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Solution Thermodynamics and Its Application to Aqueous Solutions
A Differential Approach
Introduces a differential approach to solution thermodynamics and uses it to study aqueous solutions, including updates from research findings of the last several years
Yoshikata Koga (Author)
9780444636294
Paperback / softback, published 28 March 2017
444 pages
22.9 x 15.1 x 2.8 cm, 0.72 kg
Solution Thermodynamics and its Application to Aqueous Solutions: A Differential Approach, Second Edition introduces a differential approach to solution thermodynamics, applying it to the study of aqueous solutions. This valuable approach reveals the molecular processes in solutions in greater depth than that gained by spectroscopic and other methods. The book clarifies what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. By applying the same methodology to ions that have been ranked by the Hofmeister series, the author shows that the kosmotropes are either hydrophobes or hydration centers, and that chaotropes are hydrophiles. This unique approach and important updates make the new edition a must-have reference for those active in solution chemistry.
Part A: A Differential Approach in Solution ThermodynamicsI: Basics of Thermodynamics - Derivatives of Gibbs Energy, GII: Solution Thermodynamics - Use of the Second and Third Derivatives of GIII: Determination of the Second and Third Derivatives of GIV: Fluctuation and Partial Molar Fluctuation - Understanding H2O Part B: Studies of Aqueous Solutions Using the Second, the Third, and the Fourth Derivatives of GV: Mixing Schemes in Aqueous Mono-olsVI: Mixing Schemes in Aqueous Solutions of NonelectrolytesVII: Effects of Nonelectrolytes on the Molecular Organization of H2O - 1-Propanol (1P) Probing MethodologyVIII: Effects of Ions on the Molecular Organization of H2O - 1-Propanol (1P)-Probing MethodologyIX: Interactions in Ternary Aqueous Solutions - General TreatmentX: Differential Approach Applied to Spectroscopic Studies on Aqueous SolutionsXI: The Koga Line - Boundary Between Environmentally Friendly and Hostile Water and Aqueous SolutionsXII: In Closing - Executive Summary of the Effect of Solute on H2O
Subject Areas: Chemical engineering [TDCB], Thermochemistry & chemical thermodynamics [PNRW], Physical chemistry [PNR], Thermodynamics & heat [PHH]
