{"product_id":"reactions-and-mechanisms-in-thermal-analysis-of-advanced-materials-hardback-9781119117575","title":"Reactions and Mechanisms in Thermal Analysis of Advanced Materials (Hardback) 9781119117575","description":"\u003cfont face=\"Georgia\"\u003e\r\n\u003cp\u003e\u003cfont size=\"6\"\u003eReactions and Mechanisms in Thermal Analysis of Advanced Materials\u003c\/font\u003e\u003cbr\u003e\r\n\r\n\r\n\r\n\r\n\r\n\u003c\/p\u003e\n\u003cp\u003e\u003cfont size=\"4\"\u003eAtul Tiwari (Edited by), A Tiwari (Author), Baldev Raj (Edited by)\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e9781119117575, Wiley\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eHardback, published 11 September 2015\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e616 pages\u003cbr\u003e25.4 x 17.5 x 3.6 cm, 1.179 kg\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\r\n\r\n\r\n\u003cp align=\"justify\"\u003e\u003cstrong\u003e\u003cfont size=\"3\"\u003e\u003cp\u003eStrong bonds form stronger materials. For this reason, the investigation on thermal degradation of materials is a significantly important area in research and development activities. The analysis of thermal stability can be used to assess the behavior of materials in the aggressive environmental conditions, which in turn provides valuable information about the service life span of the materiel.\u003c\/p\u003e \u003cp\u003eUnlike other books published so far that have focused on either the fundamentals of thermal analysis or the degradation pattern of the materials, this book is specifically on the mechanism of degradation of materials.\u003c\/p\u003e \u003cp\u003eThe mechanism of rapturing of chemical bonds as a result of exposure to high-temperature environment is difficult to study and resulting mechanistic pathway hard to establish. Limited information is available on this subject in the published literatures and difficult to excavate.\u003c\/p\u003e \u003cp\u003eChapters in this book are contributed by the experts working on thermal degradation and analysis of the wide variety of advanced and traditional materials. Each chapter discusses the material, its possible application, behavior of chemical entities when exposed to high-temperature environment and mode and the mechanistic route of its decomposition. Such information is crucial while selecting the chemical ingredients during the synthesis or development of new materials technology.\u003c\/p\u003e\u003c\/font\u003e\u003c\/strong\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e\u003cp\u003ePreface xv\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart 1: Degradation of Polymers\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Thermal Stability of Organic Monolayers Covalently Grafted on Silicon Surfaces 3\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eFlorent Yang, Philippe Allongue, Francois Ozanam and Jean-Noel Chazalviel\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 3\u003cbr\u003e1.2 Alkyl-Grafted Surfaces 8\u003cbr\u003e1.3 Alkoxy-Grafted Surfaces 15\u003cbr\u003e1.4 Surfaces Grafted with Aryl Groups 19\u003cbr\u003e1.5 Surfaces Grafted via Si–N Linkages 22\u003cbr\u003e1.6 Summary 27\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Thermal Analysis to Discriminate the Stability of Biomedical Ultrahigh-Molecular-Weight Polyethylenes Formulations 39\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eMaria Jose Martinez-Morlanes and Francisco Javier Medel\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 39\u003cbr\u003e2.2 Suitability of TGA Analysis for the Study of Stability of Medical Polyethylene 42\u003cbr\u003e2.3 Activation Energies of Degradation Processes in the Thermal Decomposition of UHMWPE 56\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Materials Obtained by Solid-State Thermal Decomposition of Coordination Compounds and Metal–Organic Coordination Polymers 63\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eOana Carp\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 63\u003cbr\u003e3.2 Coordination Compounds and Metal–Organic Coordination Polymers as Precursors of Oxides 65\u003cbr\u003e3.3 Coordination