{"product_id":"elements-of-molecular-and-biomolecular-electrochemistry-an-electrochemical-approach-to-electron-transfer-chemistry-hardback-9781119292333","title":"Elements of Molecular and Biomolecular Electrochemistry; An Electrochemical Approach to Electron Transfer Chemistry (Hardback) 9781119292333","description":"\u003cfont face=\"Georgia\"\u003e\r\n\u003cp\u003e\u003cfont size=\"6\"\u003eElements of Molecular and Biomolecular Electrochemistry\u003c\/font\u003e\u003cbr\u003e\r\n\u003cfont size=\"5\"\u003eAn Electrochemical Approach to Electron Transfer Chemistry\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\r\n\r\n\u003cp\u003e\u003cfont size=\"4\"\u003eJean-Michel Savéant (Author), Cyrille Costentin (Author)\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e9781119292333, Wiley\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eHardback, published 12 July 2019\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e640 pages\u003cbr\u003e22.6 x 16 x 3.6 cm, 1.157 kg\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\r\n\r\n\r\n\u003cp align=\"justify\"\u003e\u003cstrong\u003e\u003cfont size=\"3\"\u003eDieses Fachbuch, geschrieben von zwei weltweit führenden Koryphäen auf dem Gebiet der Elektrochemie, beschreibt detailliert die zentralen elektrochemischen Reaktionen, die als Grundlage für die heutige Erforschung alternativer Energielösungen dienen.\u003cbr\u003e - Bietet eine zugängliche und gut lesbare Zusammenfassung zu elektrochemischen Verfahren und der Anwendung elektrochemischer Konzepte bei funktionalen Systemen auf Molekularebene.\u003cbr\u003e - Enthält ein neues Kapitel zu dem protonengekoppelten Elektronentransfer, ein vollständig überarbeitetes Kapitel zur molekularen Katalyse bei elektrochemischen Reaktionen sowie durchgängig neue Abschnitte.\u003cbr\u003e - Stellt die Verbindung zwischen der Elektrochemie, der Molekular- und Biomolekularchemie her und stärkt deren Zusammenspiel, indem eine Vielzahl von Funktionen präsentiert werden, die sich mit Multi-Komponenten-Systemen und Paradigmen aus beiden Bereichen der Chemie erreichen lassen.\u003cbr\u003e\u003c\/font\u003e\u003c\/strong\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e\u003cp\u003ePreface xv\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Single-Electron Transfer at an Electrode \u003c\/b\u003e\u003cb\u003e1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Cyclic Voltammetry of Fast Electron Transfers: Nernstian Waves 2\u003c\/p\u003e \u003cp\u003e1.2.1 One-Electron Transfer to Molecules Attached to the Electrode Surface 2\u003c\/p\u003e \u003cp\u003e1.2.2 One-Electron Transfer to Free-moving Molecules 6\u003c\/p\u003e \u003cp\u003e1.3 Technical Aspects 10\u003c\/p\u003e \u003cp\u003e1.3.1 The Cyclic Voltammetry Experiment – Faradaic and Double-Layer Charging Currents. Ohmic Drop 10\u003c\/p\u003e \u003cp\u003e1.3.2 Other Techniques. Convolution 21\u003c\/p\u003e \u003cp\u003e1.4 Electron Transfer Kinetics 29\u003c\/p\u003e \u003cp\u003e1.4.1 Introduction 29\u003c\/p\u003e \u003cp\u003e1.4.2 Butler–Volmer Law and Marcus–Hush–Levich (MHL) Model 31\u003c\/p\u003e \u003cp\u003e1.4.3 Extraction of Electron Transfer Kinetics from Cyclic Voltammetric Signals. Comparison with Other Techniques 46\u003c\/p\u003e \u003cp\u003e1.4.4 Experimental Testing of the Electron Transfer Models 59\u003c\/p\u003e \u003cp\u003e1.5 Successive One-Electron Transfers vs. Two-Electron Transfers 64\u003c\/p\u003e \u003cp\u003e1.5.1 Introduction 64\u003c\/p\u003e \u003cp\u003e1.5.2 Cyclic Voltammetric Responses: Convolution 66\u003c\/p\u003e \u003cp\u003e1.5.3 Response of Molecules Containing Identical and Independent Reducible or Oxidizable Groups 72\u003c\/p\u003e \u003cp\u003e1.5.4 An Example of the Predominating Role of Solvation: The Oxidoreduction of Carotenoids 72\u003c\/p\u003e \u003cp\u003e1.5.5 An Example of the Predominating Role of Structural Changes: The Reduction of \u003ci\u003etrans\u003c\/i\u003e-2,3-Dinitro-2-butene 75\u003c\/p\u003e \u003cp\u003eReferences 77\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Coupling of Electrode Electron Transfers with Homogeneous Chemical Reactions \u003c\/b\u003e\u003cb\u003e81\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 81\u003c\/p\u003e \u003cp\u003e2.2 Establishing the Mechanism and Measuring the Rate Constants for Homogeneous Reactions by Means of Cyclic Voltammetry and Potential Step Chronoamperometry 83\u003c\/p\u003e \u003cp\u003e2.2.1 The EC Mechanism 83\u003c\/p\u003e \u003cp\u003e2.2.2 The CE Mechanism 97\u003c\/p\u003e \u003cp\u003e2.2.3 The Square Scheme Mechanism 99\u003c\/p\u003e \u003cp\u003e2.2.4 The ECE and DISP Mechanisms 100\u003c\/p\u003e \u003cp\u003e2.2.5 Electrodimerization 107\u003c\/p\u003e \u003cp\u003e2.2.6 Homogeneous Catalytic Reaction Schemes 113\u003c\/p\u003e \u003cp\u003e2.2.6.1 Homogeneous Electron Transfer as the Rate-Determining Step 114\u003c\/p\u003e \u003cp\u003e2.2.6.2 Homogeneous Catalytic EC Mechanism 117\u003c\/p\u003e \u003cp\u003e2.2.6.3 Deactivation of the Mediator 120\u003c\/p\u003e \u003cp\u003e2.2.7 Electrodes as Catalysts: Electron-transfer Catalyzed Reactions 122\u003c\/p\u003e \u003cp\u003e2.2.8 Numerical Computations: Simulations, Diagnostic Criteria, Working Curves 125\u003c\/p\u003e \u003cp\u003e2.3 Product Distribution in Preparative Electrolysis 129\u003c\/p\u003e \u003cp\u003e2.3.1 Introduction 129\u003c\/p\u003e \u003cp\u003e2.3.2 General Features 130\u003c\/p\u003e \u003cp\u003e2.3.3 Product Distribution Resulting from Competition Between Follow-Up Reactions 133\u003c\/p\u003e \u003cp\u003e2.3.4 The ECE–DISP Competition 135\u003c\/p\u003e \u003cp\u003e2.3.5 Other Reactions Schemes 136\u003c\/p\u003e \u003cp\u003e2.4 Classification and Examples of Electron-Transfer Coupled Chemical Reactions 137\u003c\/p\u003e \u003cp\u003e2.4.1 Coupling of Single Electron Transfer with Acid–Base Reactions 137\u003c\/p\u003e \u003cp\u003e2.4.2 Electrodimerization 146\u003c\/p\u003e \u003cp\u003e2.4.3 Electropolymerization 150\u003c\/p\u003e \u003cp\u003e2.4.4 Reduction of Carbon Dioxide 151\u003c\/p\u003e \u003cp\u003e2.4.5 H-Atom Transfer vs. Electron + Proton Transfer 153\u003c\/p\u003e \u003cp\u003e2.4.6 The S\u003csub\u003eRN\u003c\/sub\u003e1 Substitution: Electrodes and Electrons as Catalysts 157\u003c\/p\u003e \u003cp\u003e2.4.7 Conformational Changes, Isomerization and Electron Transfer 162\u003c\/p\u003e \u003cp\u003e2.5 Redox Properties of Transient Radicals 167\u003c\/p\u003e \u003cp\u003e2.5.1 Introduction 167\u003c\/p\u003e \u003cp\u003e2.5.2 The Direct Electrochemical Approach 167\u003c\/p\u003e \u003cp\u003e2.5.3 Laser Flash Electron Injection 172\u003c\/p\u003e \u003cp\u003e2.5.4 Photomodulation Voltammetry 176\u003c\/p\u003e \u003cp\u003e2.6 Electrochemistry as a Trigger for Radical Chemistry or for Ionic Chemistry 177\u003c\/p\u003e \u003cp\u003eReferences 