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NMR of Quadrupolar Nuclei in Solid Materials
Roderick E. Wasylishen (Author), Sharon E. Ashbrook (Author), Stephen Wimperis (Author)
9780470973981, Wiley
Hardback, published 15 June 2012
560 pages
25.4 x 19.6 x 2.8 cm, 1.356 kg
NMR OF QUADRUPOLAR NUCLEI IN SOLID MATERIALS Over the past 20 years technical developments in superconducting magnet technology and instrumentation have increased the potential of NMR spectroscopy so that it is now possible to study a wide range of solid materials. In addition, one can probe the nuclear environments of many other additional atoms that possess the property of spin. In particular, it is possible to carry out NMR experiments on isotopes that have nuclear spin greater that ½ (i.e. quadrupolar nuclei). Since more that two-thirds of all NMR active isotopes are quadrupolar nuclei, applications of NMR spectroscopy with quadrupolar nuclei are increasing rapidly. The purpose of this handbook is to provide under a single cover the fundamental principles, techniques and applications of quadrupolar NMR as it pertains to solid materials. Each chapter has been prepared by an expert who has made significant contributions to out understanding and appreciation of the importance of NMR studies of quadrupolar nuclei in solids. The text is divided into three sections: The first provides the reader with the background necessary to appreciate the challenges in acquiring and interpreting NMR spectra of quadrupolar neclei in solids. The second presents cutting-edge techniques and methodology for employing these techniques to investigate quadrupolar nuclei in solids. The final section explores applications of solid-state NMR studies of solids ranging from investigations of dynamics, characterizations of biological samples, organic and inorganic materials, porous materials, glasses, catalysts, semiconductors and high-temperature superconductors. About EMR Handbooks The Encyclopedia of Magnetic Resonance (EMR) publishes a wide range of online articles on all aspects of magnetic resonance in physics, chemistry, biology and medicine. The existence-of this large number of articles, written by experts in various fields, is enabling the publication of a series of EMR Handbooks on specific areas of NMR and MRI. The chapters of each of these handbooks will comprise a carefully chosen selection of Encyclopedia articles. In consultation with the EMR Editorial Board, the EMR Handbooks are coherently planned in advance by specially-selected Editors, and new articles, are written (together with updates of some already existing articles) to give appropriate complete coverage. The handbooks are intended to be of value and interest to research students, postdoctoral fellows and other researchers learning about the scientific area in question and undertaking relevant experiments, whether in academia or industry. Have the content of this handbook and the complete content of the Encyclopedia of Magnetic Resonance at your fingertips! Visit: www.wileyonlinelibrary.com/ref/emr
Contributors ix Series Preface xiii Volume Preface xv Part A: Basic Principles 1 1 Quadrupolar Interactions 2 Quadrupolar Nuclei in Solids 3 Quadrupolar Coupling: An Introduction and Crystallographic Aspects 4 Quadrupolar Nuclei in Solids: Influence of Different Interactions on Spectra Part B: Advanced Techniques 75 5 Acquisition of Wideline Solid-State NMR Spectra of Quadrupolar Nuclei 6 Sensitivity and Resolution Enhancement of Half-Integer Quadrupolar Nuclei in Solid-State NMR 7 Quadrupolar Nutation Spectroscopy 8 Dynamic Angle Spinning 9 Double Rotation (DOR) NMR 10 MQMAS NMR: Experimental Strategies 11 STMAS NMR: Experimental Advances 12 Correlation Experiments Involving Half-Integer Quadrupolar Nuclei 13 Computing Electric Field Gradient Tensors Part C: Applications 211 14 Quadrupolar NMR to Investigate Dynamics in Solid Materials 15 Alkali Metal NMR of Biological Molecules 16 Nitrogen-14 NMR Studies of Biological Systems 17 Oxygen-17 NMR Studies of Organic and Biological Molecules 18 Oxygen-17 NMR of Inorganic Materials 19 Chlorine, Bromine, and Iodine Solid-State NMR 20 Quadrupolar NMR of Ionic Conductors, Batteries, and other Energy-Related Materials 21 Quadrupolar NMR of Nanoporous Materials 22 Quadrupolar NMR in the Earth Sciences 23 Quadrupolar NMR of Superconductors 24 Quadrupolar NMR of Semiconductors 25 Quadrupolar NMR of Metal Nuclides in Biological Materials 26 Nuclear Waste Glasses: Insights from Solid-State NMR 27 Quadrupolar Metal NMR of Oxide Materials Including Catalysts 28 Quadrupolar NMR of Intermetallic Compounds Index 511
Pascal P. Man 3
Alexander J. Vega 17
Sharon E. Ashbrook, Stephen Wimperis 45
David L. Bryce, Roderick E. Wasylishen 63
Robert W. Schurko 77
Thomas T. Nakashima, Roderick E. Wasylishen 95
Arno P.M. Kentgens 107
Philip J. Grandinetti 121
Ray Dupree 133
Jean-Paul Amoureux, Marek Pruski 143
Sharon E. Ashbrook, Stephen Wimperis 163
Michael Deschamps, Dominique Massiot 179
Josef W. Zwanziger 199
Luke A. O’Dell, Christopher I. Ratcliffe 213
Gang Wu 233
Luminita Duma 255
Gang Wu 273
Sharon E. Ashbrook, Mark E. Smith 291
David L. Bryce, Cory M. Widdifield, Rebecca P. Chapman, Robert J. Attrell 321
Frédéric Blanc, Leigh Spencer, Gillian R. Goward 349
Mohamed Haouas, Charlotte Martineau, Francis Taulelle 371
Jonathan F. Stebbins 387
Nicholas J. Curro 401
James P. Yesinowski 417
Tatyana Polenova, Andrew S. Lipton, Paul D. Ellis 439
Scott Kroeker 453
Olga B. Lapina, Victor V. Terskikh 467
Frank Haarmann 495
Subject Areas: Chemistry [PN]
