{"product_id":"orbital-interactions-in-chemistry-hardback-9780471080398","title":"Orbital Interactions in Chemistry (Hardback) 9780471080398","description":"\u003cfont face=\"Georgia\"\u003e\r\n\u003cp\u003e\u003cfont size=\"6\"\u003eOrbital Interactions in Chemistry\u003c\/font\u003e\u003cbr\u003e\r\n\r\n\r\n\r\n\r\n\r\n\u003c\/p\u003e\n\u003cp\u003e\u003cfont size=\"4\"\u003eThomas A. Albright (Author), Jeremy K. Burdett (Author), Myung-Hwan Whangbo (Author)\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e9780471080398, Wiley\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eHardback, published 17 May 2013\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e848 pages\u003cbr\u003e28.7 x 22.6 x 4.8 cm, 2.173 kg\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\r\n\u003cp align=\"justify\"\u003e\u003cem\u003e\u003cfont size=\"3\"\u003e\"This book can be viewed as a unique and rather complete'encyclopaedia' of the chemical applications ofmolecular orbital theory.\" (Applied OrganometallicChemistry,1 November 2014)\u003c\/font\u003e\u003c\/em\u003e\u003c\/p\u003e\r\n\r\n\u003cp align=\"justify\"\u003e\u003cstrong\u003e\u003cfont size=\"3\"\u003eExplains the underlying structure that unites all disciplinesin chemistry\u003cbr\u003e \u003cbr\u003e Now in its second edition, this book explores organic,organometallic, inorganic, solid state, and materials chemistry,demonstrating how common molecular orbital situations arisethroughout the whole chemical spectrum. The authors explore therelationships that enable readers to grasp the theory thatunderlies and connects traditional fields of study withinchemistry, thereby providing a conceptual framework with which tothink about chemical structure and reactivity problems.\u003cbr\u003e \u003cbr\u003e Orbital Interactions in Chemistry begins by developingmodels and reviewing molecular orbital theory. Next, the bookexplores orbitals in the organic-main group as well as in solids.Lastly, the book examines orbital interaction patterns that occurin inorganic-organometallic fields as well as clusterchemistry, surface chemistry, and magnetism in solids.\u003cbr\u003e \u003cbr\u003e This Second Edition has been thoroughly revised andupdated with new discoveries and computational tools since thepublication of the first edition more than twenty-five years ago.Among the new content, readers will find:\u003cbr\u003e * Two new chapters dedicated to surface science and magneticproperties\u003cbr\u003e * Additional examples of quantum calculations, focusing oninorganic and organometallic chemistry\u003cbr\u003e * Expanded treatment of group theory\u003cbr\u003e * New results from photoelectron spectroscopy\u003cbr\u003e \u003cbr\u003e Each section ends with a set of problems, enabling readers totest their grasp of new concepts as they progress through the text.Solutions are available on the book's ftp site.\u003cbr\u003e \u003cbr\u003e Orbital Interactions in Chemistry is written for bothresearchers and students in organic, inorganic, solid state,materials, and computational chemistry. All readers will discoverthe underlying structure that unites all disciplines inchemistry.