179\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Coupling Between Electron Transfer and Heavy Atom-Bond Breaking and Formation \u003c\/b\u003e\u003cb\u003e183\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 183\u003c\/p\u003e \u003cp\u003e3.2 Dissociative Electron Transfer 185\u003c\/p\u003e \u003cp\u003e3.2.1 Thermodynamics: Microscopic Reversibility 185\u003c\/p\u003e \u003cp\u003e3.2.2 The Morse Curve Model 188\u003c\/p\u003e \u003cp\u003e3.2.3 Values of the Symmetry Factor and Variation with the Driving Force 193\u003c\/p\u003e \u003cp\u003e3.2.4 Entropy of Activation 195\u003c\/p\u003e \u003cp\u003e3.3 Interactions Between Fragments in the Product Cluster 196\u003c\/p\u003e \u003cp\u003e3.3.1 Influence on the Dynamics of Dissociative Electron Transfers 197\u003c\/p\u003e \u003cp\u003e3.3.2 A Typical Example: Dissociative Electron Transfer to Carbon Tetrachloride 198\u003c\/p\u003e \u003cp\u003e3.3.3 Stabilities of Ion-radical Adducts as a Function of the Solvent 201\u003c\/p\u003e \u003cp\u003e3.3.4 Dependency of In-cage Ion-radical Interactions on the Leaving Group 203\u003c\/p\u003e \u003cp\u003e3.4 Stepwise vs. Concerted Mechanisms 205\u003c\/p\u003e \u003cp\u003e3.4.1 Introduction 205\u003c\/p\u003e \u003cp\u003e3.4.2 Diagnostic Criteria 206\u003c\/p\u003e \u003cp\u003e3.4.3 How Molecular Structure Controls the Mechanism? 208\u003c\/p\u003e \u003cp\u003e3.4.4 Passage from One Mechanism to the Other Upon Changing the Driving Force 212\u003c\/p\u003e \u003cp\u003e3.4.5 Photoinduced vs. Thermal Processes 217\u003c\/p\u003e \u003cp\u003e3.4.6 Does Concerted Mechanism Mean that the Intermediate “Does Not Exist”? 219\u003c\/p\u003e \u003cp\u003e3.4.7 π and ? Ion Radicals: Competition Between Reaction Pathways 220\u003c\/p\u003e \u003cp\u003e3.5 Cleavage of Ion Radicals: Reaction of Radicals with Nucleophiles 221\u003c\/p\u003e \u003cp\u003e3.5.1 Introduction 221\u003c\/p\u003e \u003cp\u003e3.5.2 Heterolytic Cleavages: Coupling of Radicals with Nucleophiles 222\u003c\/p\u003e \u003cp\u003e3.5.3 Homolytic Cleavages 230\u003c\/p\u003e \u003cp\u003e3.6 Role of Solvent in Ion Radical Cleavage and in Stepwise vs. Concerted Competitions 235\u003c\/p\u003e \u003cp\u003e3.6.1 Introduction 235\u003c\/p\u003e \u003cp\u003e3.6.2 Experimental Clues 236\u003c\/p\u003e \u003cp\u003e3.6.3 A Simplified Model System 241\u003c\/p\u003e \u003cp\u003e3.7 Dichotomy and Connections Between S\u003csub\u003eN\u003c\/sub\u003e2 Reactions and Dissociative Electron Transfers 246\u003c\/p\u003e \u003cp\u003e3.7.1 Introduction 246\u003c\/p\u003e \u003cp\u003e3.7.2 Experimental Approaches 247\u003c\/p\u003e \u003cp\u003e3.7.3 Theoretical Aspects 251\u003c\/p\u003e \u003cp\u003eReferences 255\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Proton-Coupled Electron Transfers \u003c\/b\u003e\u003cb\u003e259\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 259\u003c\/p\u003e \u003cp\u003e4.2 Fundamentals 260\u003c\/p\u003e \u003cp\u003e4.2.1 Concerted and Stepwise Pathways in Proton-Coupled Electron Transfer Reactions 260\u003c\/p\u003e \u003cp\u003e4.2.2 Thermal (Electrochemical and Homogeneous) and Photoinduced Reactions 262\u003c\/p\u003e \u003cp\u003e4.2.3 Modeling Concerted Proton Electron Transfers 264\u003c\/p\u003e \u003cp\u003e4.3 Examples 268\u003c\/p\u003e \u003cp\u003e4.3.1 PCET in Hydrogen Bounded Systems: H-bond Relays 268\u003c\/p\u003e \u003cp\u003e4.3.2 PCET in Water 271\u003c\/p\u003e \u003cp\u003e4.4 Breaking