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Atomically Precise Nanochemistry
Rongchao Jin (Edited by), R Jin (Author), De-en Jiang (Edited by)
9781119788645, Wiley
Hardback, published 27 April 2023
528 pages
24.4 x 17 x 3 cm, 1.191 kg
Atomically Precise Nanochemistry Explore recent progress and developments in atomically precise nanochemistry Chemists have long been motivated to create atomically precise nanoclusters, not only for addressing some fundamental issues that were not possible to tackle with imprecise nanoparticles, but also to provide new opportunities for applications such as catalysis, optics, and biomedicine. In Atomically Precise Nanochemistry, a team of distinguished researchers delivers a state-of-the-art reference for researchers and industry professionals working in the fields of nanoscience and cluster science, in disciplines ranging from chemistry to physics, biology, materials science, and engineering. A variety of different nanoclusters are covered, including metal nanoclusters, semiconductor nanoclusters, metal-oxo systems, large-sized organometallic nano-architectures, carbon clusters, and supramolecular architectures. The book contains not only experimental contributions, but also theoretical insights into the atomic and electronic structures, as well as the catalytic mechanisms. The authors explore synthesis, structure, geometry, bonding, and applications of each type of nanocluster. Perfect for researchers working in nanoscience, nanotechnology, and materials chemistry, Atomically Precise Nanochemistry will also benefit industry professionals in these sectors seeking a practical and up-to-date resource.
List of Contributors xiii 1 Introduction to Atomically Precise Nanochemistry 1 1.1 Why Atomically Precise Nanochemistry? 1 2 Total Synthesis of Thiolate-Protected Noble Metal Nanoclusters 57 2.1 Introduction 57 3 Thiolated Gold Nanoclusters with Well-Defined Compositions and Structures 87 3.1 Introduction 87 4 Structural Design of Thiolate-Protected Gold Nanoclusters 141 4.1 Introduction 141 5 Electrocatalysis on Atomically Precise Metal Nanoclusters 161 5.1 Introduction 161 6 Atomically Precise Metal Nanoclusters as Electrocatalysts: From Experiment to Computational Insights 195 6.1 Introduction 195 7 Ag Nanoclusters: Synthesis, Structure, and Properties 227 7.1 Introduction 227 8 Atomically Precise Copper Nanoclusters: Syntheses, Structures, and Properties 257 8.1 Introduction 257 9 Atomically Precise Nanoclusters of Iron, Cobalt, and Nickel: Why Are They So Rare? 285 9.1 Introduction 285 10 Atomically Precise Heterometallic Rhodium Nanoclusters Stabilized by Carbonyl Ligands 309 10.1 Introduction 309 11 Endohedral Fullerenes: Atomically Precise Doping Inside Nano Carbon Cages 331 11.1 Introduction 331 12 On-Surface Synthesis of Polyacenes and Narrow Band-Gap Graphene Nanoribbons 373 12.1 Introduction 373 13 A Branch of Zintl Chemistry: Metal Clusters of Group 15 Elements 395 13.1 Introduction 395 14 Exploration of Controllable Synthesis and Structural Diversity of Titanium-Oxo Clusters 423 14.1 Introduction 423 15 Atom-Precise Cluster-Assembled Materials: Requirement and Progresses 453 15.1 Introduction 453 16 Coinage Metal Cluster- Assembled Materials 479 16.1 Introduction 479 Acknowledgments 499
Preface xvii
Rongchao Jin
1.2 Types of Nanoclusters Covered in This Book 7
1.3 Some Fundamental Aspects 12
1.4 Some Applications 42
1.5 Concluding Remarks 49
Qiaofeng Yao, Yitao Cao, Tiankai Chen, and Jianping Xie
2.2 Size Engineering of Metal Nanoclusters 58
2.3 Composition Engineering of Metal Nanoclusters 64
2.4 Structure Engineering of Metal Nanoclusters 73
