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Two-Dimensional Correlation Spectroscopy
Applications in Vibrational and Optical Spectroscopy
Isao Noda (Author), Yukihiro Ozaki (Author)
9780471623915, Wiley
Hardback, published 17 September 2004
312 pages
24.1 x 16 x 2.2 cm, 0.567 kg
A valuable tool for individuals using correlation spectroscopy and those that want to start using this technique. Noda is known as the founder of this technique, and together with Ozaki, they are the two biggest names in the area
* First book on 2D vibrational and optical spectroscopy - single source of information, pulling together literature papers and reveiws
* Growing number of applications of this methodology - book now needed for people thinking of using this technique
* Limitations and benefits discussed and comparisons made with 2D NMR
* Discusses 20 optical and vibrational spectroscopy (IR, Raman, UV, Visible)
Preface xi 1 Introduction 1 2 Principle of Two-dimensional Correlation Spectroscopy 15 3 Practical Computation of Two-dimensional Correlation Spectra 39 4 Generalized Two-dimensional Correlation Spectroscopy in Practice 47 5 Further Expansion of Generalized Two-dimensional Correlation Spectroscopy – Sample–Sample Correlation and Hybrid Correlation 65 6 Additional Developments in Two-dimensional Correlation Spectroscopy – Statistical Treatments, Global Phase Maps, and Chemometrics 77 7 Other Types of Two-dimensional Spectroscopy 95 8 Dynamic Two-dimensional Correlation Spectroscopy Based on Periodic Perturbations 115 8.1 Dynamic 2D IR Spectroscopy 115 9 Applications of Two-dimensional Correlation Spectroscopy to Basic Molecules 169 10 Generalized Two-dimensional Correlation Studies of Polymers and Liquid Crystals 187 11 Two-dimensional Correlation Spectroscopy and Chemical Reactions 217 12 Protein Research by Two-dimensional Correlation Spectroscopy 231 13 Applications of Two-dimensional Correlation Spectroscopy to Biological and Biomedical Sciences 245 14 Application of Heterospectral Correlation Analysis 257 15 Extension of Two-dimensional Correlation Analysis to Other Fields 271 Index 291
Acknowledgements xiii
1.1 Two-dimensional Spectroscopy 1
1.2 Overview of the Field 3
1.3 Generalized Two-dimensional Correlation 6
1.4 Heterospectral Correlation 9
1.5 Universal Applicability 10
2.1 Two-dimensional Correlation Spectroscopy 15
2.2 Generalized Two-dimensional Correlation 17
2.3 Properties of 2D Correlation Spectra 20
2.4 Analytical Expressions for Certain 2D Spectra 24
2.5 Cross-correlation Analysis and 2D Spectroscopy 31
3.1 Computation of 2D Spectra from Discrete Data 39
3.2 Unevenly Spaced Data 41
3.3 Disrelation Spectrum 43
3.4 Computational Efficiency 43
4.1 Practical Example 47
4.2 Pretreatment of Data 52
4.3 Features Arising from Factors other than Band Intensity Changes 56
5.1 Sample–Sample Correlation Spectroscopy 65
5.2 Hybrid 2D Correlation Spectroscopy 72
5.3 Additional Remarks 74
6.1 Classical Statistical Treatments and 2D Spectroscopy 77
6.2 Global 2D Phase Maps 81
6.3 Chemometrics and 2D Correlation Spectroscopy 86
7.1 Nonlinear Optical 2D Spectroscopy 96
7.2 Statistical 2D Correlation Spectroscopy 99
7.3 Other Developments in 2D Correlation Spectroscopy 110
8.2 Dynamic 2D IR Dichroism Spectra of Polymers 121
8.3 Repetitive Perturbations Beyond DIRLD 153
9.1 2D IR Study of the Dissociation of Hydrogen-bonded N-Methylacetamide 170
9.2 2D NIR Sample–Sample Correlation Study of Phase Transitions of Oleic Acid 174
9.3 2D NIR Correlation Spectroscopy Study of Water 176
9.4 2D Fluorescence Study of Polynuclear Aromatic Hydrocarbons 179
10.1 Temperature and Pressure Effects on Polyethylene 187
10.2 Reorientation of Nematic Liquid Crystals by an Electric Field 195
10.3 Temperature-dependent 2D NIR of Amorphous Polyamide 199
10.4 Composition-based 2D Raman Study of EVA Copolymers 203
10.5 Polarization Angle-dependent 2D IR Study of Ferroelectric Liquid Crystals 209
11.1 2D ATR/IR Study of Bis(hydroxyethyl terephthalate) Oligomerization 217
11.2 Hydrogen–Deuterium Exchange of Human Serum Albumin 222
12.1 Adsorption and Concentration-dependent 2D ATR/IR Study of β-Lactoglobulin 232
12.2 pH-dependent 2D ATR/IR Study of Human Serum Albumin 236
12.3 Aggregation of Lipid-bound Cytochrome c 241
13.1 2D NIR Study of Milk 246
13.2 2D IR Study of Synthetic and Biological Apatites 251
13.3 Identification and Quality Control of Traditional Chinese Medicines 253
14.1 Correlation between different Spectral Measurements 257
14.2 SAXS/IR Dichroism Correlation Study of Block Copolymer 258
14.3 Raman/NIR Correlation Study of Partially Miscible Blends 260
14.4 ATR/IR–NIR Correlation Study of BIS(hydroxyethyl terephthalate) Oligomerization 262
14.5 XAS/Raman Correlation Study of Electrochemical Reaction of Lithium with CoO 264
15.1 Applications of 2D Correlation beyond Optical Spectroscopy 271
15.2 2D Correlation Gel Permeation Chromatography (GPC) 271
15.3 2D Mass Spectrometry 281
15.4 Other Unusual Applications of 2D Correlation Analysis 282
15.5 Return to 2D NMR Spectroscopy 283
15.6 Future Developments 288
Subject Areas: Chemistry [PN]
