{"product_id":"superacid-chemistry-hardback-9780471596684","title":"Superacid Chemistry (Hardback) 9780471596684","description":"\u003cfont face=\"Georgia\"\u003e\r\n\u003cp\u003e\u003cfont size=\"6\"\u003eSuperacid Chemistry\u003c\/font\u003e\u003cbr\u003e\r\n\r\n\r\n\r\n\r\n\r\n\u003c\/p\u003e\n\u003cp\u003e\u003cfont size=\"4\"\u003eGeorge A. Olah (Author), G. K. Surya Prakash (Author), Arpad Molnar (Author), Jean Sommer (Author)\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e9780471596684, Wiley\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eHardback, published 10 March 2009\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e880 pages\u003cbr\u003e23.6 x 16.3 x 4.6 cm, 1.247 kg\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\r\n\u003cp align=\"justify\"\u003e\u003cem\u003e\u003cfont size=\"3\"\u003e\"Superacid Chemistry is a tightly worded description of the present state of the field, and as an inclusive reference book for this area of chemistry, I believe most active researchers will want access to it.\" (JACS , August 2009)\u003c\/font\u003e\u003c\/em\u003e\u003c\/p\u003e\r\n\r\n\u003cp align=\"justify\"\u003e\u003cstrong\u003e\u003cfont size=\"3\"\u003e\u003cp\u003e\u003cb\u003eThe chemistry of superacids deals with acid systems stronger than conventional strong mineral Bronsted acids such as sulfuric acid and Lewis acids such as aluminum trichloride.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eThe first edition of \u003ci\u003eSuperacid Chemistry,\u003c\/i\u003e published in 1985, quickly became the definitive work in the field. Since that time, however, the field has grown exponentially, with the development of new superacid systems and innovative superacid applications. This Second Edition of \u003ci\u003eSuperacid Chemistry\u003c\/i\u003e has been published to bring this acclaimed book fully up to date with all these new developments.\u003c\/p\u003e \u003cp\u003e\u003ci\u003eSuperacid Chemistry\u003c\/i\u003e features a team of pioneering authors in the field headed by George Olah, the 1994 Nobel Laureate in Chemistry. The book covers:\u003c\/p\u003e \u003cul\u003e \u003cli\u003eGeneral aspects of superacid chemistry, including types of superacids and experimental techniques for acidity measurements\u003c\/li\u003e \u003cli\u003eSuperacids systems, including primary, ternary, and solid superacids\u003c\/li\u003e \u003cli\u003eCarbocations in superacids, including methods of generating carbocations in superacids and methods and techniques in the study of carbocations\u003c\/li\u003e \u003cli\u003eHeterocations in superacids, including onium ions, enium ions, homo-, and heteropolyatomic cations, and cations of group 6-12 elements\u003c\/li\u003e \u003cli\u003eSuperacids catalyzed reactions, including conversion of saturated hydrocarbons and alkylation of aromatic hydrocarbons\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003eExtensive references are provided throughout the book to guide readers to the primary literature for further in-depth investigations. In short, this \u003ci\u003eSecond Edition\u003c\/i\u003e meets the growing need for current information on superacid chemistry among researchers in inorganic, organic, and physical chemistry in order to support and advance their research.\u003c\/p\u003e\u003c\/font\u003e\u003c\/strong\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e\u003cp\u003ePreface to the Second Edition xvii\u003cbr\u003ePreface to the First Edition xix\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1.General Aspects 1\u003c\/b\u003e\u003cbr\u003e1.1. Defining Acidity 1\u003cbr\u003e1.2. Definition of Superacids 6\u003cbr\u003e1.3. Types of Superacids 9\u003cbr\u003e1.4. Experimental Techniques for Acidity Measurements (Protic Acids) 11\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2. Superacid Systems 35\u003c\/b\u003e\u003cbr\u003e2.1. Primary Superacids 35\u003cbr\u003e2.2. Binary Superacids 47\u003cbr\u003e2.3. Ternary Superacids 62\u003cbr\u003e2.4. Solid Superacids 63\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3. Carbocations in Superacid Systems 83\u003c\/b\u003e\u003cbr\u003e3.1. Introduction 83\u003cbr\u003e3.2. Methods of Generating Carbocations in Superacids Systems 87\u003cbr\u003e3.3. Methods and Techniques in the Study of Carbocations 88\u003cbr\u003e3.4. Trivalent Carbocations 93\u003cbr\u003e3.5. Equilibrating (Degenerate) and Higher (Five or Six) Coordinate (Nonclassical) Carbocations 206\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4.Heterocations in Superacid Systems 311\u003c\/b\u003e\u003cbr\u003e4.1. Introduction 311\u003cbr\u003e4.2. Onium Ions 311\u003cbr\u003e4.3. Enium Ions 397\u003cbr\u003e4.4. Homo-and Heteropolyatomic Cations 426\u003cbr\u003e4.5. Cations of Group 6–12 Elements 453\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5. Superacid-Catalyzed Reactions 501\u003c\/b\u003e\u003cbr\u003e5.1. Conversion of Saturated Hydrocarbons 501\u003cbr\u003e5.2. Alkylation of Aromatic Hydrocarbons 554\u003cbr\u003e5.3. Acylation of Aromatics 608\u003cbr\u003e5.4. Carboxylation 618\u003cbr\u003e5.5. Formylation 627\u003cbr\u003e5.6. Thio- and Dithiocarboxylation 632\u003cbr\u003e5.7. Sulfonation and Sulfonylation 633\u003cbr\u003e5.8. Nitration 636\u003cbr\u003e5.9. Nitrosonium Ion (NOþ)-Induced Reactions 643\u003cbr\u003e5.10. Halogenation 647\u003cbr\u003e5.11. Amination 659\u003cbr\u003e5.12. Oxyfunctionalization 660\u003cbr\u003e5.13. Superacids in Protection Group Chemistry 676\u003cbr\u003e5.14. Superacids in Heterocyclic Chemistry 680\u003cbr\u003e5.15. Dehydration 698\u003cbr\u003e5.16. Superacidsin Carbohydrate Chemistry 700\u003cbr\u003e5.17. Rearrangements and Cyclizations 706\u003cbr\u003e5.18. Ionic Hydrogenation 727\u003cbr\u003e5.19. Esterification and Ester Cleavage 734\u003cbr\u003e5.20. Additions 735\u003cbr\u003e5.21. Ritter Reactions 742\u003cbr\u003e5.22. Polymerization 744\u003cbr\u003e5.23. Miscellaneous Reactions 750\u003c\/p\u003e \u003cp\u003eReferences 756\u003cbr\u003eOutlook 789\u003cbr\u003eIndex 791\u003c\/p\u003e\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eSubject Areas: Chemistry [\u003ca title=\"See our other books on Chemistry\" href=\"https:\/\/freshlyprintedbooks.co.uk\/search?q=%22Chemistry%20%5BPN%5D%22\"\u003ePN\u003c\/a\u003e]\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\u003c\/font\u003e","brand":"Wiley-Interscience","offers":[{"title":"Brand New","offer_id":52405526135064,"sku":"9780471596684","price":154.89,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0730\/2037\/5320\/files\/9780471596684.jpg?v=1784136175","url":"https:\/\/freshlyprintedbooks.co.uk\/products\/superacid-chemistry-hardback-9780471596684","provider":"Freshly Printed Books","version":"1.0","type":"link"}