\u003c\/font\u003e\u003c\/strong\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e\u003cp\u003ePreface xi\u003c\/p\u003e \u003cp\u003eAbout the Authors xiii\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 1 Atomic and Molecular Orbitals 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Atomic Orbitals 1\u003c\/p\u003e \u003cp\u003e1.3 Molecular Orbitals 7\u003c\/p\u003e \u003cp\u003eProblems 13\u003c\/p\u003e \u003cp\u003eReferences 14\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 2 Concepts of Bonding and Orbital Interaction 15\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Orbital Interaction Energy 15\u003c\/p\u003e \u003cp\u003e2.1.1 Degenerate Interaction 16\u003c\/p\u003e \u003cp\u003e2.1.2 Nondegenerate Interaction 18\u003c\/p\u003e \u003cp\u003e2.2 Molecular Orbital Coefficients 20\u003c\/p\u003e \u003cp\u003e2.2.1 Degenerate Interaction 21\u003c\/p\u003e \u003cp\u003e2.2.2 Nondegenerate Interaction 22\u003c\/p\u003e \u003cp\u003e2.3 The Two-Orbital Problem—Summary 24\u003c\/p\u003e \u003cp\u003e2.4 Electron Density Distribution 26\u003c\/p\u003e \u003cp\u003eProblems 31\u003c\/p\u003e \u003cp\u003eReferences 31\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 3 Perturbational Molecular Orbital Theory 32\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 32\u003c\/p\u003e \u003cp\u003e3.2 Intermolecular Perturbation 35\u003c\/p\u003e \u003cp\u003e3.3 Linear H\u003csub\u003e3\u003c\/sub\u003e, HF, and the Three-Orbital Problem 38\u003c\/p\u003e \u003cp\u003e3.4 Degenerate Perturbation 43\u003c\/p\u003e \u003cp\u003eProblems 45\u003c\/p\u003e \u003cp\u003eReferences 46\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 4 Symmetry 47\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 47\u003c\/p\u003e \u003cp\u003e4.2 Symmetry of Molecules 47\u003c\/p\u003e \u003cp\u003e4.3 Representations of Groups 53\u003c\/p\u003e \u003cp\u003e4.4 Symmetry Properties of Orbitals 59\u003c\/p\u003e \u003cp\u003e4.5 Symmetry-Adapted Wavefunctions 62\u003c\/p\u003e \u003cp\u003e4.6 Direct Products 65\u003c\/p\u003e \u003cp\u003e4.7 Symmetry Properties, Integrals, and the Noncrossing Rule 67\u003c\/p\u003e \u003cp\u003e4.8 Principles of Orbital Construction Using Symmetry Principles 69\u003c\/p\u003e \u003cp\u003e4.9 Symmetry Properties of Molecular Vibrations 73\u003c\/p\u003e \u003cp\u003eProblems 75\u003c\/p\u003e \u003cp\u003eReferences 77\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 5 Molecular Orbital Construction from Fragment Orbitals 78\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 78\u003c\/p\u003e \u003cp\u003e5.2 Triangular H\u003csub\u003e3\u003c\/sub\u003e 78\u003c\/p\u003e \u003cp\u003e5.3 Rectangular and Square Planar H\u003csub\u003e4\u003c\/sub\u003e 82\u003c\/p\u003e \u003cp\u003e5.4 Tetrahedral H\u003csub\u003e4\u003c\/sub\u003e 84\u003c\/p\u003e \u003cp\u003e5.5 Linear H\u003csub\u003e4\u003c\/sub\u003e 86\u003c\/p\u003e \u003cp\u003e5.6 Pentagonal H\u003csub\u003e5\u003c\/sub\u003e and Hexagonal H\u003csub\u003e6\u003c\/sub\u003e 88\u003c\/p\u003e \u003cp\u003e5.7 Orbitals of Cyclic Systems 91\u003c\/p\u003e \u003cp\u003eProblems 94\u003c\/p\u003e \u003cp\u003eReferences 96\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 6 Molecular Orbitals of Diatomic Molecules and Electronegativity