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Advances in Organometallic Chemistry and Catalysis
The Silver / Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book
Armando J. L. Pombeiro (Edited by), AJL Pombeiro (Author)
9781118510148, Wiley
Hardback, published 14 January 2014
736 pages
28.7 x 22.4 x 4.4 cm, 1.923 kg
“The book is written in good scientific English and should be easily understood by a graduate-level scientist who has some familiarity with the topics.” (Applied Organometallic Chemistry, 1 May 2015)
A contemporary compilation of recent achievements in organometallic chemistry The prestigious International Conference on Organometallic Chemistry (ICOMC) was launched in 1963, providing a forum for researchers from around the world to share their findings and explore new paths to advance our knowledge and application of organometallic chemistry. The 25th ICOMC, held in Lisbon in 2012, gathered more than 1,200 participants from 54 countries. This volume celebrates the 25th Silver Edition and the 50th Gold Year of the ICOMC. Featuring contributions from invited 25th ICOMC speakers, Advances in Organometallic Chemistry and Catalysis highlights recent achievements and new and emerging areas of research in the field. Its seven sections cover: Chapters discuss fundamental underlying concepts, offer illustrative examples and cases, and explore future avenues for continued research. Readers will discover basic principles and properties of organometallic compounds, reaction mechanisms, and detailed descriptions of current applications. Collectively, these chapters underscore the versatility, richness, and potential of modern organometallic chemistry, including its interrelationships with other scientific disciplines. All the contributions are extensively referenced, providing a gateway to the most important original research papers and reviews in organometallic chemistry. Presenting a contemporary understanding of organometallic chemistry and its many applications, Advances in Organometallic Chemistry and Catalysis is recommended for all researchers in the field, from students to advanced investigators.
PREFACE xi CONTRIBUTORS xv PART I ACTIVATION AND FUNCTIONALIZATION OF CARBON SINGLE BONDS AND OF SMALL 1 Organometallic Complexes as Catalysts in Oxidation of C—H Compounds 3 2 Toward Functionalization of Alkanes Under Environmentally Benign Conditions 15 3 Self-assembled Multicopper Complexes and Coordination Polymers for Oxidation and Hydrocarboxylation of Alkanes 27 4 Activation of C—O and C—F Bonds by Pincer-iridium Complexes 39 5 Functionalization of sp2 and sp3 Carbon Centers Catalysed by Polyoxometalates and Metalloporphyrins 59 6 Quasi-borinium Cation Based on Cobalt Bis(dicarbollide): Its Lewis Acidity and C—H and C—X Bond Activation 73 7 Transition-metal-promoted Functionalization of Carboranes 81 8 Weak Interactions and M—H Bond Activation 97 PART II ORGANOMETALLIC SYNTHESIS AND CATALYSIS 111 9 Complexes with Protic N-Heterocyclic Carbene (NR,NH-NHC) Ligands 113 10 Cyclopentadienyl-functionalized N-Heterocyclic Carbene Complexes of Iron and Nickel: Catalysts for Reductions 133 11 Palladium-(acyclic diaminocarbene) Species as Alternative to Palladium-(nitrogen heterocyclic carbenes) in Cross-coupling Catalysis 145 12 Synthesis of Metallocenes Via Metathesis in Metal Coordination Spheres 157 13 Metal-mediated [2 + 3] Dipolar Cycloaddition to Substrates with CN Triple