{"product_id":"organometallic-compounds-of-low-coordinate-si-ge-sn-and-pb-from-phantom-species-to-stable-compounds-hardback-9780470725436","title":"Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb; From Phantom Species to Stable Compounds (Hardback) 9780470725436","description":"\u003cfont face=\"Georgia\"\u003e\r\n\u003cp\u003e\u003cfont size=\"6\"\u003eOrganometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb\u003c\/font\u003e\u003cbr\u003e\r\n\u003cfont size=\"5\"\u003eFrom Phantom Species to Stable Compounds\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\r\n\r\n\u003cp\u003e\u003cfont size=\"4\"\u003eVladimir Ya. Lee (Author), Akira Sekiguchi (Author)\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e9780470725436, Wiley\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eHardback, published 23 July 2010\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e448 pages\u003cbr\u003e24.8 x 17.6 x 3.1 cm, 0.879 kg\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\r\n\u003cp align=\"justify\"\u003e\u003cem\u003e\u003cfont size=\"3\"\u003e\u003cp\u003e“In effect, the body of work described constitutes one of the cornerstones of modern main group chemistry and this\u003c\/p\u003e \u003cp\u003eaccount provides a highly useful reference source for the specialist as well as a non-intimidating guide for the beginner.”  (\u003ci\u003eApplied Organometallic Chemistry\u003c\/i\u003e, 6 March 2015)\u003c\/p\u003e \u003cp\u003e \u003c\/p\u003e \u003cbr\u003e \u003c\/font\u003e\u003c\/em\u003e\u003c\/p\u003e\r\n\r\n\u003cp align=\"justify\"\u003e\u003cstrong\u003e\u003cfont size=\"3\"\u003eUntil recently the low-coordinate compounds of the heavier elements of group 14 were known only as transient, unstable species which were difficult to isolate. However recent developments have led to the stabilisation of these compounds and today heavier group 14 element cations, radicals, anions, carbene analogues, alkene and alkyne analogues and aromatics have all been prepared as highly reactive, stable, fully characterizable and readily available organometallic reagents.  \u003cp\u003e\u003ci\u003eOrganometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb\u003c\/i\u003e describes the chemistry of this exciting new class of organometallics, with an emphasis on their major similarities and differences with the analogous species in organic chemistry. Topics covered include include the synthesis, structure, reactions and synthetic applications of :\u003c\/p\u003e \u003cul\u003e \u003cli\u003eSi-, Ge-, Sn and Pb-centered cations, radicals and anions\u003c\/li\u003e \u003cli\u003eheavy analogues of carbenes: silylenes, germylenes, stannylenes and plumbylenes\u003c\/li\u003e \u003cli\u003eheavy analogues of alkenes: disilenes, digermenes, distannenes, diplumbenes\u003c\/li\u003e \u003cli\u003eheavy analogues of alkynes: disilynes, digermynes, distannynes, diplumbynes, and their valence isomers\u003c\/li\u003e \u003cli\u003eheteronuclear derivatives: silenes, germenes, stannenes, silagermenes, silastannenes, germastannenes\u003c\/li\u003e \u003cli\u003eheavy analogues of alkenes of the type: \u0026gt;E\u003csub\u003e14\u003c\/sub\u003e=E\u003csub\u003e13\u003c\/sub\u003e-, \u0026gt;E\u003csub\u003e14\u003c\/sub\u003e=E\u003csub\u003e15\u003c\/sub\u003e-, \u0026gt;E\u003csub\u003e14\u003c\/sub\u003e=E\u003csub\u003e16\u003c\/sub\u003e [where E\u003csub\u003e13\u003c\/sub\u003e, E\u003csub\u003e14\u003c\/sub\u003e, E\u003csub\u003e15\u003c\/sub\u003e and E\u003csub\u003e16\u003c\/sub\u003e are elements of the groups 13, 14, 15 and 16]\u003c\/li\u003e \u003cli\u003ecyclic compounds (three-, four-, five-, and six-membered rings)\u003c\/li\u003e \u003cli\u003eheavy analogues of 1,3-dienes, allenes and other cumulenes\u003c\/li\u003e \u003cli\u003eheavy analogues of aromatic compounds; including a comparison between organometallic and organic aromaticity\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003e\u003ci\u003eOrganometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb\u003c\/i\u003e is an essential guide to this emerging class of organometallic reagents for researchers and students in main group, organometallic, synthetic and silicon chemistry\u003c\/p\u003e\u003c\/font\u003e\u003c\/strong\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e\u003cb\u003ePreface.