{"product_id":"the-experimental-determination-of-solubilities-hardback-9780471497080","title":"The Experimental Determination of Solubilities (Hardback) 9780471497080","description":"\u003cfont face=\"Georgia\"\u003e\r\n\u003cp\u003e\u003cfont size=\"6\"\u003eThe Experimental Determination of Solubilities\u003c\/font\u003e\u003cbr\u003e\r\n\r\n\r\n\r\n\r\n\r\n\u003c\/p\u003e\n\u003cp\u003e\u003cfont size=\"4\"\u003eG. T. Hefter (Edited by), GT Hefter (Author), R. P. T. Tomkins (Edited by)\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e9780471497080, Wiley\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eHardback, published 14 March 2003\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e658 pages\u003cbr\u003e23.3 x 15.8 x 4.1 cm, 1.049 kg\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\r\n\u003cp align=\"justify\"\u003e\u003cem\u003e\u003cfont size=\"3\"\u003e\"...a must for any serious library...the value of this volume and this series extends far beyond chemistry...\" (Applied Organometallic Chemistry, Vol 19 (10), October 2005)\u003c\/font\u003e\u003c\/em\u003e\u003c\/p\u003e\r\n\r\n\u003cp align=\"justify\"\u003e\u003cstrong\u003e\u003cfont size=\"3\"\u003eIn diesem Band werden vielfältige experimentelle Verfahren zur Bestimmung von Löslichkeiten beschrieben.\u003cbr\u003e - Commission on Solubility Data der IUPAC beschloß, die Qualität der Löslichkeitsdaten international anzugleichen und zu verbessern, indem verläßliche Verfahren zur Ermittlung dieser Daten zusammengefaßt veröffentlicht werden\u003cbr\u003e - alle Datentypen wurden hier berücksichtigt\u003cbr\u003e - ausführliche Angaben zur Zuverlässigkeit der einzelnen Verfahren und zur Auswahl der jeweils geeigneten Methode\u003c\/font\u003e\u003c\/strong\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e\u003cp\u003eList of Contributors xi\u003c\/p\u003e \u003cp\u003eSeries Preface xv\u003c\/p\u003e \u003cp\u003ePreface xvii\u003c\/p\u003e \u003cp\u003eAcknowledgements xxi\u003c\/p\u003e \u003cp\u003eList of Symbols xxiii\u003c\/p\u003e \u003cp\u003e\u003cb\u003eQuantities, Units and Conversions\u003c\/b\u003e\u003cb\u003e 1\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eJohn W. Lorimer\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1. Quantities and Units Used to Describe Solubility 2\u003c\/p\u003e \u003cp\u003e2. Quantities and Units Used to Describe Solubilities of Gases 6\u003c\/p\u003e \u003cp\u003e3. References 14\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Fundamentals of Solubility \u003c\/b\u003e\u003cb\u003e17\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 1.1 Thermodynamics of Solubility\u003c\/b\u003e\u003cb\u003e 19\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eJohn W. Lorimer and Roger Cohen-Adad\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1. Introduction 19\u003c\/p\u003e \u003cp\u003e2. Basic Definitions in Thermodynamics of Solubility 19\u003c\/p\u003e \u003cp\u003e3. Thermodynamics of Solubility 22\u003c\/p\u003e \u003cp\u003e4. Solubility of Gases in Liquids 26\u003c\/p\u003e \u003cp\u003e5. Solubility of Liquids in Liquids 41\u003c\/p\u003e \u003cp\u003e6. Solubility of Solids in Liquids 50\u003c\/p\u003e \u003cp\u003e7. Concluding Remarks 62\u003c\/p\u003e \u003cp\u003e8. References 62\u003c\/p\u003e \u003cp\u003eAppendix A: Some Useful Thermodynamic Concepts and Relations 70\u003c\/p\u003e \u003cp\u003eAppendix B: Numerical and Statistical Procedures in Constructing Fitting Equations 74\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 1.2 Kinetics and Mechanisms of Crystal Growth and Dissolution 77\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eJørgen Christoffersen and Margaret R. Christoffersen\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1. Introduction 77\u003c\/p\u003e \u003cp\u003e2. Fundamental Concepts 77\u003c\/p\u003e \u003cp\u003e3. Mechanisms and Rate Expressions for Dissolution and Growth 81\u003c\/p\u003e \u003cp\u003e4. Comparison of Dissolution and Precipitation Kinetics 93\u003c\/p\u003e \u003cp\u003e5. Kinetics of Approach to Equilibrium 93\u003c\/p\u003e \u003cp\u003e6. Summary of Rate-determining Mechanisms 95\u003c\/p\u003e \u003cp\u003e7. Acknowledgement 95\u003c\/p\u003e \u003cp\u003e8. References 96\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Gases \u003c\/b\u003e\u003cb\u003e99\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 2.1 Solubility of Gases in Liquids \u003c\/b\u003e\u003cb\u003e101\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eH. Lawrence Clever and Rubin