{"product_id":"adsorbents-fundamentals-and-applications-hardback-9780471297413","title":"Adsorbents; Fundamentals and Applications (Hardback) 9780471297413","description":"\u003cfont face=\"Georgia\"\u003e\r\n\u003cp\u003e\u003cfont size=\"6\"\u003eAdsorbents\u003c\/font\u003e\u003cbr\u003e\r\n\u003cfont size=\"5\"\u003eFundamentals and Applications\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\r\n\r\n\u003cp\u003e\u003cfont size=\"4\"\u003eRalph T. Yang (Author)\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e9780471297413, Wiley\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eHardback, published 20 May 2003\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e424 pages\u003cbr\u003e24.6 x 16.1 x 2.5 cm, 0.688 kg\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\r\n\u003cp align=\"justify\"\u003e\u003cem\u003e\u003cfont size=\"3\"\u003e\"…a very good book on a very important topic. Well-written, resplendent with figures and tables, and well-referenced are some of my observations.\" (\u003ci\u003eJournal of Hazardous Materials\u003c\/i\u003e, 109, 2004)  \u003cp\u003e\"...fulfils existing demand for a simple and comprehensive text devoted to commercial and novel adsorbents...a valuable guide...\" (\u003ci\u003eJournal of the American Chemical Society\u003c\/i\u003e, Vol. 125, No. 39, 2003)\u003c\/p\u003e\u003c\/font\u003e\u003c\/em\u003e\u003c\/p\u003e\r\n\r\n\u003cp align=\"justify\"\u003e\u003cstrong\u003e\u003cfont size=\"3\"\u003eDieses Buch bespricht die Grundprinzipien des zweckgerichteten Designs, der Herstellung und des Einsatzes adsorbierender Materialien zur Stofftrennung und Stoffreinigung.\u003cbr\u003e - Themenspektrum reicht von Grundlagen (Beschreibung der Adsorptionskräfte) bis zu modernsten Materialien (Nanoröhren, p-Komplexbildner)\u003cbr\u003e - zeigt, wie Rechenmethoden und Molekülsimulation in den Designprozess eingebunden werden\u003cbr\u003e - spricht auch innovative Anwendungsfelder an, etwa die Entschwefelung von Dieseltreibstoff\u003c\/font\u003e\u003c\/strong\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003e\u003cp\u003ePreface xi\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Introductory Remarks 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1. Equilibrium Separation and Kinetic Separation 2\u003c\/p\u003e \u003cp\u003e1.2. Commercial Sorbents and Applications 3\u003c\/p\u003e \u003cp\u003e1.3. New Sorbents and Future Applications 6\u003c\/p\u003e \u003cp\u003eReferences 7\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Fundamental Factors for Designing Adsorbent 8\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1. Potential Energies for Adsorption 8\u003c\/p\u003e \u003cp\u003e2.2. Heat of Adsorption 10\u003c\/p\u003e \u003cp\u003e2.3. Effects of Adsorbate Properties on Adsorption: Polarizability (α), Dipole Moment (μ), and  Quadrupole Moment (Q) 11\u003c\/p\u003e \u003cp\u003e2.4. Basic Considerations for Sorbent Design 12\u003c\/p\u003e \u003cp\u003e2.4.1. Polarizability (α), Electronic Charge (q), and van der Waals Radius (r) 12\u003c\/p\u003e \u003cp\u003e2.4.2. Pore Size and Geometry 13\u003c\/p\u003e \u003cp\u003eReferences 16\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Sorbent Selection: Equilibrium Isotherms, Diffusion, Cyclic Processes, and Sorbent Selection Criteria \u003c\/b\u003e\u003cb\u003e17\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1. Equilibrium Isotherms and Diffusion 18\u003c\/p\u003e \u003cp\u003e3.1.1. Langmuir Isotherms for