{"product_id":"hypervalent-iodine-in-organic-synthesis-hardback-9780127149752","title":"Hypervalent Iodine in Organic Synthesis (Hardback) 9780127149752","description":"\u003cfont face=\"Georgia\"\u003e\r\n\u003cp\u003e\u003cfont size=\"6\"\u003eHypervalent Iodine in Organic Synthesis\u003c\/font\u003e\u003cbr\u003e\r\n\r\n\r\n\r\n\r\n\r\n\u003c\/p\u003e\n\u003cp\u003e\u003cfont size=\"4\"\u003eA. Varvoglis (Author), O. Meth-Cohn (Series edited by), Alan R. Katritzky (Series edited by), C. S. Rees (Series edited by)\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e9780127149752, Elsevier Science\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eHardback, published 14 November 1996\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e223 pages\u003cbr\u003e22.9 x 15.1 x 2 cm, 0.49 kg\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\r\n\u003cp align=\"justify\"\u003e\u003cem\u003e\u003cfont size=\"3\"\u003e\"I suspect there will be no synthetic chemist who, after reading this book, will not try to include the valuable hypervalent iodine reagents in their synthetic plans.\" \u003cb\u003e--Andrew N. Boa in CHEMISTRY IN BRITAIN\u003c\/b\u003e\u003c\/font\u003e\u003c\/em\u003e\u003c\/p\u003e\r\n\r\n\u003cp align=\"justify\"\u003e\u003cstrong\u003e\u003cfont size=\"3\"\u003e\u003cp\u003eThis book describes the fascinating chemistry of the many kinds of organic compounds of hypervalent iodine. Each chapter deals with a particular iodine compound or families of compounds which have been used as reagents in a plethora of useful transformations. These include assorted oxidation, such as with the precious Dess-Martin reagent as well as with a wide range of further reactions.\u003c\/p\u003e  \u003cp\u003eProminent features of hypervalent iodine reagents derived from iodobenzene are: ready availability, operational simplicity, mild reaction conditions, and high efficiency. They are environmentally safe and can be recycled. New species may be easily prepared by introducing substituents in the benzene ring or changing the ligand attached to iodine. Their combination with other reagents broadens considerably their synthetic potential. Today, no synthetic chemist can afford to ignore the valuable hypervalentiodine reagents.\u003c\/p\u003e\u003c\/font\u003e\u003c\/strong\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eForeword. Preface. General Considerations. Preparative Methods for Hypervalent Iodine Reagents. (Diacetoxyiodo)benzene. [Bis(acyloxy)iodo]arenes. Iodosylbenzene. (Difluoroiodo)-and (dichloroiodo)arenes. [Hydroxy(tosyloxy)iodo]benzene and Its Analogues. Diaryliodonium Salts. Phenyliodonium Salts with an Aliphatic Moiety. Phenyliodonium Zwitterions. Reagents of Iodine (V). Some Further Reagents of Iodine (lll). Index of Compounds and Methods. Subject Index.Foreword. Preface. \u003cb\u003eGeneral Considerations:\u003c\/b\u003e Introduction. A Note on Classes and Nomenclature. Bonding and Structure in Hypervalent Iodine. Reactivity Patterns. Practical Aspects. General References. \u003cb\u003ePreparative Methods for Hypervalent Iodine Reagents:\u003c\/b\u003e [Bis(acyloxy)iodo]arenes. (Difluoroiodo)- and (dichloroiodo)arenes. Iodosylarenes. [Hydroxy(iosyloxy)iodo]benzene and its Analogues. Reagents of Iodine (V). \u003cb\u003e(Diacetoxyiodo)benzene:\u003c\/b\u003e Acetoxylation. Transformations of Carbonyl Compounds. Phenolic Oxidation. Oxidation of Nitrogen Compounds. Hypervalent iodine Reagents in Combination with Azido Compounds. DIB and Sodium Azide in Combination with Other Reagents. Transformations of Alkynes Involving Thiophenols and Diphenyl Diselenide. Miscellaneous Reactions. \u003cb\u003e[Bis(acyloxy)iodo]arenes:\u003c\/b\u003e Part A: Reactions with [bis(trifluoroacetoxy)iodo]benzene. Transformations of Alkynes. Transformations of Ketones. Phenolic Oxidation. Oxidation of Nitrogen Compounds. Transfomration of Sulfur Compounds. Miscellaneous Transformations. Part B: Reactions with [bis(acyloxy)iodo]arenes. Oxidations. Homolytic Alkylation and Arylation. \u003cb\u003eIodosylbenzene:\u003c\/b\u003e Reactions with Unsaturated Compounds. Reactions with Alcohols and Carbonyl Compounds. Reactions with NitrogenCompounds. Reactions with Sulfur and Other Compounds. \u003cb\u003e(Difluoroiodo)-and (dichloroiodo)arenes:\u003c\/b\u003e Chlorination. Remote Functionalism, of Steroids. Fluorination. Further Transformations. \u003cb\u003e[Hydroxy(tosyloxy)iodo]benzene and Its Analogues:\u003c\/b\u003e Reactionswith Alkenes and Allenes. Reactions with Alkynes and Alcohols. Reactions with Keto Compounds. Reactions with Nitrogen, Sulfur, and Other compounds. \u003cb\u003eDiaryliodonium Salts:\u003c\/b\u003e Preparative Methods. Carbon-Carbon Bond-Forming Reactions. Arylation of Heteroatoms. \u003cb\u003ePhenyliodonium Salts with an Aliphatic Moiety:\u003c\/b\u003e Preparative Methods. Reactivity of Perfluoroalkyl Phenyliodonium Salts. Reactivity of Other Iodonium Salts. \u003cb\u003ePhenyliodonium Zwitterions:\u003c\/b\u003e Preparation. Reactivity of Iodine-Carbon Ylides. Reactivity of Iodine-Nitrogen Ylides. Reactivity of 1,4-dipoles. \u003cb\u003eReagents of Iodine)V_:\u003c\/b\u003e Reactions with Iodylarenes. Reactions with Dess-Martin Reagent and \u003ci\u003eo\u003c\/i\u003e-iodylbenzoic Acid. \u003cb\u003eSome Further Reagents of Iodine (III):\u003c\/b\u003e \u003ci\u003eo\u003c\/i\u003e-Iodosylbenzoic Acid and Its Derivatives. Reagents with Iodine-Oxygen Bonds. Reagents with Iodine-Nitrogen Bonds. Index of Compounds and Methods. Subject Index.\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eSubject Areas: Organic chemistry [\u003ca title=\"See our other books on Organic chemistry\" href=\"https:\/\/freshlyprintedbooks.co.uk\/search?q=%22Organic%20chemistry%20%5BPNN%5D%22\"\u003ePNN\u003c\/a\u003e]\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\u003c\/font\u003e","brand":"Academic Press","offers":[{"title":"Default Title","offer_id":46649434898712,"sku":"9780127149752","price":112.69,"currency_code":"GBP","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0730\/2037\/5320\/products\/9780127149752.jpg?v=1694100951","url":"https:\/\/freshlyprintedbooks.co.uk\/products\/hypervalent-iodine-in-organic-synthesis-hardback-9780127149752","provider":"Freshly Printed Books","version":"1.0","type":"link"}