Battino\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1. Introduction 101\u003c\/p\u003e \u003cp\u003e2. Quantities Used as a Measure of Gas Solubility 102\u003c\/p\u003e \u003cp\u003e3. The Solution Components 107\u003c\/p\u003e \u003cp\u003e4. Degassing The Solvent 108\u003c\/p\u003e \u003cp\u003e5. Experimental Methods 110\u003c\/p\u003e \u003cp\u003e6. Related Experiments that Complement Gas Solubility Data 130\u003c\/p\u003e \u003cp\u003e7. Treatment of Data 132\u003c\/p\u003e \u003cp\u003e8. Standards 137\u003c\/p\u003e \u003cp\u003e9. Summary and Recommendations 144\u003c\/p\u003e \u003cp\u003e10. References 145\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 2.2 Solubility of Gases in Polymers \u003c\/b\u003e\u003cb\u003e151\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eY uri Y ampolski and Russell Paterson\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1. Introduction 151\u003c\/p\u003e \u003cp\u003e2. Manometric Methods 152\u003c\/p\u003e \u003cp\u003e3. Gravimetric Methods 156\u003c\/p\u003e \u003cp\u003e4. Inverse Gas Chromatography 160\u003c\/p\u003e \u003cp\u003e5. Miscellaneous 165\u003c\/p\u003e \u003cp\u003e6. Conclusions 167\u003c\/p\u003e \u003cp\u003e7. References 168\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 2.3 Solubility of Gases in Molten Salts and Molten Metals \u003c\/b\u003e\u003cb\u003e173\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eReginald P.T. Tomkins\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1. Solubility of Gases in Molten Salts 173\u003c\/p\u003e \u003cp\u003e2. Solubility of Gases in Molten Metals 203\u003c\/p\u003e \u003cp\u003e3. References 215\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 2.4 Solubility of Gases in Solid Metals \u003c\/b\u003e\u003cb\u003e219\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eY Sakamoto and F. A. Lewis\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1. Sieverts Method 220\u003c\/p\u003e \u003cp\u003e2. Equilibrate.Quench.Analyze Method 222\u003c\/p\u003e \u003cp\u003e3. Gravimetric Method 224\u003c\/p\u003e \u003cp\u003e4. Changes of Lattice Parameters and Electrical Resistivity Due to Dissolved Hydrogen in Metals 225\u003c\/p\u003e \u003cp\u003e5. Determination of Changes of Hydrogen Solubilities from Measurements of Electrode Potential Under Conditions of Controlled Electolyte Stirring 228\u003c\/p\u003e \u003cp\u003e6. References 232\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Liquids\u003c\/b\u003e\u003cb\u003e 235\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 3 Liquid–Liquid Solubilities \u003c\/b\u003e\u003cb\u003e237\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eGlenn T. Hefter\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1. Introduction 237\u003c\/p\u003e \u003cp\u003e2. The Synthetic Method 238\u003c\/p\u003e \u003cp\u003e3. The Analytical Method 244\u003c\/p\u003e \u003cp\u003e4. Miscellaneous Methods 249\u003c\/p\u003e \u003cp\u003e5. Sample Purity 253\u003c\/p\u003e \u003cp\u003e6. Test Systems 253\u003c\/p\u003e \u003cp\u003e7. References 254\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Solids\u003c\/b\u003e\u003cb\u003e 257\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 4.1 Solubility of Solids in Liquids \u003c\/b\u003e\u003cb\u003e259\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eRoger Cohen-Adad and Marie-Thér\u003c\/i\u003e\u003ci\u003eèse Cohen Adad\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1. General Review of Methods 259\u003c\/p\u003e \u003cp\u003e2. Analytical Methods 264\u003c\/p\u003e \u003cp\u003e3. Synthetic Methods 277\u003c\/p\u003e \u003cp\u003e4. Combinatorial. Methods 306\u003c\/p\u003e \u003cp\u003e5. Summary of Experimental Difficulties 309\u003c\/p\u003e \u003cp\u003e6. References 311\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 4.2 Solubility of Sparingly Soluble Ionic Solids in Liquids \u003c\/b\u003e\u003cb\u003e315\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eHeinz Gamsjger and Erich Königsberger\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1. Introduction 315\u003c\/p\u003e \u003cp\u003e2. Fundamentals and Applications of Solubility Measurements 316\u003c\/p\u003e \u003cp\u003e3. The Experimental Determination of Solubilities of Sparingly Soluble Compounds 331\u003c\/p\u003e \u003cp\u003e4. Summary, Conclusions and Recommendations 351\u003c\/p\u003e \u003cp\u003e5. References 353\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 4.3 Solubility of Salt–Water Systems at High Temperatures and Pressures \u003c\/b\u003e\u003cb\u003e359\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eVladimir M. Valyashko and B.R. Churagulov\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1. Introduction 359\u003c\/p\u003e \u003cp\u003e2. Phase Diagram Construction (Theory) 361\u003c\/p\u003e \u003cp\u003e3. Methods and Equipment for Studying Phase Equilibria in Aqueous Systems at High Pressures and Temperatures 387\u003c\/p\u003e \u003cp\u003e4. References 427\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 4.4 Solubility of Metals and Non-metallic Substances in Liquid Metals \u003c\/b\u003e\u003cb\u003e437\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eCezary Guminski and Hans U. Borgstedt\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1. Methods Based on Phase Separation 437\u003c\/p\u003e \u003cp\u003e2. Methods Without Separation of the Solute from the Saturated Solution 448\u003c\/p\u003e \u003cp\u003e3. Indirect Methods 465\u003c\/p\u003e \u003cp\u003e4. Solubility Determinations of Metals and Non-metals in Solid Metals 469\u003c\/p\u003e \u003cp\u003e5. References 469\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 4.5 Solubility of Solids in Solids\u003c\/b\u003e\u003cb\u003e 477\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eJames Sangster\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1. Introduction 477\u003c\/p\u003e \u003cp\u003e2. The Equilibrium Phase Diagram 477\u003c\/p\u003e \u003cp\u003e3. Thermal Analysis 479\u003c\/p\u003e \u003cp\u003e4. Quenching Followed by Analysis 485\u003c\/p\u003e \u003cp\u003e5. X-Ray Examination 486\u003c\/p\u003e \u003cp\u003e6. Ionic Conductivity 486\u003c\/p\u003e \u003cp\u003e7. Interdiffusion 487\u003c\/p\u003e \u003cp\u003e8. Other Methods 487\u003c\/p\u003e \u003cp\u003e9. References 489\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Special Systems \u003c\/b\u003e\u003cb\u003e491\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 5.1 Solubility of Solids and Liquids in Supercritical Fluids\u003c\/b\u003e\u003cb\u003e 493\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eKarel Aim and Maurizio Fermeglia\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1. Introduction 493\u003c\/p\u003e \u003cp\u003e2. Basic Equations and Nomenclature 496\u003c\/p\u003e \u003cp\u003e3. Experimental Determination of Solubilities in Dense Gases 498\u003c\/p\u003e \u003cp\u003e4. Static Methods 504\u003c\/p\u003e \u003cp\u003e5. Recirculation Methods 515\u003c\/p\u003e \u003cp\u003e6. Flow Methods 522\u003c\/p\u003e \u003cp\u003e7. Saturation (Transpiration) Methods 528\u003c\/p\u003e \u003cp\u003e8. Dew- and Bubble-point Methods 534\u003c\/p\u003e \u003cp\u003e9. Supercritical Fluid Chromatography 538\u003c\/p\u003e \u003cp\u003e10. References 541\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 5.2 Solubility of Solids and Liquids in Cryogenic Liquids\u003c\/b\u003e\u003cb\u003e 557\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eElzbieta Szczepaniec-Cieciak\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1. Introduction 557\u003c\/p\u003e \u003cp\u003e2. Experimental Techniques for the Determination of Solid.Liquid (S.L) and Solid.Liquid.Vapor (S.L.V) Equilibria in Cryogenic Systems 565\u003c\/p\u003e \u003cp\u003e3. Concluding Remarks 584\u003c\/p\u003e \u003cp\u003e4. References 586\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 5.3 Solubility of Polymers in Liquids \u003c\/b\u003e\u003cb\u003e595\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eSonja Krause\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1. Sample Problems 596\u003c\/p\u003e \u003cp\u003e2. Kinetic Problems 600\u003c\/p\u003e \u003cp\u003e3. Phase Diagrams 601\u003c\/p\u003e \u003cp\u003e4. Methods 605\u003c\/p\u003e \u003cp\u003e5. References 615\u003c\/p\u003e \u003cp\u003eIndex 617\u003c\/p\u003e\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eSubject Areas: Chemistry [\u003ca title=\"See our other books on Chemistry\" href=\"https:\/\/freshlyprintedbooks.co.uk\/search?q=%22Chemistry%20%5BPN%5D%22\"\u003ePN\u003c\/a\u003e]\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\u003c\/font\u003e","brand":"Wiley","offers":[{"title":"Brand New","offer_id":52293495456024,"sku":"9780471497080","price":287.99,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0730\/2037\/5320\/files\/9780471497080.jpg?v=1781642428","url":"https:\/\/freshlyprintedbooks.co.uk\/products\/the-experimental-determination-of-solubilities-hardback-9780471497080","provider":"Freshly Printed Books","version":"1.0","type":"link"}