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Catalytic Methods in Asymmetric Synthesis
Advanced Materials, Techniques, and Applications
Michelangelo Gruttadauria (Edited by), M Gruttadauria (Author), Francesco Giacalone (Edited by)
9780470641361, Wiley
Hardback, published 28 October 2011
720 pages, Drawings: 0 B&W, 0 Color
24.4 x 16.5 x 4.1 cm, 1.143 kg
This book covers advances in the methods of catalytic asymmetric synthesis and their applications. Coverage moves from new materials and technologies to homogeneous metal-free catalysts and homogeneous metal catalysts. The applications of several methodologies for the synthesis of biologically active molecules are discussed. Part I addresses recent advances in new materials and technologies such as supported catalysts, supports, self-supported catalysts, chiral ionic liquids, supercritical fluids, flow reactors and microwaves related to asymmetric catalysis. Part II covers advances and milestones in organocatalytic, enzymatic and metal-based mediated asymmetric synthesis, including applications for the synthesis of biologically active molecules. Written by leading international experts, this book consists of 16 chapters with 2000 References and illustrations of 560 schemes and figures.
PREFACE xi FOREWORD xiii CONTRIBUTORS xv I NEW MATERIALS AND TECHNOLOGIES: SUPPORTED CATALYSTS, SUPPORTS, SELFSUPPORTED CATALYSTS, CHIRAL IONIC LIQUID, SUPERCRITICAL FLUIDS, FLOW REACTORS, AND MICROWAVES 1 1 RECYCLABLE STEREOSELECTIVE CATALYSTS 3 2 RECYCLABLE ORGANOCATALYSTS IN ASYMMETRIC REACTIONS 83 3 SYNTHESIS AND CHARACTERIZATION OF SUPPORTED CHIRAL CATALYSTS 177 4 SYNTHESIS OF CHIRAL CATALYSTS SUPPORTED ON ORGANIC POLYMERS 209 5 SELF-SUPPORTED CHIRAL CATALYSTS 257 6 CATALYSIS WITH CHIRALLY MODIFIED METAL SURFACES: SCOPE AND MECHANISMS 291 7 CHIRAL IONIC LIQUIDS FOR ASYMMETRIC REACTIONS 323 8 ASYMMETRIC REACTIONS IN FLOW REACTORS 345 9 ASYMMETRIC CATALYTIC SYNTHESIS IN SUPERCRITICAL FLUIDS 373 10 MICROWAVE-ASSISTED TRANSITION METAL-CATALYZED ASYMMETRIC SYNTHESIS 391 II RECENT ADVANCES IN ORGANOCATALYTIC, ENZYMATIC, AND METAL-BASED MEDIATED ASYMMETRIC SYNTHESIS 413 11 RECENT ADVANCES ON STEREOSELECTIVE ORGANOCATALYTIC REACTIONS. ORGANOCATALYTIC SYNTHESIS OF NATURAL PRODUCTS AND DRUGS 415 12 RECENT ADVANCES IN BIOCATALYSIS APPLIED TO ORGANIC SYNTHESIS 491 13 PEPTIDES FOR ASYMMETRIC CATALYSIS 529 14 SILICATE-MEDIATED STEREOSELECTIVE REACTIONS CATALYZED BY CHIRAL LEWIS BASES 579 15 RECENT ADVANCES IN THE METAL-CATALYZED STEREOSELECTIVE SYNTHESIS OF BIOLOGICALLY ACTIVE MOLECULES 625 16 STEREOSELECTIVE NITROGEN HETEROCYCLE SYNTHESIS MEDIATED BY CHIRAL METAL CATALYSTS 671 INDEX 689
Carlos M. Monteiro, Alexandre F. Trindade, Pedro M. P. Gois, and Carlos A. M. Afonso
Michelangelo Gruttadauria, Francesco Giacalone, and Renato Noto
Carmela Aprile, Hermenegildo Garcia, and Paolo P. Pescarmona
Tor Erik Kristensen and Tore Hansen
Hongchao Guo and Kuiling Ding
Angelo Vargas, Cecilia Mondelli, and Alfons Baiker
Annie-Claude Gaumont, Yves Génisson, Frédéric Guillen, Viacheslav Zgonnik, and Jean-Christophe Plaquevent
Munawwer Rasheed, Simon C. Elmore, and Thomas Wirth
Tomoko Matsuda
Luke R. Odell and Mats Larhed
Monika Raj and Vinod K. Singh
Gonzalo De Gonzalo, Iván Lavandera, and Vicente Gotor
Matthias Freund and Svetlana B. Tsogoeva
Maurizio Benaglia, Stefania Guizzetti, and Sergio Rossi
Catalina Ferrer, Xavier Verdaguer, and Antoni Riera
Sherry R. Chemler
Subject Areas: Chemistry [PN]
