{"product_id":"guidelines-for-chemical-reactivity-evaluation-and-application-to-process-design-hardback-9780816904792","title":"Guidelines for Chemical Reactivity Evaluation and Application to Process Design (Hardback) 9780816904792","description":"\u003cfont face=\"Georgia\"\u003e\r\n\u003cp\u003e\u003cfont size=\"6\"\u003eGuidelines for Chemical Reactivity Evaluation and Application to Process Design\u003c\/font\u003e\u003cbr\u003e\r\n\r\n\r\n\r\n\r\n\r\n\u003c\/p\u003e\n\u003cp\u003e\u003cfont size=\"4\"\u003eCCPS (Author)\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e9780816904792, Wiley\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eHardback, published 1 April 1995\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e238 pages\u003cbr\u003e23.9 x 16.4 x 1.8 cm, 0.494 kg\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\r\n\r\n\r\n\u003cp align=\"justify\"\u003e\u003cstrong\u003e\u003cfont size=\"3\"\u003eDrawn from international sources, this book provides principles and strategies for the evaluation of chemical reactions, and for using this information in process design and management. A useful resource for engineers who design, start-up, operate, and manage chemical and petrochemical plants, the book places special emphasis on the use of state-of-the-art technology in theory, testing methods, and applications in design and operations.\u003c\/font\u003e\u003c\/strong\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e\u003cb\u003eList of Tables.\u003c\/b\u003e  \u003cp\u003e\u003cb\u003eList of Figures.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePreface.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eAcknowledgments.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eGlossary.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eList of Symbols.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 1. Introduction\u003c\/b\u003e.\u003c\/p\u003e \u003cp\u003e1.1. General.\u003c\/p\u003e \u003cp\u003e1.2. Chemical Reactivity.\u003c\/p\u003e \u003cp\u003e1.3. Detonations, Deflagrations, and Runaways.\u003c\/p\u003e \u003cp\u003e1.4. Assessment and Testing Strategies.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 2. Identification of Hazardous Chemical Reactivity.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1. Summary\/Strategy.\u003c\/p\u003e \u003cp\u003e2.1.1. Introduction.\u003c\/p\u003e \u003cp\u003e2.1.2. Hazard Identification Strategy.\u003c\/p\u003e \u003cp\u003e2.1.3. Exothermic Reactions.\u003c\/p\u003e \u003cp\u003e2.1.4. Experimental Thermal and Reactivity Measurements.\u003c\/p\u003e \u003cp\u003e2.1.5. Test Strategies.\u003c\/p\u003e \u003cp\u003e2.1.6. Overview of Thermal Stability Test methods.\u003c\/p\u003e \u003cp\u003e2.1.7. Examples of Interpretation and Application of Test Data.\u003c\/p\u003e \u003cp\u003e2.2. Technical Section.\u003c\/p\u003e \u003cp\u003e2.2.2. Identification of High Energy Substances.\u003c\/p\u003e \u003cp\u003e2.2.3. Hazard Prediction by Thermodynamic Calculations.\u003c\/p\u003e \u003cp\u003e2.2.3.1. Oxygen Balance.\u003c\/p\u003e \u003cp\u003e2.2.3.2. Calculation of the Reaction Enthalpy.\u003c\/p\u003e \u003cp\u003e2.2.3.3. Application of Computer Programs.\u003c\/p\u003e \u003cp\u003e2.2.4. Instability\/Incompatibility Factors.\u003c\/p\u003e \u003cp\u003e2.2.4.1. Factors Influencing Stability.\u003c\/p\u003e \u003cp\u003e2.2.4.2. Redox Systems.\u003c\/p\u003e \u003cp\u003e2.2.4.3. Reactions with Water.\u003c\/p\u003e \u003cp\u003e2.2.4.4. Reactions between Halogenated Hydrocarbons and Metals.\u003c\/p\u003e \u003cp\u003e2.3. Practical Testing.\u003c\/p\u003e \u003cp\u003e2.3.1. Screening Tests.\u003c\/p\u003e \u003cp\u003e2.3.1.1. Thermal Analysis.