Perturbation 97\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 97\u003c\/p\u003e \u003cp\u003e6.2 Orbital Hybridization 98\u003c\/p\u003e \u003cp\u003e6.3 Molecular Orbitals of Diatomic Molecules 99\u003c\/p\u003e \u003cp\u003e6.4 Electronegativity Perturbation 105\u003c\/p\u003e \u003cp\u003e6.5 Photoelectron Spectroscopy and Through-Bond Conjugation 112\u003c\/p\u003e \u003cp\u003eProblems 118\u003c\/p\u003e \u003cp\u003eReferences 122\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 7 Molecular Orbitals and Geometrical Perturbation 123\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Molecular Orbitals of AH\u003csub\u003e2 \u003c\/sub\u003e123\u003c\/p\u003e \u003cp\u003e7.2 Geometrical Perturbation 128\u003c\/p\u003e \u003cp\u003e7.3 Walsh Diagrams 131\u003c\/p\u003e \u003cp\u003e7.4 Jahn–Teller Distortions 134\u003c\/p\u003e \u003cp\u003e7.4.1 First-Order Jahn–Teller Distortion 135\u003c\/p\u003e \u003cp\u003e7.4.2 Second-Order Jahn–Teller Distortion 136\u003c\/p\u003e \u003cp\u003e7.4.3 Three-Center Bonding 139\u003c\/p\u003e \u003cp\u003e7.5 Bond Orbitals and Photoelectron Spectra Of AH\u003csub\u003e2\u003c\/sub\u003e Molecules 141\u003c\/p\u003e \u003cp\u003eProblems 147\u003c\/p\u003e \u003cp\u003eReferences 150\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 8 State Wavefunctions and State Energies 151\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 151\u003c\/p\u003e \u003cp\u003e8.2 The Molecular Hamiltonian and State Wavefunctions 152\u003c\/p\u003e \u003cp\u003e8.3 Fock Operator 154\u003c\/p\u003e \u003cp\u003e8.4 State Energy 156\u003c\/p\u003e \u003cp\u003e8.5 Excitation Energy 157\u003c\/p\u003e \u003cp\u003e8.6 Ionization Potential and Electron Affinity 160\u003c\/p\u003e \u003cp\u003e8.7 Electron Density Distribution and Magnitudes of Coulomb and Exchange Repulsions 160\u003c\/p\u003e \u003cp\u003e8.8 Low versus High Spin States 162\u003c\/p\u003e \u003cp\u003e8.9 Electron–Electron Repulsion and Charged Species 164\u003c\/p\u003e \u003cp\u003e8.10 Configuration Interaction 165\u003c\/p\u003e \u003cp\u003e8.11 Toward More Quantitative Treatments 170\u003c\/p\u003e \u003cp\u003e8.12 The Density Functional Method 174\u003c\/p\u003e \u003cp\u003eProblems 176\u003c\/p\u003e \u003cp\u003eReferences 177\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 9 Molecular Orbitals of Small Building Blocks 179\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 179\u003c\/p\u003e \u003cp\u003e9.2 The AH System 179\u003c\/p\u003e \u003cp\u003e9.3 Shapes of AH\u003csub\u003e3 \u003c\/sub\u003eSystems 182\u003c\/p\u003e \u003cp\u003e9.4 \u003ci\u003e\u003cb\u003eπ\u003c\/b\u003e\u003c\/i\u003e-Bonding Effects of Ligands 190\u003c\/p\u003e \u003cp\u003e9.5 The AH\u003csub\u003e4\u003c\/sub\u003e System 193\u003c\/p\u003e \u003cp\u003e9.6 The AH\u003ci\u003e\u003csub\u003en\u003c\/sub\u003e\u003c\/i\u003e Series—Some Generalizations 198\u003c\/p\u003e \u003cp\u003eProblems 201\u003c\/p\u003e \u003cp\u003eReferences 202\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 10 Molecules with Two Heavy Atoms 204\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 204\u003c\/p\u003e \u003cp\u003e10.2 A\u003csub\u003e2\u003c\/sub\u003e H\u003csub\u003e6\u003c\/sub\u003e