part of any undergraduate chemistry course. This book describes the principles that govern chemical reactivity, and shows how these principles can be used to make predictions about the mechanisms and outcomes of chemical reactions. Molecular orbital theory is used to provide up-to-date explanations of chemical reactivity, in an entirely non-mathematical approach suited to organic chemists. A valuable section explains the use of curly arrows, vital for describing reaction mechanisms. A whole chapter is devoted to exploring the thought processes involved in predicting the mechanisms of unfamiliar reactions. Each chapter is followed by a summary of the important points and a selection of problems to help the reader make sure that the material in that chapter has been assimilated. The book concludes with a comprehensive glossary of technical terms. This text will be of valuable for first- and second-year chemistry undergraduates studying organic chemistry.

1. Chemical structure
2. Ionic species
3. Why reactions happen
4. Reactive carbon species
5. The effect of heteroatoms
6. Types of reaction
7. Techniques for investigating mechanisms
8. How to suggest mechanisms
9. Case histories
Glossary
Answers to problems
Index.

Subject Areas: Organic chemistry [PNN]