\u003c\/p\u003e \u003cp\u003e2.3.1.2. Isoperibolic Calorimetry.\u003c\/p\u003e \u003cp\u003e2.3.2. Thermal Stability and Runaway Testing.\u003c\/p\u003e \u003cp\u003e2.3.2.1. Isothermal Storage Tests.\u003c\/p\u003e \u003cp\u003e2.3.2.2. Dewar Flask Testing and Adiabatic Storage Tests.\u003c\/p\u003e \u003cp\u003e2.3.2.3. Accelerating Rate Calorimeter (ARC).\u003c\/p\u003e \u003cp\u003e2.3.2.4. Stability Tests for Powders.\u003c\/p\u003e \u003cp\u003e2.3.3. Explosibility Testing.\u003c\/p\u003e \u003cp\u003e2.3.3.1.Detonation Testing.\u003c\/p\u003e \u003cp\u003e2.3.3.2. Deflagration Testing and Autoclave Testing.\u003c\/p\u003e \u003cp\u003e2.3.3.3. Mechanical Sensitivity Testing.\u003c\/p\u003e \u003cp\u003e2.3.3.4. Sensitivity to heating Under Confinement.\u003c\/p\u003e \u003cp\u003e2.3.4. Reactivity Testing.\u003c\/p\u003e \u003cp\u003e2.3.4.1. Pyrophoric Properties.\u003c\/p\u003e \u003cp\u003e2.3.4.2. Reactivity with Water.\u003c\/p\u003e \u003cp\u003e2.3.4.3. Oxidizing Properties.\u003c\/p\u003e \u003cp\u003e2.3.5. Flammability Testing.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 3. Chemical Reactivity Considerations in Process\/Reactor Design and Operation.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1. Introduction.\u003c\/p\u003e \u003cp\u003e3.1.1. Thermal Hazards: Identification and Analysis.\u003c\/p\u003e \u003cp\u003e3.1.1.1. Cause, Definition, and Prevention of a Runaway.\u003c\/p\u003e \u003cp\u003e3.1.1.2. Some Simple Rules for Inherent Safety.\u003c\/p\u003e \u003cp\u003e3.1.1.3. Strategy for Inherent Safety in Design and Operation.\u003c\/p\u003e \u003cp\u003e3.1.1.4. Equipment to be Used for the Analysis of Hazards.\u003c\/p\u003e \u003cp\u003e3.2. Reactor, Heat and Mass Balance Considerations.\u003c\/p\u003e \u003cp\u003e3.2.1. Heat and Mass Balances, Kinetics, and Reaction Stability.\u003c\/p\u003e \u003cp\u003e3.2.1.1. Adiabatic Temperature Rise.\u003c\/p\u003e \u003cp\u003e3.2.1.2. The Reaction.\u003c\/p\u003e \u003cp\u003e3.2.1.3. Reaction Rate.\u003c\/p\u003e \u003cp\u003e3.2.1.4. Reaction Rate Constant.\u003c\/p\u003e \u003cp\u003e3.2.1.5. Concentration of Reactants.\u003c\/p\u003e \u003cp\u003e3.2.1.6. Effect of Surrounding Temperature on Stability.\u003c\/p\u003e \u003cp\u003e3.2.1.7. Effect of Agitation and Surface Fouling on Stability.\u003c\/p\u003e \u003cp\u003e3.2.1.8. Mass Balance.\u003c\/p\u003e \u003cp\u003e3.2.2. Choice of Reactor.\u003c\/p\u003e \u003cp\u003e3.2.3. Heat Transfer.\u003c\/p\u003e \u003cp\u003e3.2.3.1. Heat Transfer in Nonagitated Vessels.\u003c\/p\u003e \u003cp\u003e3.2.3.2. Heat Transfer in Agitated Vessels.\u003c\/p\u003e \u003cp\u003e3.3. Acquisition and Use of Process Design data.\u003c\/p\u003e \u003cp\u003e3.3.1. Introduction.\u003c\/p\u003e \u003cp\u003e3.3.2. Bench-Scale Equipment for Batch\/Tank Reactors.\u003c\/p\u003e \u003cp\u003e3.3.2.1. Reaction Calorimeter (RC1).\u003c\/p\u003e \u003cp\u003e3.3.2.2. Contalab.\u003c\/p\u003e \u003cp\u003e3.3.2.3. CPA ThermoMetric Instruments.\u003c\/p\u003e \u003cp\u003e3.3.2.4. Quantitative Reaction Calorimeter.\u003c\/p\u003e \u003cp\u003e3.3.2.5. Specialized Rectors.\u003c\/p\u003e \u003cp\u003e3.3.2.6. Vent Size Package (VSP).\u003c\/p\u003e \u003cp\u003e3.3.2.7. Reactive System Screening Tool (RSST).\u003c\/p\u003e \u003cp\u003e3.3.3. Process Safety for Reactive Systems.\u003c\/p\u003e \u003cp\u003e3.3.3.1. Test Plan.\u003c\/p\u003e \u003cp\u003e3.3.3.2. System Under Investigation.\u003c\/p\u003e \u003cp\u003e3.3.3.3. Test Results.\u003c\/p\u003e \u003cp\u003e3.3.3.4. Malfunction and Process Deviation Testing.\u003c\/p\u003e \u003cp\u003e3.3.3.5. Pressure Effect.