Bond: Recent Advances 171 14 Coordination Chemistry of Oxazoline/Thiazoline-based P,N Ligands 185 15 “Click” Copper Catalyzed Azide-alkyne Cycloaddition (CuAAC) in Aqueous Medium 199 16 Organogold Catalysis: Homogeneous Gold-catalyzed Transformations for a Golden Jubilee 207 17 Vanadium(IV) Complexes Derived from Aromatic o-Hydroxyaldehydes and Tyrosine Derivatives: Catalytic Evaluation in Sulfoxidations 227 18 Microwave-assisted Catalytic Oxidation of Alcohols to Carbonyl Compounds 233 19 Oxidation of Glycerol with Hydrogen Peroxide Catalyzed by Metal Complexes 247 20 Involvement of an Acetato Ligand in the Reductive Elimination Step of the Rhodium-catalyzed Methanol Carbonylation 259 21 Half-sandwich Rhodium(III), Iridium(III), and Ruthenium(II) Complexes with Ancillary Pyrazole-based Ligands 269 22 Carbon-scorpionate Complexes in Oxidation Catalysis 285 23 Toward Chemoselective Bioconjugative Desulfitative Catalysis 295 24 Sulfoxide Redox Chemistry with Molybdenum Catalysts 305 25 A New Family of Zirconium Complexes Anchored by Dianionic Cyclam-based Ligands: Syntheses, 26 Metal-organo Multicatalysis: An Emerging Concept 325 PART III ORGANOMETALLIC POLYMERIZATION CATALYSIS 343 27 Coordinative Chain Transfer Polymerisations and Copolymerisations by Means of Rare Earths 28 Charge-neutral and Cationic Complexes of Large Alkaline Earths for Ring-opening Polymerization PART IV ORGANOMETALLIC POLYMERS AND MATERIALS 379 29 Organometallic Polymers 381 30 From Serendipity to Porosity: Synthesis and Reactivity of Coordination Polymers Based on Copper Trinuclear Triangular Motifs 407 31 Organometallic Nanoparticles 421 32 Organometallic Compounds in the Synthesis of New Materials: Old Ligands, New Tricks 437 33 The Role of Organometallic Complexes in the Synthesis of Shaped Carbon Materials 445 34 Metal Catalysis in Fullerene Chemistry 459 35 Organometallic Complexes of Sumanene 473 36 Advances in Luminescent Tetracoordinate Organoboron Compounds 485 37 Mechanochemistry: A Tool in the Synthesis of Catalysts, Metallodrugs, and Metallopharmaceuticals 493 PART V ORGANOMETALLIC CHEMISTRY AND SUSTAINABLE ENERGY 501 38 Organometallic Complexes for Dye-sensitized Solar Cells (DSSC) 503 39 Synthetic Photosynthesis for the Conversion of Large Volumes of Carbon Dioxide into Energy-Rich Molecules: Saving Fossil Fuels by Recycling Carbon 513 40 Ionic Liquids for Hydrogen Storage: Opportunities for Organometallic Chemistry 529 PART VI BIOORGANOMETALLIC CHEMISTRY 543 41 Metal Carbonyls for CO-based Therapies: Challenges and Successes 545 42 The Ferrocifen Family as Potent and Selective Antitumor Compounds: Mechanisms of Action 563 43 On the Track to Cancer Therapy: Paving New Ways With Ruthenium Organometallics 581 44 Organometallic Chemistry of Rhenium and Technetium Fueled by Biomedical Applications 589 45 Metal-based Indolobenzazepines and Indoloquinolines: From Moderate cdk Inhibitors to Potential Antitumor Drugs 605 46 Metal-based Chelates and Nanosystems as MRI Contrast Agents 619 PART VII ORGANOMETALLIC ELECTROCHEMISTRY 631 47 Electrochemistry and Supramolecular Interactions of “Ferrocifen” Anticancer Drugs with Cyclodextrins and Lipid Bilayers: An Electrochemical Overview 633 48 Electrochemistry of Fischer Aminocarbene Complexes: Effects of Structure on Redox Properties, Electron Distribution, and Reaction Mechanisms 653 49 Electron Transfer-induced Coordination Changes in Organometallic Complexes with Non-innocent Hemilabile Ligands 667 50 Redox Potential–Structure Relationships and Parameterization in Characterization and Identification of Organometallic Compounds 677 51 Endohedral Metallofullerenes Today: More and More Versatile Ships in Multiform Bottles—Electrochemistry of X-Ray Characterized Monometallofullerenes 691 POSTSCRIPT: A SHORT HISTORY OF THE ICOMC CONFERENCES 703 INDEX 707