Compounds and Metal–Organic Coordination Polymers as Precursors of Sulfides 72\u003cbr\u003e3.4 Coordination Compounds as Precursors of Composites 74\u003cbr\u003e3.5 Coordination Compounds and Metal–Organic Coordination Polymers as Precursors of New Complexes 74\u003cbr\u003e3.6 Coordination Compounds and Metal–Organic Coordination Polymers as Precursor of Metals 75\u003cbr\u003e3.7 Coordination Compounds as Precursor of Nitrides 76\u003cbr\u003e3.8 Other Materials 77\u003cbr\u003e3.9 Conclusions 77\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Methods for Limiting the Flammability of High-Density Polyethylene with Magnesium Hydroxide 85\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eJoanna Lenża, Maria Sozańska and Henryk Rydarowski\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 85\u003cbr\u003e4.2 Experimental Part 88\u003cbr\u003e4.3 Results and Discussion 91\u003cbr\u003e4.4 Conclusions 99\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Thermal Analysis in the Study of Polymer (Bio)-degradation 103\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eJoanna Rydz, Marta Musioł and Henryk Janeczek\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 103\u003cbr\u003e5.2 Differential Scanning Calorimetry 105\u003cbr\u003e5.3 Dynamic Mechanical Analysis 112\u003cbr\u003e5.4 Thermogravimetric Analysis 115\u003cbr\u003e5.5 Conclusions 120\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Thermal and Oxidative Degradation Behavior of Polymers and Nanocomposites 127\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eGauri Ramasubramanian and Samy Madbouly\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 127\u003cbr\u003e6.2 Thermal Degradation 131\u003cbr\u003e6.3 Chemical and Oxidative Degradation 137\u003cbr\u003e6.4 Photo-oxidation 143\u003cbr\u003e6.5 Environmental and Biological Degradation 148\u003cbr\u003e6.6 Degradation of Polymer Nanocomposites 154\u003cbr\u003e6.7 Conclusions 162\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Thermal Degradation Effects on Polyurethanes and Their Nanocomposites 165\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eIvan Navarro-Baena, Marina P. Arrieta, Alicia Mujica-Garcia, Valentina Sessini, Jose M. Kenny and Laura Peponi\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 165\u003cbr\u003e7.2 Main Techniques Used for Studying the Thermal Degradation Process 167\u003cbr\u003e7.3 Degradation Mechanisms 169\u003cbr\u003e7.4 Chemical Approaches Used to Improve the Thermal Stability of PU 171\u003cbr\u003e7.5 Thermal Degradation of PU Based on Natural Sources 172\u003cbr\u003e7.6 Nanocomposites 174\u003cbr\u003e7.7 PU Electrospun Fibers 181\u003cbr\u003e7.8 Conclusions 184\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Controllable Thermal Degradation of Thermosetting Epoxy Resins 191\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eZhonggang Wang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 191\u003cbr\u003e8.2 Ester-, Carbamate-, and Carbonate-Linked Reworkable Epoxy Resins 193\u003cbr\u003e8.3 Ether-Linked Reworkable Epoxy Resins 195\u003cbr\u003e8.4 Phosphate- and Phosphite-Linked Reworkable Epoxy Resins 196\u003cbr\u003e8.5 Sulfite-Linked Reworkable Epoxy Resins 204\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Mechanism of Thermal Degradation of Vinylidene Chloride Barrier Polymers 209\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eBob A. Howell\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 209\u003cbr\u003e9.2 Discussion 210\u003cbr\u003e9.3 Conclusions 218\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Role of Mass Spectrometry in the Elucidation of Thermal Degradation Mechanisms in Polymeric Materials 221\u003c\/b\u003e\u003cbr\u003e\u003ci\u003ePaola Rizzarelli and Sabrina Carroccio\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 221\u003cbr\u003e10.2 Thermogravimetry-Mass Spectrometry (TG-MS) 224\u003cbr\u003e10.3 Gas Chromatography-Mass Spectrometry (GC-MS) and Pyrolysis-Gas Chromatography\/Mass Spectrometry (Py-GC\/MS) 228\u003cbr\u003e10.4 Direct Pyrolysis Mass Spectrometry (DPMS) 237\u003cbr\u003e10.5 Matrix-Assisted Laser Desorption Ionisation