Systems 204\u003c\/p\u003e \u003cp\u003e10.3 12-Electron A\u003csub\u003e2\u003c\/sub\u003e H\u003csub\u003e4\u003c\/sub\u003e Systems 208\u003c\/p\u003e \u003cp\u003e10.3.1 Sudden Polarization 211\u003c\/p\u003e \u003cp\u003e10.3.2 Substituent Effects 214\u003c\/p\u003e \u003cp\u003e10.3.3 Dimerization and Pyramidalization of AH\u003csub\u003e 2 \u003c\/sub\u003e218\u003c\/p\u003e \u003cp\u003e10.4 14-Electron AH\u003csub\u003e2\u003c\/sub\u003e BH\u003csub\u003e2\u003c\/sub\u003e Systems 220\u003c\/p\u003e \u003cp\u003e10.5 AH\u003csub\u003e3\u003c\/sub\u003e BH\u003csub\u003e2\u003c\/sub\u003e Systems 223\u003c\/p\u003e \u003cp\u003e10.6 AH\u003csub\u003e3 \u003c\/sub\u003eBH Systems 232\u003c\/p\u003e \u003cp\u003eProblems 234\u003c\/p\u003e \u003cp\u003eReferences 238\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 11 Orbital Interactions through Space and through Bonds 241\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction 241\u003c\/p\u003e \u003cp\u003e11.2 In-Plane σ orbitals of Small Rings 241\u003c\/p\u003e \u003cp\u003e11.2.1 Cyclopropane 241\u003c\/p\u003e \u003cp\u003e11.2.2 Cyclobutane 246\u003c\/p\u003e \u003cp\u003e11.3 Through-Bond Interaction 253\u003c\/p\u003e \u003cp\u003e11.3.1 The Nature of Through-Bond Coupling 253\u003c\/p\u003e \u003cp\u003e11.3.2 Other Through-Bond Coupling Units 256\u003c\/p\u003e \u003cp\u003e11.4 Breaking a C–C Bond 258\u003c\/p\u003e \u003cp\u003eProblems 265\u003c\/p\u003e \u003cp\u003eReferences 269\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 12 Polyenes and Conjugated Systems 272\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e12.1 Acyclic Polyenes 272\u003c\/p\u003e \u003cp\u003e12.2 Hückel Theory 274\u003c\/p\u003e \u003cp\u003e12.3 Cyclic Systems 277\u003c\/p\u003e \u003cp\u003e12.4 Spin Polarization 285\u003c\/p\u003e \u003cp\u003e12.5 Low- versus High-Spin States in Polyenes 289\u003c\/p\u003e \u003cp\u003e12.6 Cross-Conjugated Polyenes 291\u003c\/p\u003e \u003cp\u003e12.7 Perturbations of Cyclic Systems 294\u003c\/p\u003e \u003cp\u003e12.8 Conjugation in Three Dimensions 303\u003c\/p\u003e \u003cp\u003eProblems 306\u003c\/p\u003e \u003cp\u003eReferences 310\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 13 Solids 313\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e13.1 Energy Bands 313\u003c\/p\u003e \u003cp\u003e13.2 Distortions in One-Dimensional Systems 328\u003c\/p\u003e \u003cp\u003e13.3 Other One-Dimensional Systems 334\u003c\/p\u003e \u003cp\u003e13.4 Two- and Three-Dimensional Systems 339\u003c\/p\u003e \u003cp\u003e13.5 Electron Counting and Structure 350\u003c\/p\u003e \u003cp\u003e13.6 High-Spin and Low-Spin Considerations 353\u003c\/p\u003e \u003cp\u003eProblems 353\u003c\/p\u003e \u003cp\u003eReferences 357\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 14 Hypervalent Molecules 359\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e14.1 Orbitals of Octahedrally Based Molecules 359\u003c\/p\u003e \u003cp\u003e14.2 Solid-State Hypervalent Compounds 373\u003c\/p\u003e \u003cp\u003e14.3 Geometries of Hypervalent Molecules 383\u003c\/p\u003e \u003cp\u003eProblems 392\u003c\/p\u003e \u003cp\u003eReferences 399\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 