MOLECULES 1
Georgiy B. Shul’pin
Armando J. L. Pombeiro
Alexander M. Kirillov, Marina V. Kirillova, and Armando J. L. Pombeiro
Jason Hackenberg, Karsten Krogh-Jespersen, and Alan S. Goldman
M´ario M. Q. Sim˜oes, Isabel C. M. S. Santos, Maria Gra¸ca P. M. S. Neves, Ana M. V. Cavaleiro, and Jos´e A. S. Cavaleiro
V. I. Bregadze, I. B. Sivaev, I. D. Kosenko, I. A. Lobanova, Z. A. Starikova, and I. A. Godovikov
Zaozao Qiu and Zuowei Xie
Elena Shubina, Natalia Belkova, Oleg Filippov, and Lina Epstein
F. Ekkehardt Hahn
Beatriz Royo
Vadim P. Boyarskiy, Konstantin V. Luzyanin, and Vadim Yu. Kukushkin
Antoni Pietrzykowski and W©©odzimierz Buchowicz
Konstantin V. Luzyanin and Maxim L. Kznetsov
Shuanming Zhang, Roberto Pattacini, and Pierre Braunstein
Joaqu´©¥n Garc´©¥a-A´lvarez and Jose´ Gimeno
Fabien Gagosz
Jo˜ao Costa Pessoa, Isabel Correia, and Pedro Ad˜ao
Yauhen Yu. Karabach, Maximilian N. Kopylovich, Kamran T. Mahmudov, and Armando J. L. Pombeiro
Dalmo Mandelli, Wagner A. Carvalho, Lidia S. Shul’pina, Alexander M. Kirillov, Marina V. Kirillova,
Armando J. L. Pombeiro, and Georgiy B. Shul’pin
Duc Hanh Nguyen, Nicolas Lassauque, Thomas Davin, Laurent Maron, Carole Le Berre, Philippe Serp, and Philippe Kalck
Claudio Pettinari, Riccardo Pettinari, Corrado Di Nicola, and Fabio Marchetti
Lu´©¥sa M. D. R. S. Martins and Armando J. L. Pombeiro
Lanny S. Liebeskind and Ethel C. Garnier-Amblard
Maria Jos´e Calhorda and Luis F. Veiros
Structures, and Catalytic Applications 315
Ana M. Martins, Rui F. Munh´a, Luis G. Alves, and Shanmuga Bharathi
Alexandre F. Trindade, Jo˜ao N. Rosa, F´abio M. F. Santos, and Pedro M. P. Gois
Organometallic Catalysts for the Synthesis of Tailor-made Polymers 345
Marc Visseaux, Thomas Chenal, and Philippe Zinck
and Fine Chemicals Catalysis 359
Jean-Fran¸cois Carpentier, Bo Liu, and Yann Sarazin
Manuel Serrano-Ruiz, Franco Scalambra, and Antonio Romerosa
Luciano Pandolfo
Patricia Lara, Karine Philippot, Lise-Marie Lacroix, S´ebastien Lachaize, Nikos Liakakos, Katerina Soulantica, and Bruno Chaudret
Piotr Sobota and ¨©ukasz John
Neil J. Coville and Edward N. Nxumalo
Salvatore Filippone, Enrique E. Maroto, A´ngel Mart´©¥n-Domenech, and Nazario Mart´©¥n
Toru Amaya and Toshikazu Hirao
D. Suresh and Pedro T. Gomes
Vˆania Andr´e, Clara S. B. Gomes, and M. Teresa Duarte
Delele W. Ayele, Wei-Nein Su, John Rick, Hung-Ming Chen, Chun-Jern Pan, Nibret G. Akalework, and Bing-Joe Hwang
Michele Aresta and Angela Dibenedetto
Martin H. G. Prechtl and Sebastian Sahler
Carlos C. Rom˜ao and Helena L. A. Vieira
G´erard Jaouen and Siden Top
Tˆania S. Morais and M. Helena Garcia
Ant´onio Paulo, Goreti Ribeiro Morais, and Isabel Santos
Michael F. Primik, Lukas K. Filak, and Vladimir B. Arion
Sara Figueiredo and Carlos F. G. C. Geraldes
Olivier Buriez, Eric Labb´e, and Christian Amatore
Ji¢§r´©¥ Ludv´©¥k and Irena Hoskovcov´a
Wolfgang Kaim, Martina Bubrin, and Ralph H¨ubner
M. F´atima C. Guedes da Silva and Armando J. L. Pombeiro
Fabrizia Fabrizi de Biani and Piero Zanello
Ekkehardt Hahn
Subject Areas: Chemistry [PN]