Bonds with Protons and Electrons 279\u003c\/p\u003e \u003cp\u003eReferences 283\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Molecular Catalysis of Electrochemical Reactions \u003c\/b\u003e\u003cb\u003e285\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 285\u003c\/p\u003e \u003cp\u003e5.2 Homogeneous Molecular Catalysis 287\u003c\/p\u003e \u003cp\u003e5.2.1 Contrasting Redox and Chemical Catalysis 287\u003c\/p\u003e \u003cp\u003e5.2.2 Applications of Homogeneous Redox Catalysis to the Characterization of Short-Lived Intermediates 288\u003c\/p\u003e \u003cp\u003e5.2.2.1 Principle and Achievements of the Method 288\u003c\/p\u003e \u003cp\u003e5.2.2.2 Comparison with Fast Cyclic Voltammetry and Laser Flash Photolysis 291\u003c\/p\u003e \u003cp\u003e5.2.2.3 Determination of the Standard Potential for the Formation of Very Unstable Primary Intermediates 293\u003c\/p\u003e \u003cp\u003e5.2.2.4 Redox Catalysis of Electrocatalytic Processes 294\u003c\/p\u003e \u003cp\u003e5.2.3 Overpotential, Turnover Frequency, Catalysts’ Benchmarking, Catalytic Tafel Plots, Maximal Turnover Number 296\u003c\/p\u003e \u003cp\u003e5.2.4 Inhibition by Intermediates and Other Secondary Phenomena. Remedies 299\u003c\/p\u003e \u003cp\u003e5.2.5 Multi-Electron Multistep Mechanisms 301\u003c\/p\u003e \u003cp\u003e5.2.6 Competition Between Heterolytic and Homolytic Catalytic Mechanisms 319\u003c\/p\u003e \u003cp\u003e5.2.7 Intelligent Design of Molecular Catalysts 325\u003c\/p\u003e \u003cp\u003e5.2.7.1 Redox vs. Chemical Catalysis: The Reduction of Vicinal Dibromides. Rates and Stereoselectivity 325\u003c\/p\u003e \u003cp\u003e5.2.7.2 Correlation Between Catalysis Kinetics and Thermodynamics: The “Iron Law” Restraining Through-Structure Substituent Effect Within a Catalyst Family 326\u003c\/p\u003e \u003cp\u003e5.2.7.3 Escaping the “Iron Law”: Through-Space Substituent Effects 329\u003c\/p\u003e \u003cp\u003e5.3 Supported Molecular Catalysis (Immobilized Catalysts) 332\u003c\/p\u003e \u003cp\u003e5.3.1 Redox and Chemical Catalysis at Monolayer and Multilayer-Coated Electrodes 332\u003c\/p\u003e \u003cp\u003e5.3.2 Catalysis at Monolayer-Coated Electrodes 333\u003c\/p\u003e \u003cp\u003e5.3.3 Permeation Through Electrode Coatings. Inhibition 342\u003c\/p\u003e \u003cp\u003e5.3.4 Electron Hopping Conduction in Assemblies of Redox Centers 349\u003c\/p\u003e \u003cp\u003e5.3.5 Ohmic Conduction in Mesoporous Electrodes 352\u003c\/p\u003e \u003cp\u003e5.3.6 Catalysis at Multilayer-Coated Electrodes 356\u003c\/p\u003e \u003cp\u003e5.3.7 Combining an Electron-shuttling Mediator with a Chemical Catalyst in a Multilayer Electrode Coating 374\u003c\/p\u003e \u003cp\u003eReferences 379\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Enzymatic Catalysis of Electrochemical Reactions \u003c\/b\u003e\u003cb\u003e383\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 383\u003c\/p\u003e \u003cp\u003e6.2 Homogenous Enzymatic Catalysis 384\u003c\/p\u003e \u003cp\u003e6.2.1 Introduction 384\u003c\/p\u003e \u003cp\u003e6.2.2 The “Ping-Pong” Mechanism. Kinetic Control by Substrate and\/or Cosubstrate 385\u003c\/p\u003e \u003cp\u003e6.2.3 A Model Example: Glucose Oxidase with Excess Glucose 392\u003c\/p\u003e \u003cp\u003e6.2.4 Molecular Recognition of an Enzyme by Artificial One-Electron Cosubstrates 394\u003c\/p\u003e \u003cp\u003e6.2.5 Deciphering a Complex Electroenzymatic Response: Horseradish Peroxidase 398\u003c\/p\u003e \u003cp\u003e6.3 Immobilized Enzymes in Monomolecular Layers 402\u003c\/p\u003e \u003cp\u003e6.3.1 Introduction 402\u003c\/p\u003e \u003cp\u003e6.3.2 The “Ping-Pong” Mechanism with an Immobilized Enzyme and the Cosubstrate in Solution 402\u003c\/p\u003e \u003cp\u003e6.3.3 Antigen–Antibody Immobilization of Glucose Oxidase: Kinetic Analysis 411\u003c\/p\u003e \u003cp\u003e6.3.4 Application to the Kinetic Characterization of Biomolecular Recognition 413\u003c\/p\u003e \u003cp\u003e6.3.5 Immobilized Horseradish Peroxidase 420\u003c\/p\u003e \u003cp\u003e6.3.6 Immobilization of Both the Enzyme and the Cosubstrate: Electron Transfer and Electron Transport in Integrated Systems 425\u003c\/p\u003e \u003cp\u003e6.4 Spatially Ordered Multi-monomolecular Layered Enzyme Coatings 430\u003c\/p\u003e \u003cp\u003e6.4.1 Step-by-Step Antigen–Antibody Construction of Multi-monomolecular Layer Enzyme Coatings 430\u003c\/p\u003e \u003cp\u003e6.4.2 Reaction Dynamics with the Cosubstrate in Solution: Evidence for Spatial Order 432\u003c\/p\u003e \u003cp\u003eReferences 436\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Appendices \u003c\/b\u003e\u003cb\u003e439\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Single-Electron Transfer at an Electrode 439\u003c\/p\u003e \u003cp\u003e7.1.1 Laplace Transformation: Useful Definitions and Relationships 439\u003c\/p\u003e \u003cp\u003e7.1.2 Cyclic Voltammetry of Nernstian Systems: Current– and Charge–Potential Curves 439\u003c\/p\u003e \u003cp\u003e7.1.3 Double-Layer Charging in Cyclic Voltammetry: Oscillating and Nonoscillating Behaviors 446\u003c\/p\u003e \u003cp\u003e7.1.4 Effect of Ohmic Drop and Double-Layer Charging on Nernstian Cyclic Voltammograms 448\u003c\/p\u003e \u003cp\u003e7.1.5 Potential Step and Double Potential Step Chronoamperometry of Nernstian Systems 451\u003c\/p\u003e \u003cp\u003e7.1.6 Overlapping of Double-Layer Charging and Faradaic Currents in Potential Step and Double Potential Step Chronoamperometry. Oscillating and Nonoscillating Behaviors 453\u003c\/p\u003e \u003cp\u003e7.1.7 Solvent Reorganization in Marcus–Hush–Levich Model 455\u003c\/p\u003e \u003cp\u003e7.1.8 Effect of the Multiplicity of Electronic States in the Electrode 460\u003c\/p\u003e \u003cp\u003e7.1.9 Cyclic Voltammetry of Two-Electron Nernstian Systems. Disproportionation 463\u003c\/p\u003e \u003cp\u003e7.2 Coupling of Homogeneous Chemical Reactions with Electron Transfer 465\u003c\/p\u003e \u003cp\u003e7.2.1 The EC Mechanism 465\u003c\/p\u003e \u003cp\u003e7.2.2 The CE Mechanism 471\u003c\/p\u003e \u003cp\u003e7.2.3 Double Potential Step Responses for Processes Involving First- or Second-Order Follow-Up Reactions 474\u003c\/p\u003e \u003cp\u003e7.2.4 The ECE and DISP Mechanisms 475\u003c\/p\u003e \u003cp\u003e7.2.5 Electrodimerization 483\u003c\/p\u003e \u003cp\u003e7.2.6 Competition Between Dimerization of and Electron Transfer to Intermediates 490\u003c\/p\u003e \u003cp\u003e7.2.7 Homogeneous Catalysis 495\u003c\/p\u003e \u003cp\u003e7.2.7.1 Homogeneous Electron Transfer as the Rate-Determining Step 495\u003c\/p\u003e \u003cp\u003e7.2.7.2 Homogeneous Catalytic EC Mechanism 499\u003c\/p\u003e \u003cp\u003e7.2.7.3 Deactivation of the Mediator 500\u003c\/p\u003e \u003cp\u003e7.2.8 Product Distribution in Preparative Electrolysis 502\u003c\/p\u003e \u003cp\u003e7.3 Electron Transfer, Bond Breaking, and Bond Formation 525\u003c\/p\u003e \u003cp\u003e7.3.1 Contribution