{"product_id":"olefin-metathesis-and-metathesis-polymerization-hardback-9780123770455","title":"Olefin Metathesis and Metathesis Polymerization (Hardback) 9780123770455","description":"\u003cfont face=\"Georgia\"\u003e\r\n\u003cp\u003e\u003cfont size=\"6\"\u003eOlefin Metathesis and Metathesis Polymerization\u003c\/font\u003e\u003cbr\u003e\r\n\r\n\r\n\r\n\r\n\r\n\u003c\/p\u003e\n\u003cp\u003e\u003cfont size=\"4\"\u003eK. J. Ivin (Author), J. C. Mol (Author)\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e9780123770455, Elsevier Science\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eHardback, published 7 January 1997\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e496 pages\u003cbr\u003e22.9 x 15.1 x 3 cm, 0.84 kg\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\r\n\u003cp align=\"justify\"\u003e\u003cem\u003e\u003cfont size=\"3\"\u003e\u003cp\u003e\"Coverage of the literature is up-to-date...,and the book is very well indexed; there is no difficulty in finding your way to a topic of interest. As a document of an important branch of organometallic chemistry, this book is complete and should satisfy all chemists with an interest in olefin metathesis and related reactions.\" \u003cb\u003e--JOURNAL OF AMERICAN CHEMISTRY SOCIETY\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\"Any reader wishing to know anything about olefin matathesis and metathesis polymerization cannot do better than start with this excellant monograph. . . Nobody active in the area can afford to be without this monograph and any library which serves a research community interest in catalysis, organic synthesis and polymer science and technology will need this book on its shelves.\" \u003cb\u003e--POLYMER INTERNATIONAL, Vol. 45, 1998\u003c\/b\u003e\u003c\/p\u003e\u003c\/font\u003e\u003c\/em\u003e\u003c\/p\u003e\r\n\r\n\u003cp align=\"justify\"\u003e\u003cstrong\u003e\u003cfont size=\"3\"\u003e\u003cp\u003eThis book is a follow-up to Ivins \u003ci\u003eOlefin Metathesis\u003c\/i\u003e, (Academic Press, 1983). Bringing the standard text in the field up to date, this Second Edition is a result of rapid growth in the field, sparked by the discovery of numerous well-defined metal carbene complexes that can act as very efficient initiators of all types of olefin metathesis reaction, including ring-closing metathesis of acyclic dienes, enynes, and dienynes; ring-opening metathesis polymerizationof cycloalkenes, acyclic diene metathesis polymerization; and polymerization of alkynes, as well as simple olefin metathesis.\u003c\/p\u003e  \u003cp\u003e\u003ci\u003eOlefin Metathesis and Metathesis Polymerization\u003c\/i\u003e provides a broad, up-to-date account of the subject from its beginnings in 1957 to the latest applications in organic synthesis. The book follows the same format as the original, making it useful toteachers and to researchers, and will be of particular interest to those working in the fields of organic chemistry, polymer chemistry, organometallic chemistry, catalysis, materials science and chemical engineering.\u003c\/p\u003e\u003c\/font\u003e\u003c\/strong\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003ePreface. Abbreviations. \u003cb\u003eIntroduction:\u003c\/b\u003e The Olefin Metathesis Reaction. Brief History. The Metal Carbene Mechanism. Equilibria and Stereoselectivity. \u003cb\u003eSurvey of Catalyst Systems:\u003c\/b\u003e Group IV. Group V. GroupVI. Group VII. Group VIII. Photochemically Activated Catalysts. \u003cb\u003eThe Metal Carbene\/Metallacyclobutane Mechanism:\u003c\/b\u003e Evidence from Cross-Metathesis Reactions. Evidence from the Stereochemistry of Metathesis of Internal Olefins. Evidence from Ring-Opening Metathesis Polymerization (ROMP). Evidence from the reactions of Well-Defined Metal Carbene Complexes. Evidence from the Reactions of Metallacyclobutane Complexes. Evidence of Initiating Species in Systems with Non-Carbene Catalysts. Theoretical Treatments. \u003cb\u003eRelated Reactions:\u003c\/b\u003e [2+2] Reactions Between Compounds Containing Multiple Bonds. Relationship to Ziegler-Natta Polymerization. Involvement of Three-Membered Ring Compounds in Metathesis Reactions. \u003cb\u003eEthene and Terminal Alkenes:\u003c\/b\u003e Ethene. Propene. But-1-ene and its Derivatives. Pent-1-ene and its Derivatives. Hex-1-ene and its Derivatives. Higher Acyclic Terminal Alkenes. \u003cb\u003eAcyclic Disubstituted and Trisubstituted Ethenes. Cis\/trans\u003c\/b\u003e Isomerization. Pent-2-ene and 4-Substituted Derivatives. Hex-2-ene and 4-Methylhex-2-ene.Hept-2-ene and Hept-3-ene. Higher Acyclic Internal Olefins. Stereoselectivity in the Metathesis of Acyclic Olefins. 