{"product_id":"thermodynamics-of-molecular-species-hardback-9780471012542","title":"Thermodynamics of Molecular Species (Hardback) 9780471012542","description":"\u003cfont face=\"Georgia\"\u003e\r\n\u003cp\u003e\u003cfont size=\"6\"\u003eThermodynamics of Molecular Species\u003c\/font\u003e\u003cbr\u003e\r\n\r\n\r\n\r\n\r\n\r\n\u003c\/p\u003e\n\u003cp\u003e\u003cfont size=\"4\"\u003eErnest Grunwald (Author)\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e9780471012542, Wiley\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eHardback, published 10 January 1997\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e344 pages\u003cbr\u003e24.2 x 16.3 x 2 cm, 0.709 kg\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\r\n\r\n\r\n\u003cp align=\"justify\"\u003e\u003cstrong\u003e\u003cfont size=\"3\"\u003eAn updated and fresh perspective of the subject based on the concepts that the thermodynamic properties of a system are independent whether composition is specified in terms of formal components or molecular species and that the laws of thermodynamics are independent of the observational time-scale. By applying these concepts, the author has derived approximately 20 general theorems concerned with the thermodynamic properties of molecular species and their relationships to those of the formal components. Grunwald defines molecular species to include all participants in reaction mechanisms. Proved theories are supplemented with verbal explanations and explicit examples. Applications chapters include environmental isomers in liquids and thermodynamic properties of water and aqueous systems. Extra thermodynamic chapters feature interionic attraction theory and structure-energy correlation.\u003c\/font\u003e\u003c\/strong\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eThermodynamic Components and Molecular Species.\u003cbr\u003e \u003cbr\u003e Gibbs Free Energy, Chemical Equilibrium, and Correspondence Theorems.\u003cbr\u003e \u003cbr\u003e Dilute Solutions, Standard Partial Free Energies, and the Stability Theorem.\u003cbr\u003e \u003cbr\u003e Displacements from Equilibrium and Error Tolerance.\u003cbr\u003e \u003cbr\u003e Linear Free-Energy Relationships, Transition-State Theory, and Error Tolerance.\u003cbr\u003e \u003cbr\u003e Enthalpy-Entropy Compensation and Dormant Interactions.\u003cbr\u003e \u003cbr\u003e Effect of Molar Shifts on State Functions.\u003cbr\u003e \u003cbr\u003e Molar-Shift Terms in Dilute Solutions.\u003cbr\u003e \u003cbr\u003e Hard-Sphere and Potential-Energy Cages Around Molecules in Liquids.\u003cbr\u003e \u003cbr\u003e Environmental Isomers, Molecular Complexes and Cage Exchange in Liquids.\u003cbr\u003e \u003cbr\u003e Solvation in Dilute Solutions.\u003cbr\u003e \u003cbr\u003e Thermodynamics of Ionic Species.\u003cbr\u003e \u003cbr\u003e References.\u003cbr\u003e \u003cbr\u003e Index.\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eSubject Areas: Chemistry [\u003ca title=\"See our other books on Chemistry\" href=\"https:\/\/freshlyprintedbooks.co.uk\/search?q=%22Chemistry%20%5BPN%5D%22\"\u003ePN\u003c\/a\u003e]\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\u003c\/font\u003e","brand":"Wiley","offers":[{"title":"Brand New","offer_id":52278192865560,"sku":"9780471012542","price":142.55,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0730\/2037\/5320\/files\/9780471012542.jpg?v=1781459029","url":"https:\/\/freshlyprintedbooks.co.uk\/products\/thermodynamics-of-molecular-species-hardback-9780471012542","provider":"Freshly Printed Books","version":"1.0","type":"link"}