{"product_id":"transition-metal-hydrides-hardback-9780471187684","title":"Transition Metal Hydrides (Hardback) 9780471187684","description":"\u003cfont face=\"Georgia\"\u003e\r\n\u003cp\u003e\u003cfont size=\"6\"\u003eTransition Metal Hydrides\u003c\/font\u003e\u003cbr\u003e\r\n\r\n\r\n\r\n\r\n\r\n\u003c\/p\u003e\n\u003cp\u003e\u003cfont size=\"4\"\u003eA. Dedieu (Edited by), A Dedieu (Author)\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e9780471187684, Wiley\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eHardback, published 6 December 1991\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e412 pages\u003cbr\u003e24.3 x 16.2 x 2.8 cm, 0.73 kg\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\r\n\r\n\r\n\u003cp align=\"justify\"\u003e\u003cstrong\u003e\u003cfont size=\"3\"\u003eEin Streifzug durch die neuesten Fortschritte im Verständnis der Struktur und Reaktivität von Übergangsmetallen. Experimentelle Daten und die Ergebnisse von Computersimulationen stellt das Autorenteam einander gegenüber. Der Leser erhält einen fundierten Eindruck über ein Gebiet, das für viele stöchiometrische und katalytische Prozesse der organischen Chemie von großer Bedeutung ist.\u003cbr\u003e Das Werk ist ein hervorragendes Nachschlagewerk für Metallorganiker, Komplex- und Strukturchemiker und sollte in keiner Instituts- und Universitätsbibliothek fehlen.\u003c\/font\u003e\u003c\/strong\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e1. Introduction to Transition Metal Hydrides \u003cp\u003eWhat is a Transition Metal Hydride?\u003c\/p\u003e \u003cp\u003eImportance of Transition Metal Hydrides in Catalysis\u003c\/p\u003e \u003cp\u003eTheoretical Approaches to Studying Metal Hydrides (DFT, MO Theory)\u003c\/p\u003e \u003cp\u003e2. Electronic Structure and Bonding\u003c\/p\u003e \u003cp\u003eMetal-Hydrogen Bond Character\u003c\/p\u003e \u003cp\u003eBack-Donation and its Influence on Stability\u003c\/p\u003e \u003cp\u003eFactors Affecting Hydride Stability (Metal Oxidation State, Ligand Effects)\u003c\/p\u003e \u003cp\u003e3. Structural Features of Transition Metal Hydrides\u003c\/p\u003e \u003cp\u003eCoordination Geometry and Hydride Position\u003c\/p\u003e \u003cp\u003eX-ray Crystallography and Neutron Diffraction Studies\u003c\/p\u003e \u003cp\u003eSpectroscopic Characterization (NMR, IR)\u003c\/p\u003e \u003cp\u003e4. Formation of Transition Metal Hydrides Oxidative Addition of H2, Heterolytic Cleavage of H2, and Protonation of a Metal Complex.\u003c\/p\u003e \u003cp\u003e5. Reactivity of Transition Metal Hydrides\u003c\/p\u003e \u003cp\u003eInsertion Reactions (CO, Olefins)\u003c\/p\u003e \u003cp\u003eReductive Elimination\u003c\/p\u003e \u003cp\u003eHydrogen Transfer Reactions\u003c\/p\u003e \u003cp\u003eBeta-Hydride Elimination\u003c\/p\u003e \u003cp\u003e6. Catalytic Applications of Transition Metal Hydrides\u003c\/p\u003e \u003cp\u003eHydrogenation Reactions (Alkenes, Alkynes, Carbonyl Compounds)\u003c\/p\u003e \u003cp\u003eHydrosilylation\u003c\/p\u003e \u003cp\u003eHydroboration\u003c\/p\u003e \u003cp\u003eAsymmetric Catalysis\u003c\/p\u003e \u003cp\u003e7. Selected Case Studies The Wilkins on Catalyst (Rh-based), The Crabtree Catalyst (Ir-based), and Metal Hydrides in Polymerization Reactions.\u003c\/p\u003e \u003cp\u003e8. Recent Advances and Future Directions Computational Modeling of Hydride Reactivity, Development of New Catalysts for Hydrogen Storage, and Biomimetic Hydride Transfer Systems.\u003c\/p\u003e\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eSubject Areas: Chemistry [\u003ca title=\"See our other books on Chemistry\" href=\"https:\/\/freshlyprintedbooks.co.uk\/search?q=%22Chemistry%20%5BPN%5D%22\"\u003ePN\u003c\/a\u003e]\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\u003c\/font\u003e","brand":"Wiley-VCH","offers":[{"title":"Brand New","offer_id":52286286856472,"sku":"9780471187684","price":215.56,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0730\/2037\/5320\/files\/9780471187684.jpg?v=1781548773","url":"https:\/\/freshlyprintedbooks.co.uk\/products\/transition-metal-hydrides-hardback-9780471187684","provider":"Freshly Printed Books","version":"1.0","type":"link"}