15 Transition Metal Complexes: A Starting Point at the Octahedron 401\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e15.1 Introduction 401\u003c\/p\u003e \u003cp\u003e15.2 Octahedral ML\u003csub\u003e6\u003c\/sub\u003e 402\u003c\/p\u003e \u003cp\u003e15.3 \u003ci\u003e\u003cb\u003eπ\u003c\/b\u003e\u003c\/i\u003e-Effects in an Octahedron 406\u003c\/p\u003e \u003cp\u003e15.4 Distortions from an Octahedral Geometry 416\u003c\/p\u003e \u003cp\u003e15.5 The Octahedron in the Solid State 423\u003c\/p\u003e \u003cp\u003eProblems 431\u003c\/p\u003e \u003cp\u003eReferences 434\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 16 Square Planar, Tetrahedral ML 4 Complexes, and Electron Counting 436\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e16.1 Introduction 436\u003c\/p\u003e \u003cp\u003e16.2 The Square Planar ML\u003csub\u003e4\u003c\/sub\u003e Molecule 436\u003c\/p\u003e \u003cp\u003e16.3 Electron Counting 438\u003c\/p\u003e \u003cp\u003e16.4 The Square Planar-Tetrahedral ML\u003csub\u003e4\u003c\/sub\u003e Interconversion 448\u003c\/p\u003e \u003cp\u003e16.5 The Solid State 453\u003c\/p\u003e \u003cp\u003eProblems 460\u003c\/p\u003e \u003cp\u003eReferences 463\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 17 Five Coordination 465\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e17.1 Introduction 465\u003c\/p\u003e \u003cp\u003e17.2 The C\u003csub\u003e4v\u003c\/sub\u003e M\u003csub\u003e5\u003c\/sub\u003e Fragment 466\u003c\/p\u003e \u003cp\u003e17.3 Five Coordination 468\u003c\/p\u003e \u003cp\u003e17.4 Molecules Built Up from ML\u003csub\u003e5\u003c\/sub\u003e Fragments 480\u003c\/p\u003e \u003cp\u003e17.5 Pentacoordinate Nitrosyls 489\u003c\/p\u003e \u003cp\u003e17.6 Square Pyramids in The Solid State 492\u003c\/p\u003e \u003cp\u003eProblems 498\u003c\/p\u003e \u003cp\u003eReferences 500\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 18 The C\u003csub\u003e2v\u003c\/sub\u003e ML\u003csub\u003e3 \u003c\/sub\u003eFragment 503\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e18.1 Introduction 503\u003c\/p\u003e \u003cp\u003e18.2 The Orbitals of A C\u003csub\u003e2v\u003c\/sub\u003e ML\u003csub\u003e3 \u003c\/sub\u003eFragment 503\u003c\/p\u003e \u003cp\u003e18.3 ML\u003csub\u003e3\u003c\/sub\u003e-Containing Metallacycles 511\u003c\/p\u003e \u003cp\u003e18.4 Comparison of C\u003csub\u003e2v\u003c\/sub\u003e ML\u003csub\u003e3\u003c\/sub\u003e and C\u003csub\u003e4v\u003c\/sub\u003e ML\u003csub\u003e5\u003c\/sub\u003e Fragments 518\u003c\/p\u003e \u003cp\u003eProblems 523\u003c\/p\u003e \u003cp\u003eReferences 525\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 19 The ML\u003csub\u003e2\u003c\/sub\u003e and ML\u003csub\u003e4\u003c\/sub\u003e Fragments 527\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e19.1 Development of the C\u003csub\u003e2v\u003c\/sub\u003e ML\u003csub\u003e4 \u003c\/sub\u003eFragment Orbitals 527\u003c\/p\u003e \u003cp\u003e19.2 The Fe(CO)\u003csub\u003e4\u003c\/sub\u003e Story 529\u003c\/p\u003e \u003cp\u003e19.3 Olefin–ML \u003csub\u003e4\u003c\/sub\u003e Complexes and M\u003csub\u003e2\u003c\/sub\u003e L\u003csub\u003e8\u003c\/sub\u003e Dimers 533\u003c\/p\u003e \u003cp\u003e19.4 The