Mass Spectrometry (MALDI MS) 242\u003cbr\u003e10.6 Other Mass Spectrometric Techniques 246\u003cbr\u003e10.7 Conclusions 249\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 The Mechanism of Poly(styrene) Degradation 259\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eBob A. Howell\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction 259\u003cbr\u003e11.2 Discussion 260\u003cbr\u003e11.3 Conclusions 266\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 The Use of Thermal Volatilization Analysis of Polylactic Acid and Its Blends with Starch 269\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eDerval dos Santos Rosa, Claudio Roberto Passatore, and Jose Ricardo Nunes de Macedo\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction 269\u003cbr\u003e12.2 Use of TVA 271\u003cbr\u003e12.3 TVA as an Analytic Technique 272\u003cbr\u003e12.4 TVA-PLA Investigation 274\u003cbr\u003e12.5 TVA – Thermoplastic Starch 276\u003cbr\u003e12.6 Analyses of TVA – PLA and Their Mixtures with Thermoplastic Starch 280\u003cbr\u003e12.7 Conclusions 282\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart 2: Degradation of Other Materials\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Reaction Mechanisms in Thermal Analysis of Amazon Oilseeds 287\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eOrquidea Vasconcelos dos Santos, Carlos Emmerson and Suzana Caetano da Silva Lannes\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e13.1 Introduction 287\u003c\/p\u003e \u003cp\u003e13.2 Oxidative Stability 297\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 Thermal Degradation of Cellulose and Cellulosic Substrates 301\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eJenny Alongi and Giulio Malucelli\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e14.1 Introduction 301\u003cbr\u003e14.2 Thermal and Thermo-oxidative Degradation of Cellulose 302\u003cbr\u003e14.3 Factors Affecting Cellulose Thermal Degradation: Charring\/Volatilisation Competition 318\u003cbr\u003e14.4 Conclusions 329\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Thermal Decomposition Behavior of Sodium Alkoxides of Relevance to Fast Reactor Technology 333\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eK. Chandran, M. Kamruddin, S. Anthonysamy and V. Ganesan\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e15.1 Introduction 333\u003cbr\u003e15.2 Preparation of Sodium Alkoxides 334\u003cbr\u003e15.3 Characterization of Sodium Alkoxides 339\u003cbr\u003e15.4 Thermal Decomposition of Sodium Alkoxides 348\u003cbr\u003e15.5 Kinetic Analysis 364\u003c\/p\u003e \u003cp\u003e\u003cb\u003e16 Thermal Degradation and Morphological Characteristics of Bone Products 393\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eF. Miculescu, A. Maidaniuc, G.E. Stan, M. Miculescu, S.I. Voicu, L.T.Ciocan\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e16.1 Introduction and Objectives 393\u003cbr\u003e16.2 Short Overview on the Thermal Analysis Experimental Methods 396\u003cbr\u003e16.3 Morpho-structural Changes Induced by the Thermal Treatments Applied to Hard Tissues. Bone Degradation Mechanism 400\u003cbr\u003e16.4 Conclusions 408\u003c\/p\u003e \u003cp\u003e\u003cb\u003e17 Processes and Mechanisms in Hydrothermal Degradation of Waste Electric and Electronic Equipment 411\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eYu Luling, He Wenzhi and Li Guangming\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e17.1 Introduction 411\u003cbr\u003e17.2 Application of Hydrothermal Degradation in Treatment of WEEE 414\u003cbr\u003e17.3 Mechanism of Hydrothermal Degradation for Treatment of WEEE 418\u003cbr\u003e17.4 Conclusion 431\u003c\/p\u003e \u003cp\u003e\u003cb\u003e18 Heat Transfer Mechanism and Thermomechanical Analysis of Masonry \u003c\/b\u003e\u003cb\u003eStructures (Mortars and Bricks) Subjected to High Temperatures 437\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eM.E. Macia Torregrosa and J. Camacho Diez\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e18.1 Introduction: State of the Art 437\u003cbr\u003e18.2 Heat Transfer Mechanisms through a Masonry Element under Load 