Single and Mixed Gases 18\u003c\/p\u003e \u003cp\u003e3.1.2. Potential Theory Isotherms for Single and Mixed Gases 20\u003c\/p\u003e \u003cp\u003e3.1.3. Ideal Adsorbed Solution Theory for Mixture and Similarities with Langmuir and Potential Theories 22\u003c\/p\u003e \u003cp\u003e3.1.4. Diffusion in Micropores: Concentration Dependence and Predicting Mixed Diffusivities 23\u003c\/p\u003e \u003cp\u003e3.2. Temperature Swing Adsorption and Pressure Swing Adsorption 27\u003c\/p\u003e \u003cp\u003e3.2.1. Temperature Swing Adsorption 28\u003c\/p\u003e \u003cp\u003e3.2.2. Pressure Swing Adsorption 30\u003c\/p\u003e \u003cp\u003e3.3. Simple Criteria for Sorbent Selection 40\u003c\/p\u003e \u003cp\u003eReferences 49\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Pore Size Distribution 54\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1. The Kelvin Equation 54\u003c\/p\u003e \u003cp\u003e4.2. Horv´ath–Kawazoe Approach 55\u003c\/p\u003e \u003cp\u003e4.2.1. The Original HK Slit-Shaped Pore Model 57\u003c\/p\u003e \u003cp\u003e4.2.2. Modified HK Model for Slit-Shaped Pores 60\u003c\/p\u003e \u003cp\u003e4.2.3. Modified Model for Cylindrical Pores 68\u003c\/p\u003e \u003cp\u003e4.3. The Integral Equation Approach 74\u003c\/p\u003e \u003cp\u003eReferences 76\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Activated Carbon 79\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1. Formation and Manufacture of Activated Carbon 79\u003c\/p\u003e \u003cp\u003e5.2. Pore Structure and Standard Tests for Activated Carbon 82\u003c\/p\u003e \u003cp\u003e5.3. General Adsorption Properties 84\u003c\/p\u003e \u003cp\u003e5.4. Surface Chemistry and Its Effects on Adsorption 86\u003c\/p\u003e \u003cp\u003e5.4.1. Effects of Surface Functionalities on Gas Adsorption 89\u003c\/p\u003e \u003cp\u003e5.5. Adsorption from Solution and Effects of Surface Functionalities 92\u003c\/p\u003e \u003cp\u003e5.5.1. Adsorption from Dilute Solution (Particularly Phenols) 93\u003c\/p\u003e \u003cp\u003e5.5.2. Effects of Surface Functionalities on Adsorption 99\u003c\/p\u003e \u003cp\u003e5.6. Activated Carbon Fibers 104\u003c\/p\u003e \u003cp\u003e5.6.1. Adsorption Isotherms 109\u003c\/p\u003e \u003cp\u003e5.7. Carbon Molecular Sieves 109\u003c\/p\u003e \u003cp\u003e5.7.1. Carbon Deposition Step 114\u003c\/p\u003e \u003cp\u003e5.7.2. Kinetic Separation: Isotherms and Diffusivities 115\u003c\/p\u003e \u003cp\u003e5.7.3. Carbon Molecular Sieve Membranes 117\u003c\/p\u003e \u003cp\u003eReferences 123\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Silica Gel, MCM, and Activated Alumina 131\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1. Silica Gels: Preparation and General Properties 131\u003c\/p\u003e \u003cp\u003e6.2. Surface Chemistry of Silicas: The Silanol Groups 134\u003c\/p\u003e \u003cp\u003e6.3. The Silanol Number (OHnm−1) 135\u003c\/p\u003e \u003cp\u003e6.4. MCM-41 139\u003c\/p\u003e \u003cp\u003e6.5. Chemical Modification of Silicas and Molecular Imprinting 141\u003c\/p\u003e \u003cp\u003e6.6. Activated Alumina 146\u003c\/p\u003e \u003cp\u003e6.7. Activated Alumina as Special Sorbents 150\u003c\/p\u003e \u003cp\u003eReferences 154\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Zeolites and Molecular Sieves 157\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1. Zeolite Types A, X, and Y 158\u003c\/p\u003e \u003cp\u003e7.1.1. Structure and Cation Sites of Type A Zeolite 158\u003c\/p\u003e \u003cp\u003e7.1.2. Structure and Cation Sites of Types X and