\u003c\/p\u003e \u003cp\u003e3.3.3.6. Results from the ARC, RSST, and VSP.\u003c\/p\u003e \u003cp\u003e3.3.4. Scale-up and Pilot Plants.\u003c\/p\u003e \u003cp\u003e3.3.4.1. General Remarks.\u003c\/p\u003e \u003cp\u003e3.3.4.2. Chemical Kinetics.\u003c\/p\u003e \u003cp\u003e3.3.4.3. Mass Transfer\/Mixing.\u003c\/p\u003e \u003cp\u003e3.3.4.4. Heat Transfer.\u003c\/p\u003e \u003cp\u003e3.3.4.5. Self-Heating.\u003c\/p\u003e \u003cp\u003e3.3.4.6. Scale-Up of Accelerating Rate Calorimeter (ARC) Results.\u003c\/p\u003e \u003cp\u003e3.3.4.7. Scale-Up of Vent Size Package (VSP) Results.\u003c\/p\u003e \u003cp\u003e3.3.5. Process Design Applications.\u003c\/p\u003e \u003cp\u003e3.3.5.1. Batch and Semi-Batch Processing Plants.\u003c\/p\u003e \u003cp\u003e3.3.5.2. An Example Involving Peroxides.\u003c\/p\u003e \u003cp\u003e3.3.5.3. An Example Involving a Continuous Nitration.\u003c\/p\u003e \u003cp\u003e3.3.5.4. A Self-Heating Example.\u003c\/p\u003e \u003cp\u003e3.3.5.5. Batch-to-Continuous Example\u003c\/p\u003e \u003cp\u003e3.3.5.6. Integrated Relief Evaluation.\u003c\/p\u003e \u003cp\u003e3.3.6. Storage and Handling.\u003c\/p\u003e \u003cp\u003e3.3.6.1. Scale-Up Example for Storage.\u003c\/p\u003e \u003cp\u003e3.3.6.2. Peroxides.\u003c\/p\u003e \u003cp\u003e3.3.6.3. Passive Means to Prevent Explosions.\u003c\/p\u003e \u003cp\u003e3.3.7. Dryers and Filters.\u003c\/p\u003e \u003cp\u003e3.4. Protective Measures.\u003c\/p\u003e \u003cp\u003e3.4.1. Containment.\u003c\/p\u003e \u003cp\u003e3.4.1.1. Introduction.\u003c\/p\u003e \u003cp\u003e3.4.1.2. Determination of Gas-Vapor Release.\u003c\/p\u003e \u003cp\u003e3.4.1.3. Laboratory Scale.\u003c\/p\u003e \u003cp\u003e3.4.1.4. Full-Scale Example.\u003c\/p\u003e \u003cp\u003e3.4.2. Instrumentation and Detection of Runaways.\u003c\/p\u003e \u003cp\u003e3.4.2.1. Methods of On-Line Detection.\u003c\/p\u003e \u003cp\u003e3.4.2.2. Methods of Noise Suppression.\u003c\/p\u003e \u003cp\u003e3.4.3. Mitigation Measures.\u003c\/p\u003e \u003cp\u003e3.4.3.1. Reaction Quenching Methods.\u003c\/p\u003e \u003cp\u003e3.4.3.2. An Example Involving a Sulfonation.\u003c\/p\u003e \u003cp\u003e3.4.3.3. Relief Disposal.\u003c\/p\u003e \u003cp\u003e3.4.3.4. Dispersion, Flaring, Scrubbing, and Containment.\u003c\/p\u003e \u003cp\u003e3.4.3.5. Venting.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eChapter 4. Management of Chemical Process Safety.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1. Hazard Identification and Quantification.\u003c\/p\u003e \u003cp\u003e4.2. Hazard Evaluation Procedures.\u003c\/p\u003e \u003cp\u003e4.3. Chemical Process Safety Management.\u003c\/p\u003e \u003cp\u003e4.4. Future Trends.\u003c\/p\u003e \u003cp\u003e\u003cb\u003eReferences.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eReferences Cited.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eSelected Additional Readings.\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eIndex.\u003c\/b\u003e\u003c\/p\u003e\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eSubject Areas: Chemistry [\u003ca title=\"See our other books on Chemistry\" href=\"https:\/\/freshlyprintedbooks.co.uk\/search?q=%22Chemistry%20%5BPN%5D%22\"\u003ePN\u003c\/a\u003e]\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\u003c\/font\u003e","brand":"Wiley-AIChE","offers":[{"title":"Brand New","offer_id":52410713506072,"sku":"9780816904792","price":107.59,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0730\/2037\/5320\/files\/9780816904792.jpg?v=1784249811","url":"https:\/\/freshlyprintedbooks.co.uk\/products\/guidelines-for-chemical-reactivity-evaluation-and-application-to-process-design-hardback-9780816904792","provider":"Freshly Printed Books","version":"1.0","type":"link"}