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Organic Reactions, Volume 100
Scott E. Denmark (Editor-in-chief), SE Denmark (Author)
9781119456667, Wiley
Hardback, published 2 January 2020
1136 pages
23.1 x 15.5 x 4.6 cm, 1.406 kg
Written by a "who is who" of leading organic chemists, this anniversary volume represent the Organic Reactions editors' choice of the most important, ground-breaking and versatile reactions in current organic synthesis. The 15 reaction types selected for this volume include reactions for carbon-carbon bond formation, cross-coupling reactions, hydro- and halofunctionalizations, among many others.
In line with the successful recipe of the series, each chapter is focused on a single reaction, discussing its mechanism and stereochemistry, scope and limitations, applications to synthesis, comparison with other methods, and experimental procedures. Each chapter concludes with a tabular survey of selected key application examples, complete with reported reaction conditions and yields, to serve as a quick reference guide for synthesis planning.
1. The Negishi Cross-Coupling Reaction 1 2. Generation and Trapping of Functionalized Aryl- and Heteroarylmagnesium and -Zinc Compounds 63 3. Copper-Catalyzed, Enantioselective Hydrofunctionalization of Alkenes 121 4. The Catalytic, Enantioselective Favorskii Reaction: in Situ Formation of Metal Alkynylides and Their Additions to Aldehydes 207 5. Enantioselective Lithiation–Substitution of Nitrogen-Containing Heterocycles 255 6. Catalytic, Enantioselective, Transfer Hydrogenation 329 7. Hydrofunctionalization of Alkenes by Hydrogen-Atom Transfer 383 8. Carbon–Carbon Bond Formation by Metallaphotoredox Catalysis 471 9. Suzuki–Miyaura Cross-Coupling 547 10. ortho-Directed C–H Alkylation of Substituted Benzenes 621 11. Catalytic, Enantioselective, C–H Functionalization to Form Carbon–Carbon Bonds 671 12. Catalytic, Enantioselective Fluorination Reactions 749 13. Catalyst-Controlled Glycosylation 801 14. Palladium-Catalyzed Amination of Aryl Halides 853 15. Catalytic, Enantioselective, Copper–Boryl Additions to Alkenes 959 Cumulative Chapter Titles by Volume 1057 Author Index, Volumes 1–100 1075 Chapter and Topic Index, Volumes 1–100 1083
Colin Diner and Michael G. Organ
Ferdinand H. Lutter, Maximilian S. Hofmayer, Jeffrey M. Hammann, Vladimir Malakhov, and Paul Knochel
Haoxuan Wang and Stephen L. Buchwald
Yeshua Sempere and Erick M. Carreira
Kevin Kasten, Nico Seling, and Peter O’Brien
Masahiro Yoshimura and Masato Kitamura
Ryan A. Shenvi, Jeishla L. M. Matos, and Samantha A. Green
Eric D. Nacsa and David W. C. MacMillan
Alexander B. Pagett and Guy C. Lloyd-Jones
Yusuke Ano and Naoto Chatani
Qing-Feng Wu, Gang Chen, Jian He, and Jin-Quan Yu
Richard T. Thornbury and F. Dean Toste
Samuel M. Levi and Eric N. Jacobsen
John F. Hartwig, Kevin H. Shaughnessy, Shashank Shekhar, and Rebecca A. Green
Amir H. Hoveyda, Ming Joo Koh, Kyunga Lee, and Jaehee Lee
Subject Areas: Chemistry [PN]