442\u003cbr\u003e18.3 Influence of High Temperatures on the Structural Behavior of a Masonry Element 444\u003cbr\u003e18.4 Factors Involved in the Behavior of the Masonry Subjected to High Temperatures 444\u003cbr\u003e18.5 Properties of the Ceramic Pieces 449\u003cbr\u003e18.6 Properties of the Mortar 456\u003c\/p\u003e \u003cp\u003e\u003cb\u003e19 Application of Vibrational Spectroscopy to Elucidate Protein Conformational Changes Promoted by Thermal Treatment in Muscle-Based Food 467\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eA.M. Herrero, P. Carmona, F. Jimenez-Colmenero and C. Ruiz-Capillas\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e19.1 Introduction 467\u003cbr\u003e19.2 Protein Structure 468\u003cbr\u003e19.3 Muscle-Based Food Proteins: Thermal treatment 468\u003cbr\u003e19.4 Vibrational Spectroscopic Methods and Protein Structure 469\u003cbr\u003e19.5 Vibrational Spectroscopy to Elucidate Structural Changes Induced by Thermal Treatment in Muscle Foods\u003cbr\u003e473\u003cbr\u003e19.6 Conclusions 479\u003c\/p\u003e \u003cp\u003e\u003cb\u003e20 Thermal Activation of Layered Hydroxide-Based Catalysts 483\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eMilica Hadnadjev-Kostic, Tatjana Vulic and Radmila Marinkovic-Neducin\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e20.1 Introduction 483\u003cbr\u003e20.2 LDH General Properties 484\u003cbr\u003e20.3 Thermal Activation of LDH-Based Catalysts – Thermal Decomposition Pathway from LDH to Mixed Oxides\u003cbr\u003e490\u003cbr\u003e20.4 Properties of Thermally Activated LDHs 495\u003cbr\u003e20.5 Application of LDH-Based Materials 501\u003cbr\u003e20.6 Synthesis Methods of Ti-Containing LDH-Based Materials 502\u003cbr\u003e20.7 Synthesis Methods for the Association of TiO2 and LDH-Based Catalysts 502\u003cbr\u003e20.8 Conclusions and Perspectives 509\u003c\/p\u003e \u003cp\u003e\u003cb\u003e21 Thermal Decomposition of Natural Fibers: Kinetics and Degradation Mechanisms 515\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eMatheus Poletto, Heitor L. Ornaghi Junior and Ademir J. Zattera\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e21.1 Introduction 515\u003cbr\u003e21.2 Theoretical Background 516\u003cbr\u003e21.3 Chemical Composition of the Natural Fibers 522\u003cbr\u003e21.4 XRD Analysis Applied to Natural Fibers 524\u003cbr\u003e21.5 Thermogravimetric Analysis of Natural Fibers 527\u003cbr\u003e21.6 Kinetic Degradation and Reaction Mechanisms in the Solid State of Natural Fibers 532\u003cbr\u003e21.7 Conclusion 541\u003c\/p\u003e \u003cp\u003e\u003cb\u003e22 On the Kinetic Mechanism of Non-isothermal Degradation of Solids 547\u003c\/b\u003e\u003cbr\u003e\u003ci\u003eLyubomir T. Vlaev, Velyana G. Georgieva, and Mariana P. Tavlieva\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e22.1 Introduction 547\u003cbr\u003e22.2 Mathematical Background in the Thermogravimetry 549\u003cbr\u003e22.3 Kinetic Mechanism of the Thermal Degradation of CaC2O4・H2O 561\u003cbr\u003e22.4 Kinetic Mechanism of the Thermal Degradation of Chitin 567\u003cbr\u003e22.5 Kinetic Mechanism of the Thermal Degradation of Rice Husks 571\u003cbr\u003e22.6 Conclusions 574\u003c\/p\u003e \u003cp\u003eAcknowledgments 575\u003cbr\u003eReferences 575\u003cbr\u003eIndex 579\u003c\/p\u003e\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eSubject Areas: Mechanical engineering \u0026amp; materials [\u003ca title=\"See our other books on Mechanical engineering \u0026amp; materials\" href=\"https:\/\/freshlyprintedbooks.co.uk\/search?q=%22Mechanical%20engineering%20\u0026amp;%20materials%20%5BTG%5D%22\"\u003eTG\u003c\/a\u003e]\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\u003c\/font\u003e","brand":"Wiley-Scrivener","offers":[{"title":"Brand New","offer_id":52421417861400,"sku":"9781119117575","price":146.66,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0730\/2037\/5320\/files\/9781119117575.jpg?v=1784595663","url":"https:\/\/freshlyprintedbooks.co.uk\/products\/reactions-and-mechanisms-in-thermal-analysis-of-advanced-materials-hardback-9781119117575","provider":"Freshly Printed Books","version":"1.0","type":"link"}