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Ultra-High Temperature Ceramics
Materials for Extreme Environment Applications
William G. Fahrenholtz (Edited by), W Fahrenholtz (Author), Eric J. Wuchina (Edited by), William E. Lee (Edited by), Yanchun Zhou (Edited by)
9781118700785, Wiley
Hardback, published 23 December 2014
464 pages
24.3 x 16.3 x 2.9 cm, 0.735 kg
The first comprehensive book to focus on ultra-high temperature ceramic materials in more than 20 years Ultra-High Temperature Ceramics are a family of compounds that display an unusual combination of properties, including extremely high melting temperatures (>3000°C), high hardness, and good chemical stability and strength at high temperatures. Typical UHTC materials are the carbides, nitrides, and borides of transition metals, but the Group IV compounds (Ti, Zr, Hf) plus TaC are generally considered to be the main focus of research due to the superior melting temperatures and stable high-melting temperature oxide that forms in situ. Rather than focusing on the latest scientific results, Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications broadly and critically combines the historical aspects and the state-of-the-art on the processing, densification, properties, and performance of boride and carbide ceramics. In reviewing the historic studies and recent progress in the field, Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications provides: Contributions are based on presentations by leading research groups at the conference "Ultra-High Temperature Ceramics: Materials for Extreme Environment Applications II" held May 13-19, 2012 in Hernstein, Austria. Bringing together disparate researchers from academia, government, and industry in a singular forum, the meeting cultivated didactic discussions and efforts between bench researchers, designers and engineers in assaying results in a broader context and moving the technology forward toward near- and long-term use. This book is useful for furnace manufacturers, aerospace manufacturers that may be pursuing hypersonic technology, researchers studying any aspect of boride and carbide ceramics, and practitioners of high-temperature structural ceramics.
Acknowledgments ix Contributors List xi 1 Introduction 1 2 A Historical Perspective on Research Related to Ultra-High Temperature Ceramics 6 3 Reactive Processes for Diboride-Based Ultra-High Temperature Ceramics 33 4 First-Principles Investigation on the Chemical Bonding and Intrinsic Elastic Properties of Transition Metal Diborides TMB2 (TM=Zr, Hf, Nb, Ta, and Y) 60 5 Near-Net-Shaping of Ultra-High Temperature Ceramics 83 6 Sintering and Densification MECHANISMS of Ultra-High Temperature Ceramics 112 7 U HTC Composites for Hypersonic Applications 144 8 Mechanical Properties of Zirconium-Diboride Based UHTCs 167 9 Thermal Conductivity of ZrB2 and HfB2 197 10 Deformation and Hardness of UHTCs as a Function of Temperature 236 11 Modeling and Evaluating the Environmental Degradation of UHTCs under Hypersonic Flow 267 12 Tantalum Carbides: Their Microstructures and Deformation Behavior 291 13 Titanium Diboride 316 14 Th e Group IV Carbides and Nitrides 361 15 Nuclear Applications for Ultra-High Temperature Ceramics and MAX Phases 391 Index 437
William G. Fahrenholtz, Eric J. Wuchina, William E. Lee, and Yanchun Zhou
William G. Fahrenholtz
Guo-Jun Zhang, Hai-Tao Liu, Wen-Wen Wu, Ji Zou, De-Wei Ni, Wei-Ming Guo, Ji-Xuan Liu, and Xin-Gang Wang
Yanchun Zhou, Jiemin Wang, Zhen Li, Xun Zhan, and Jingyang Wang
Carolina Tallon and George V. Franks
Diletta Sciti, Laura Silvestroni, Valentina Medri, and Frédéric Monteverde
Anish Paul, Jon Binner, and Bala Vaidhyanathan
Eric W. Neuman and Greg E. Hilmas
Gregory J. K. Harrington and Greg E. Hilmas
J. Wang and L. J. Vandeperre
Triplicane A. Parthasarathy, Michael K. Cinibulk and Mark Opeka
Gregory B. Thompson and Christopher R. Weinberger
Brahma Raju Golla, Twisampati Bhandari, Amartya Mukhopadhyay, and Bikramjit Basu
Eric J. Wuchina and Mark Opeka
William E. Lee, Edoardo Giorgi, Robert Harrison, Alexandre Maître, and Olivier Rapaud
16 UHTC-Based Hot Structures: Characterization, Design, and On-Ground/In-Flight Testing 416
Davide Alfano, Roberto Gardi, Luigi Scatteia, and Antonio Del Vecchio
Subject Areas: Mechanical engineering & materials [TG]