C\u003csub\u003e2v\u003c\/sub\u003e ML\u003csub\u003e2\u003c\/sub\u003e Fragment 537\u003c\/p\u003e \u003cp\u003e19.5 Polyene–ML\u003csub\u003e2\u003c\/sub\u003e Complexes 539\u003c\/p\u003e \u003cp\u003e19.6 Reductive Elimination and Oxidative Addition 552\u003c\/p\u003e \u003cp\u003eProblems 561\u003c\/p\u003e \u003cp\u003eReferences 566\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 20 Complexes of ML\u003csub\u003e3\u003c\/sub\u003e , MCp and Cp\u003csub\u003e2 \u003c\/sub\u003eM570\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e20.1 Derivation of Orbitals for a C\u003csub\u003e3v\u003c\/sub\u003e ML\u003csub\u003e3 \u003c\/sub\u003eFragment 570\u003c\/p\u003e \u003cp\u003e20.2 The CpM Fragment Orbitals 582\u003c\/p\u003e \u003cp\u003e20.3 Cp\u003csub\u003e2\u003c\/sub\u003e M and Metallocenes 592\u003c\/p\u003e \u003cp\u003e20.4 Cp\u003csub\u003e2\u003c\/sub\u003e ML\u003ci\u003e\u003csub\u003en\u003c\/sub\u003e\u003c\/i\u003e Complexes 595\u003c\/p\u003e \u003cp\u003eProblems 607\u003c\/p\u003e \u003cp\u003eReferences 613\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 21 The Isolobal Analogy 616\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e21.1 Introduction 616\u003c\/p\u003e \u003cp\u003e21.2 Generation of Isolobal Fragments 617\u003c\/p\u003e \u003cp\u003e21.3 Caveats 621\u003c\/p\u003e \u003cp\u003e21.4 Illustrations of the Isolobal Analogy 623\u003c\/p\u003e \u003cp\u003e21.5 Reactions 634\u003c\/p\u003e \u003cp\u003e21.6 Extensions 639\u003c\/p\u003e \u003cp\u003eProblems 646\u003c\/p\u003e \u003cp\u003eReferences 649\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 22 Cluster Compounds 653\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e22.1 Types of Cluster Compounds 653\u003c\/p\u003e \u003cp\u003e22.2 Cluster Orbitals 657\u003c\/p\u003e \u003cp\u003e22.3 Wade’s Rules 660\u003c\/p\u003e \u003cp\u003e22.4 Violations 671\u003c\/p\u003e \u003cp\u003e22.5 Extensions 677\u003c\/p\u003e \u003cp\u003eProblems 681\u003c\/p\u003e \u003cp\u003eReferences 687\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 23 Chemistry on the Surface 691\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e23.1 Introduction 691\u003c\/p\u003e \u003cp\u003e23.2 General Structural Considerations 693\u003c\/p\u003e \u003cp\u003e23.3 General Considerations of Adsorption on Surfaces 696\u003c\/p\u003e \u003cp\u003e23.4 Diatomics on a Surface 699\u003c\/p\u003e \u003cp\u003e23.5 The Surface of Semiconductors 721\u003c\/p\u003e \u003cp\u003eProblems 728\u003c\/p\u003e \u003cp\u003eReferences 731\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 24 Magnetic Properties 735\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e24.1 Introduction 735\u003c\/p\u003e \u003cp\u003e24.2 The Magnetic Insulating State 736\u003c\/p\u003e \u003cp\u003e24.2.1 Electronic Structures 736\u003c\/p\u003e \u003cp\u003e24.2.2 Factors Affecting the Effective On-Site Repulsion 738\u003c\/p\u003e \u003cp\u003e24.2.3 Effect of Spin Arrangement on the Band Gap 740\u003c\/p\u003e \u003cp\u003e24.3 Properties Associated with the Magnetic Moment 741\u003c\/p\u003e \u003cp\u003e24.3.1 The Magnetic Moment 741\u003c\/p\u003e \u003cp\u003e24.3.2 Magnetization 743\u003c\/p\u003e \u003cp\u003e24.3.3 Magnetic