\u003c\/b\u003e  \u003cp\u003e\u003cb\u003eAbbreviations.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1. Heavy Analogs of Carbenium Ions: Si-, Ge-, Sn- and Pb-Centered Cations.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction.\u003c\/p\u003e \u003cp\u003e1.2 Synthesis of RR'R\"E\u003csup\u003e+\u003c\/sup\u003eCations (E = Si-Pb).\u003c\/p\u003e \u003cp\u003e1.3 Reactions and Synthetic Applications of RRRE\u003csup\u003e+\u003c\/sup\u003e Cations\u003csup\u003e16\u003c\/sup\u003e.\u003c\/p\u003e \u003cp\u003e1.4 Theoretical Studies.\u003c\/p\u003e \u003cp\u003e1.5 Early Studies of RR'R\"E\u003csup\u003e+\u003c\/sup\u003e Cations: Free or Coordinated?\u003c\/p\u003e \u003cp\u003e1.6 Stable RR'R\"E\u003csup\u003e+\u003c\/sup\u003e Cations.\u003c\/p\u003e \u003cp\u003e1.7 Summary and Outlook.\u003c\/p\u003e \u003cp\u003e1.8 References.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2. Heavy Analogs of Organic Free Radicals: Si-, Ge-, Sn- and Pb-Centered Radicals.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction.\u003c\/p\u003e \u003cp\u003e2.2 Early Studies: Transient Species RR'R\"E.\u003c\/p\u003e \u003cp\u003e2.3 Persistent Radicals (Generation and Identification).\u003c\/p\u003e \u003cp\u003e2.4 Stable Radicals.\u003c\/p\u003e \u003cp\u003e2.5 Summary and Outlook.\u003c\/p\u003e \u003cp\u003e2.6 References.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3. Heavy Analogs of Carbanions: Si-, Ge-, Sn- and Pb-Centered Anions.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction.\u003c\/p\u003e \u003cp\u003e3.2 Synthesis.\u003c\/p\u003e \u003cp\u003e3.3 Structure.\u003c\/p\u003e \u003cp\u003e3.4 Reactions and Synthetic Applications.\u003c\/p\u003e \u003cp\u003e3.5 Recent Developments.\u003c\/p\u003e \u003cp\u003e3.6 Summary and Outlook.\u003c\/p\u003e \u003cp\u003e3.7 References.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4. Heavy Analogs of Carbenes: Silylenes, Germylenes, Stannylenes and Plumbylenes.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction.\u003c\/p\u003e \u003cp\u003e4.2 Generation.\u003c\/p\u003e \u003cp\u003e4.3 Spectroscopic Identification.\u003c\/p\u003e \u003cp\u003e4.4 Structure.\u003c\/p\u003e \u003cp\u003e4.5 Reactions of Transient Species.\u003c\/p\u003e \u003cp\u003e4.6 Stable\/Persistent Silylenes, Germylenes, Stannylenes and Plumbylenes.\u003c\/p\u003e \u003cp\u003e4.7 Summary and Outlook.\u003c\/p\u003e \u003cp\u003e4.8 References.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5. Heavy Analogs of Alkenes, 1,3-Dienes, Allenes and Alkynes: Multiply Bonded Derivatives of Si, Ge, Sn and Pb.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction.\u003c\/p\u003e \u003cp\u003e5.2 Early Studies: Generation and Identification.\u003c\/p\u003e \u003cp\u003e5.3 Stable Derivatives (Synthesis and Structure).\u003c\/p\u003e \u003cp\u003e5.4 Summary and Outlook.\u003c\/p\u003e \u003cp\u003e5.5 References.\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6. Heavy Analogs of Aromatic Compounds.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction.\u003c\/p\u003e \u003cp\u003e6.2 Early Studies.\u003c\/p\u003e \u003cp\u003e6.3 Stable Compounds (Synthesis and Structure).\u003c\/p\u003e \u003cp\u003e6.4 Summary and Outlook.\u003c\/p\u003e \u003cp\u003e6.5 References.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eIndex.\u003c\/b\u003e\u003c\/p\u003e\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eSubject Areas: Chemistry [\u003ca title=\"See our other books on Chemistry\" href=\"https:\/\/freshlyprintedbooks.co.uk\/search?q=%22Chemistry%20%5BPN%5D%22\"\u003ePN\u003c\/a\u003e]\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\u003c\/font\u003e","brand":"Wiley","offers":[{"title":"Brand New","offer_id":52278024667416,"sku":"9780470725436","price":120.99,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0730\/2037\/5320\/files\/9780470725436.jpg?v=1781456119","url":"https:\/\/freshlyprintedbooks.co.uk\/products\/organometallic-compounds-of-low-coordinate-si-ge-sn-and-pb-from-phantom-species-to-stable-compounds-hardback-9780470725436","provider":"Freshly Printed Books","version":"1.0","type":"link"}