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The Mizoroki-Heck Reaction
Martin Oestreich (Edited by), M Oestreich (Author)
9780470033944, Wiley
Hardback, published 20 February 2009
608 pages
24.4 x 16.8 x 3.8 cm, 1.162 kg
"It is by far the most authoritative book in this area written to date and has employed many of the major contributors in the area over recent years to provide chapters, resulting in good...coverage of the literature." (Applied Organimetallic Chemistry , March 2010) "This book is a welcome addition to the subject and provides almost all the areas you would want to be covered." (Organic Process Research & Development Journal, 2010) "The selection and clear arrangement of the competently written chapters of this book is well done, giving a rapid general overview of current knowledge about various aspects of this important reaction." (Angewandte Chemie December 2009)
“I am convinced that this book will rapidly become the most important reference text for research chemists in academia and industry who seek orientation in the rapidly growing and – for the layman – confusing field described as the “’Mizoroki–Heck reaction’.” (Synthesis, March 2010)
Exploring the importance of Richard F. Heck’s carbon coupling reaction, this book highlights the subject of the 2010 Nobel Prize in Chemistry for palladium-catalyzed cross couplings in organic synthesis, and includes a foreword from Nobel Prize winner Richard F. Heck. The Mizoroki-Heck reaction is a palladium-catalyzed carbon–carbon bond forming process which is widely used in organic and organometallic synthesis. It has seen increasing use in the past decade as chemists look for strategies enabling the controlled construction of complex carbon skeletons. The Mizoroki-Heck Reaction is the first dedicated volume on this important reaction, including topics on: Several chapters are devoted to asymmetric Heck reactions with particular focus on the construction of otherwise difficult-to-obtain sterically congested tertiary and quaternary carbons. Industrial and academic applications are highlighted in the final section. The Mizoroki-Heck Reaction will find a place on the bookshelves of any organic or organometallic chemist. “I am convinced that this book will rapidly become the most important reference text for research chemists in academia and industry who seek orientation in the rapidly growing and – for the layman – confusing field described as the “’Mizoroki–Heck reaction’.” (Synthesis, March 2010)
Foreword by Professor Richard F. Heck 1 Mechanisms of the Mizoroki–Heck Reaction Anny Jutand 2 Focus on Catalyst Development and Ligand Design Irina P. Beletskaya and Andrei V. Cheprakov 3 Focus on Regioselectivity and Product Outcome in Organic Synthesis Peter Nilsson, Kristofer Olofsson and Mats Larhed 4 Waste-Minimized Mizoroki–Heck Reactions Lukas Gooßen and Käthe Gooßen 5 Formation of Carbocycles Axel B. Machotta and Martin Oestreich 6 Formation of Heterocycles Thierry Muller and Stefan Bräse 7 Chelation-Controlled Mizoroki–Heck Reactions Kenichiro Itami and Jun-ichi Yoshida 8 The Mizoroki–Heck Reaction in Domino Processes Lutz F. Tietze and Laura M. Levy 9 Oxidative Heck-Type Reactions (Fujiwara–Moritani Reactions) Eric M. Ferreira, Haiming Zhang and Brian M. Stoltz 10 Mizoroki–Heck Reactions with Metals Other than Palladium Lutz Ackermann and Robert Born 11 Ligand Design for Intermolecular Asymmetric Mizoroki–Heck Reactions Anthony G. Coyne, Martin O. Fitzpatrick and Patrick J. Guiry 12 Intramolecular Enantioselective Mizoroki–Heck Reactions James T. Link and Carol K. Wada 13 Desymmetrizing Heck Reactions Masakatsu Shibasaki and Takashi Ohshima 14 Combinatorial and Solid-Phase Syntheses Thierry Muller and Stefan Bräse 15 Mizoroki–Heck Reactions: Modern Solvent Systems and Reaction Techniques Werner Bonrath, Ulla L´etinois, Thomas Netscher and Jan Schütz 16 The Asymmetric Intramolecular Mizoroki–Heck Reaction in Natural Product Total Synthesis Amy B. Dounay and Larry E. Overman
Subject Areas: Chemistry [PN]