2.5 Top-Down Etching Reaction of Metal Nanoclusters 78
2.6 Conclusion and Outlooks 80
Wanmiao Gu and Zhikun Wu
3.2 Synthesis, Purification, and Characterization of Gold Nanoclusters 88
3.3 Structures of Gold Nanoclusters 95
3.4 Properties and Applications 115
3.5 Conclusion and Future Perspectives 130
Pengye Liu, Wenhua Han, and Wen Wu Xu
4.2 Structural Design Based on "Divide and Protect" Rule 142
4.3 Structural Design via Redistributing the "Staple"; Motifs on the Known Au Core Structures 144
4.4 Structural Design via Structural Evolution 149
4.5 Structural Design via Grand Unified Model 153
4.6 Conclusion and Perspectives 155
Hoeun Seong, Woojun Choi, Yongsung Jo, and Dongil Lee
5.2 Electrochemistry of Atomically Precise Metal Nanoclusters 164
5.3 Electrocatalytic Water Splitting on Atomically Precise Metal Nanoclusters 170
5.4 Electrocatalytic Conversion of CO 2 on Atomically Precise Metal Nanoclusters 178
5.5 Conclusions and Outlook 187
Fang Sun, Qing Tang, and De-en Jiang
6.2 Factors Affecting the Activity and Selectivity of NCs Electrocatalysis 196
6.3 Important Electrocatalytic Applications 205
6.4 Conclusion and Perspectives 219
Manman Zhou and Manzhou Zhu
7.2 Synthetic Methods 228
7.3 Structure of Ag NCs 229
7.4 Properties of Ag NCs 245
7.5 Conclusion and Perspectives 250
Chunwei Dong, Saidkhodzha Nematulloev, Peng Yuan, and Osman M. Bakr
8.2 Syntheses of Copper NCs 258
8.3 Structures of Copper NCs 261
8.4 Properties 270
8.5 Summary Comparison with Gold and Silver NCs 277
8.6 Conclusion and Perspectives 278
Trevor W. Hayton
9.2 General Considerations 287
9.3 Synthesis of Ni APNCs 288
9.4 Synthesis of Co APNCs 294
9.5 Attempted Synthesis of Fe APNCs 297
9.6 Conclusions and Outlook 299
Guido Bussoli, Cristiana Cesari, Cristina Femoni, Maria C. Iapalucci, Silvia Ruggieri, and Stefano Zacchini
10.2 Synthesis of Heterometallic Rhodium Carbonyl Nanoclusters 311
10.3 Electron-Reservoir Behavior of Heterometallic Rhodium Nanoclusters 319
10.4 Conclusions and Perspectives 322
Yang-Rong Yao, Jiawei Qiu, Lihao Zheng, Hongjie Jiang, Yunpeng Xia, and Ning Chen
11.2 Synthesis of Endohedral Metallofullerenes 332
11.3 Fullerene Structures Tuned by Endohedral Doping 334
11.4 Properties Tuned by Endohedral Doping 342
11.5 Chemical Reactivity Tune by Endohedral Doping 358
11.6 Conclusions and Perspectives 362
Hironobu Hayashi and Hiroko Yamada
12.2 Bottom-Up Synthesis of Graphene Nanoribbons 375
12.3 On-Surface Synthesis of Narrow Bandgap Armchair-Type Graphene Nanoribbons 378
12.4 On-Surface Synthesis of Polyacenes as Partial Structure of Zigzag-Type Graphene Nanoribbons 382
12.5 Conclusion and Perspectives 390
Yu-He Xu, Nikolay V. Tkachenko, Alvaro Muñoz-Castro, Alexander I. Boldyrev, and Zhong-Ming Sun
13.2 Complex Coordination Modes in Arsenic Clusters 399
13.3 Antimony Clusters with Aromaticity and Anti-Aromaticity 401
13.4 Recent Advances in Bismuth-Containing Compounds 408
13.5 Ternary Clusters Containing Group 15 Elements 411
13.6 Conclusion and Perspectives 414
Mei-Yan Gao, Lei Zhang, and Jian Zhang
14.2 Coordination Delayed Hydrolysis Strategy 425
14.3 Ti-O Core Diversity 427
14.4 Ligand Diversity 432
14.5 Metal-Doping Diversity 438
14.6 Structural Influence on Properties and Applications 441
14.7 Conclusion and Perspectives 445
Sourav Biswas, Panpan Sun, Xia Xin, Sukhendu Mandal, and Di Sun
15.2 Prospect of Cluster-Assembling Process and Their Classification 454
15.3 Conclusions and Outlook 474
Zhao-Yang Wang and Shuang-Quan Zang
16.2 Structures of Metal Cluster-Assembled Materials 480
16.3 Applications 493
16.4 Conclusion 499
References 499
Index 503
Subject Areas: Chemistry [PN]