1,1-Disubstituted Olefins. Trisubstituted Ethenes. \u003cb\u003eAcyclic Functionalized Alkenes:\u003c\/b\u003e Esters. Other Carbonyl-Containing Compounds. Ethers. Amines. Nitriles. Chlorides and Bromides. Sulfides and Sulfonates. Silancs and Germanes. Phospanes. \u003cb\u003eAcyclic Dienes:\u003c\/b\u003e Double Bonds Linked only by C Atoms. Double Bonds Linked by C and Si, Ge orSn Atoms. Double Bonds Linked by C and N Atoms. Double Bonds Linked by C, Si, and O Atoms. Divinylferrocene. Some Further Applications in Organic Synthesis. Copolymers by Metathesis Condensation. \u003cb\u003eCross-Metathesis Between Acyclic Compounds:\u003c\/b\u003e Ethene.Propene. Butenes. Pentenes. Hexenes. Higher Olefins. Functionalized Olefins. \u003cb\u003eAcetylenes:\u003c\/b\u003e Metathesis Reactions Involving Total Cleavage of the C=C bond. Metathesis Reactions Involving Cleavage of Two of the thress C=C Bonds. Metathesis Reactions of Enynes and Dienynes. Other Metathesis Routes to Polyacetylenes. \u003cb\u003eRing-Opening Metathesis Polymerization: General Aspects:\u003c\/b\u003e Thermodynamic Aspects. Efficiency of Initiation. The Use of Chain-Transfer Agents. Molecular Weight Distributions. Polymer Micostructure. \u003cb\u003eMonocyclic Alkenes and Polyenes:\u003c\/b\u003e Four-Membered Rings. Five-Membered Rings. Six-Membered Rings. Seven-Membered Rings. Eight-Membered Rings. Nine-Membered Rings. Ten-Membered Rings. Twelve-Membered and Other Rings. \u003cb\u003ePolycyclic Alkenes:\u003c\/b\u003e Monomers Containing a Fused Cyclobutene Ring. Monomers Containing a Fused Cyclopentene Ring and One Double Bond. Monomers Containing a Fused Cyclopentene Ring and More than One Double Bond. Bicyclo[2.2.1] Compounds Containing Heteroatoms in the Ring System. Other Bicyclic Compounds. \u003cb\u003eCopolymers of Cycloalkenes:\u003c\/b\u003e Direct Metathesis Copolymerization. Cyclic Co-Oligomers. Block Copolymers by Sequential Addition of Monomers to Living Systems. Block Copolymers by Modification of Homopolymers. Comb and GraftCopolymers. Copolymers by ROMP in Conjunction with Radical Reactions. \u003cb\u003eCross-Metathesis Between Cyclic and Acyclic Olefins:\u003c\/b\u003e End-Groups and Telomers. Dependence of Molecular Weight on [M2]\/[M1]. Kinetic Data. \u003cb\u003eDegradation of UnsaturatedPolymers by Metathesis:\u003c\/b\u003e Degradation by Intramolecular Metathesis. \u003cb\u003eApplications of the Olefin Metathesis Reaction:\u003c\/b\u003e The Phillips Triolefin Process. The Neohexene Process. The Shell Higher Olefins Process. Other Multistage Processes Involving Metathesis. The Isoamylene Process. (\u003cb\u003eCircle around alpha and omega\u003c\/b\u003e) ((-Diolefins. \u003ci\u003etrans\u003c\/i\u003e-Poly(1-Pentenylene). \u003ci\u003etrans\u003c\/i\u003e-Poly(1-octenylene). Polymers of Norhornene. Polymers of Norbornene Derivatives. Miscellaneous. Bibliography. Subject Index.\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eSubject Areas: Plastics \u0026amp; polymers technology [\u003ca title=\"See our other books on Plastics \u0026amp; polymers technology\" href=\"https:\/\/freshlyprintedbooks.co.uk\/search?q=%22Plastics%20\u0026amp;%20polymers%20technology%20%5BTDCP%5D%22\"\u003eTDCP\u003c\/a\u003e], Physical chemistry [\u003ca title=\"See our other books on Physical chemistry\" href=\"https:\/\/freshlyprintedbooks.co.uk\/search?q=%22Physical%20chemistry%20%5BPNR%5D%22\"\u003ePNR\u003c\/a\u003e], Organic chemistry [\u003ca title=\"See our other books on Organic chemistry\" href=\"https:\/\/freshlyprintedbooks.co.uk\/search?q=%22Organic%20chemistry%20%5BPNN%5D%22\"\u003ePNN\u003c\/a\u003e]\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\u003c\/font\u003e","brand":"Academic Press","offers":[{"title":"Default Title","offer_id":46649308414232,"sku":"9780123770455","price":109.49,"currency_code":"GBP","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0730\/2037\/5320\/products\/9780123770455.jpg?v=1695013982","url":"https:\/\/freshlyprintedbooks.co.uk\/products\/olefin-metathesis-and-metathesis-polymerization-hardback-9780123770455","provider":"Freshly Printed Books","version":"1.0","type":"link"}