Susceptibility 743\u003c\/p\u003e \u003cp\u003e24.3.4 Experimental Investigation of Magnetic Energy Levels 745\u003c\/p\u003e \u003cp\u003e24.4 Symmetric Spin Exchange 745\u003c\/p\u003e \u003cp\u003e24.4.1 Mapping Analysis for a Spin Dimer 745\u003c\/p\u003e \u003cp\u003e24.4.2 Through-Space and Through-Bond Orbital Interactions Leading to Spin Exchange 748\u003c\/p\u003e \u003cp\u003e24.4.3 Mapping Analysis Based on Broken-Symmetry States 751\u003c\/p\u003e \u003cp\u003e24.5 Magnetic Structure 754\u003c\/p\u003e \u003cp\u003e24.5.1 Spin Frustration and Noncollinear Spin Arrangement 754\u003c\/p\u003e \u003cp\u003e24.5.2 Long-Range Antiferromagnetic Order 755\u003c\/p\u003e \u003cp\u003e24.5.3 Ferromagnetic and Ferromagnetic-Like Transitions 759\u003c\/p\u003e \u003cp\u003e24.5.4 Typical Cases Leading to Ferromagnetic Interaction 760\u003c\/p\u003e \u003cp\u003e24.5.5 Short-Range Order 763\u003c\/p\u003e \u003cp\u003e24.6 The Energy Gap in the Magnetic Energy Spectrum 763\u003c\/p\u003e \u003cp\u003e24.6.1 Spin Gap and Field-Induced Magnetic Order 763\u003c\/p\u003e \u003cp\u003e24.6.2 Magnetization Plateaus 765\u003c\/p\u003e \u003cp\u003e24.7 Spin–Orbit Coupling 766\u003c\/p\u003e \u003cp\u003e24.7.1 Spin Orientation 766\u003c\/p\u003e \u003cp\u003e24.7.2 Single-Ion Anisotropy 770\u003c\/p\u003e \u003cp\u003e24.7.3 Uniaxial Magnetism versus Jahn–Teller Instability 771\u003c\/p\u003e \u003cp\u003e24.7.4 The Dzyaloshinskii–Moriya Interaction 774\u003c\/p\u003e \u003cp\u003e24.7.5 Singlet–Triplet Mixing Under Spin–Orbit Coupling 777\u003c\/p\u003e \u003cp\u003e24.8 What Appears versus What Is 778\u003c\/p\u003e \u003cp\u003e24.8.1 Idle Spin in Cu\u003csub\u003e3\u003c\/sub\u003e(OH)\u003csub\u003e4\u003c\/sub\u003eSO\u003csub\u003e4\u003c\/sub\u003e 778\u003c\/p\u003e \u003cp\u003e24.8.2 The FM–AFM versus AFM–AFM Chain 779\u003c\/p\u003e \u003cp\u003e24.8.3 Diamond Chains 780\u003c\/p\u003e \u003cp\u003e24.8.4 Spin Gap Behavior of a Two-Dimensional Square Net 782\u003c\/p\u003e \u003cp\u003e24.9 Model Hamiltonians Beyond the Level of Spin Exchange 785\u003c\/p\u003e \u003cp\u003e24.10 Summary Remarks 785\u003c\/p\u003e \u003cp\u003eProblems 786\u003c\/p\u003e \u003cp\u003eReferences 789\u003c\/p\u003e \u003cp\u003eAppendix I Perturbational Molecular Orbital Theory 793\u003c\/p\u003e \u003cp\u003eAppendix II Some Common Group Tables 803\u003c\/p\u003e \u003cp\u003eAppendix III Normal Modes for Some Common Structural Types 808\u003c\/p\u003e \u003cp\u003eIndex 813\u003c\/p\u003e\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eSubject Areas: Chemistry [\u003ca title=\"See our other books on Chemistry\" href=\"https:\/\/freshlyprintedbooks.co.uk\/search?q=%22Chemistry%20%5BPN%5D%22\"\u003ePN\u003c\/a\u003e]\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\u003c\/font\u003e","brand":"Wiley-Interscience","offers":[{"title":"Brand New","offer_id":52501198405912,"sku":"9780471080398","price":121.99,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0730\/2037\/5320\/files\/9780471080398.jpg?v=1786216619","url":"https:\/\/freshlyprintedbooks.co.uk\/products\/orbital-interactions-in-chemistry-hardback-9780471080398","provider":"Freshly Printed Books","version":"1.0","type":"link"}