Palladacycles
Catalysis and Beyond

A comprehensive overview of recent research and application of palladacycles in catalysis for cross-coupling and similar reactions.

Anant Kapdi (Edited by), Debabrata Maiti (Edited by)

9780128155059, Elsevier Science

Paperback, published 15 June 2019

420 pages
22.9 x 15.1 x 2.7 cm, 0.59 kg

Palladacycles: Catalysis and Beyond provides an overview of recent research in palladacycles in catalysis for cross-coupling and similar reactions. In the quest for developing highly efficient and robust palladium-based catalysts for C-C bond formation via cross-coupling reactions, palladacycles have played a significant role. In recent years, they have found a wide variety of applications, ranging from catalysts for cross-coupling and related reactions, to their more recent application as anticancer agents. This book explores early examples of the use of palladacyclic complexes in catalysis employing azobenzene and hydrazobenzene as coordinating ligands. Its applications in processes such as selective reduction of alkenes, alkynes, or nitroalkanes are also covered.

1. Palladacycles as Efficient Precatalysts for Suzuki-Miyaura Cross-Coupling Reaction 2. Palladacycles as Precatalysts for Heck and Sonogashira Cross-Coupling Reactions 3. Palladacycles as Efficient Precatalysts for Negishi and Buchwald-Hartwig Amination Reactions 4. Introduction of Water-Solubility in Palladacycles and their Catalytic Applications 5. Palladacyclic Complexes as Efficient Catalysts for CdH Bond Functionalization Reactions 6. Multicomponent Reaction Sequences Using Palladacyclic Complexes 7. Enantioselective Synthesis Using Chiral Palladacycles 9. Nanoparticular or Colloidal Pathways for Palladacycles-Mediated Catalytic Processes 10. Miscellaneous Applications of Palladacycles

Subject Areas: Metals technology / metallurgy [TDM], Inorganic chemistry [PNK]