of the Cleaving Bond Stretching to Internal Reorganization of the First Step of the Stepwise Mechanism 525\u003c\/p\u003e \u003cp\u003e7.3.2 Morse Curve Model of Intramolecular Dissociative Electron Transfer 526\u003c\/p\u003e \u003cp\u003e7.4 Proton-Coupled Electron Transfers 528\u003c\/p\u003e \u003cp\u003e7.4.1 Rate Law for Electrochemical CPET 528\u003c\/p\u003e \u003cp\u003e7.4.2 Current–Potential Relationship for PCET in Water 533\u003c\/p\u003e \u003cp\u003e7.4.3 Competition Between Dimerization and CPET Kinetics 538\u003c\/p\u003e \u003cp\u003e7.5 Analysis of Supported Molecular Catalysis by Rotating Disk Electrode Voltammetry and Cyclic Voltammetry 541\u003c\/p\u003e \u003cp\u003e7.5.1 Catalysis at Monolayer Electrode Coatings 541\u003c\/p\u003e \u003cp\u003e7.5.2 Inhibition of Electron Transfer at Partially Blocked Electrodes 544\u003c\/p\u003e \u003cp\u003e7.5.3 Equivalent Diffusion and Migration Laws for Electron Hopping Between Fixed Sites 545\u003c\/p\u003e \u003cp\u003e7.5.4 Ohmic Conduction in Mesoporous Electrodes 547\u003c\/p\u003e \u003cp\u003e7.5.5 Catalysis at Multilayered Electrode Coatings: RDVE 556\u003c\/p\u003e \u003cp\u003e7.5.6 Ohmic Transport in Electrocatalytic Film 562\u003c\/p\u003e \u003cp\u003e7.5.6.1 Governing Equations 562\u003c\/p\u003e \u003cp\u003e7.5.6.2 Dimensionless Formulation 563\u003c\/p\u003e \u003cp\u003e7.5.6.3 Semianalytical Resolution 564\u003c\/p\u003e \u003cp\u003e7.5.6.4 Asymptotes of the Catalytic Tafel Plots for \u003ci\u003e\u003cb\u003eE \u003c\/b\u003e\u003c\/i\u003e→ ±∞ 567\u003c\/p\u003e \u003cp\u003e7.5.7 Catalysis at Multilayered Electrode Coatings: Cyclic Voltammetry 568\u003c\/p\u003e \u003cp\u003e7.5.7.1 Formulation 568\u003c\/p\u003e \u003cp\u003e7.5.7.2 Resolution in the Absence of Substrate Consumption 569\u003c\/p\u003e \u003cp\u003e7.5.7.3 Resolution in Pure Kinetics Conditions (Fast Kinetics) with Possible Substrate Consumption 571\u003c\/p\u003e \u003cp\u003e7.5.7.4 Resolution in Fast-conducting Conditions with Possible Substrate Consumption 577\u003c\/p\u003e \u003cp\u003e7.6 Enzymatic Catalysis Responses 580\u003c\/p\u003e \u003cp\u003e7.6.1 The “Ping-Pong” Mechanism in Homogeneous Enzymatic Catalysis 580\u003c\/p\u003e \u003cp\u003e7.6.2 Catalysis and Inhibition in Homogeneous Systems 585\u003c\/p\u003e \u003cp\u003e7.6.2.1 Derivation of Eq. (6.10) 585\u003c\/p\u003e \u003cp\u003e7.6.2.2 Control by Substrate Diffusion 589\u003c\/p\u003e \u003cp\u003e7.6.3 Catalysis at Multilayered Electrode Coatings 591\u003c\/p\u003e \u003cp\u003eReferences 597\u003c\/p\u003e \u003cp\u003eGlossary of Symbols 599\u003c\/p\u003e \u003cp\u003eIndex 611\u003c\/p\u003e\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eSubject Areas: Chemistry [\u003ca title=\"See our other books on Chemistry\" href=\"https:\/\/freshlyprintedbooks.co.uk\/search?q=%22Chemistry%20%5BPN%5D%22\"\u003ePN\u003c\/a\u003e]\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\u003c\/font\u003e","brand":"Wiley","offers":[{"title":"Brand New","offer_id":52501428502808,"sku":"9781119292333","price":126.49,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0730\/2037\/5320\/files\/9781119292333.jpg?v=1786237926","url":"https:\/\/freshlyprintedbooks.co.uk\/products\/elements-of-molecular-and-biomolecular-electrochemistry-an-electrochemical-approach-to-electron-transfer-chemistry-hardback-9781119292333","provider":"Freshly Printed Books","version":"1.0","type":"link"}