Y Zeolites 160\u003c\/p\u003e \u003cp\u003e7.1.3. Examples of Molecular Sieving 161\u003c\/p\u003e \u003cp\u003e7.2. Zeolites and Molecular Sieves: Synthesis and Molecular Sieving Properties 164\u003c\/p\u003e \u003cp\u003e7.2.1. Synthesis of Zeolites A, X, and Y 164\u003c\/p\u003e \u003cp\u003e7.2.2. Organic Additives (Templates) in Synthesis of Zeolites and Molecular Sieves 165\u003c\/p\u003e \u003cp\u003e7.3. Unique Adsorption Properties: Anionic Oxygens and Isolated Cations 173\u003c\/p\u003e \u003cp\u003e7.4. Interactions of Adsorbate with Cations: Effects of Cation Site, Charge, and Ionic Radius 175\u003c\/p\u003e \u003cp\u003e7.4.1. Cation Sites 175\u003c\/p\u003e \u003cp\u003e7.4.2. Effects of Cation Sites on Adsorption 180\u003c\/p\u003e \u003cp\u003e7.4.3. Effects of Cation Charge and Ionic Radius 183\u003c\/p\u003e \u003cp\u003eReferences 187\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 π-Complexation Sorbents and Applications 191\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1. Preparation of Three Types of Sorbents 192\u003c\/p\u003e \u003cp\u003e8.1.1. Supported Monolayer Salts 193\u003c\/p\u003e \u003cp\u003e8.1.2. Ion-Exchanged Zeolites 197\u003c\/p\u003e \u003cp\u003e8.1.3. Ion-Exchanged Resins 201\u003c\/p\u003e \u003cp\u003e8.2. Molecular Orbital Theory Calculations 202\u003c\/p\u003e \u003cp\u003e8.2.1. Molecular Orbital Theory—Electronic Structure Methods 202\u003c\/p\u003e \u003cp\u003e8.2.2. Semi-Empirical Methods 203\u003c\/p\u003e \u003cp\u003e8.2.3. Density Functional Theory Methods 203\u003c\/p\u003e \u003cp\u003e8.2.4. Ab Initio Methods 204\u003c\/p\u003e \u003cp\u003e8.2.5. Basis Set 205\u003c\/p\u003e \u003cp\u003e8.2.6. Effective Core Potentials 205\u003c\/p\u003e \u003cp\u003e8.2.7. Model Chemistry and Molecular Systems 206\u003c\/p\u003e \u003cp\u003e8.2.8. Natural Bond Orbital 207\u003c\/p\u003e \u003cp\u003e8.2.9. Adsorption Bond Energy Calculation 208\u003c\/p\u003e \u003cp\u003e8.3. Nature of π-Complexation Bonding 208\u003c\/p\u003e \u003cp\u003e8.3.1. Understanding π-Complexation Bond through Molecular Orbital Theory 209\u003c\/p\u003e \u003cp\u003e8.3.2. π-Complexation Bonds with Different Cations 212\u003c\/p\u003e \u003cp\u003e8.3.3. Effects of Different Anions and Substrates 213\u003c\/p\u003e \u003cp\u003e8.4. Bulk Separations by π-Complexation 216\u003c\/p\u003e \u003cp\u003e8.4.1. Deactivation of π-Complexation Sorbents 216\u003c\/p\u003e \u003cp\u003e8.4.2. CO Separation by π-Complexation 216\u003c\/p\u003e \u003cp\u003e8.4.3. OlefinParaffin Separations 219\u003c\/p\u003e \u003cp\u003e8.4.4. AromaticsAliphatics Separation 220\u003c\/p\u003e \u003cp\u003e8.4.5. Possible Sorbents for Simulated Moving-Bed Applications 222\u003c\/p\u003e \u003cp\u003e8.5. Purification by π-Complexation 223\u003c\/p\u003e \u003cp\u003e8.5.1. Removal of Dienes from Olefins 224\u003c\/p\u003e \u003cp\u003e8.5.2. Removal of Aromatics from Aliphatics 226\u003c\/p\u003e \u003cp\u003eReferences 227\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Carbon Nanotubes, Pillared Clays, and Polymeric Resins 231\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e9.1. Carbon Nanotubes 231\u003c\/p\u003e \u003cp\u003e9.1.1. Catalytic Decomposition 233\u003c\/p\u003e \u003cp\u003e9.1.2. Arc Discharge and Laser Vaporization 241\u003c\/p\u003e \u003cp\u003e9.1.3. Adsorption Properties of Carbon Nanotubes 243\u003c\/p\u003e \u003cp\u003e9.2. Pillared Clays 253\u003c\/p\u003e \u003cp\u003e9.2.1. Syntheses of PILCs 253\u003c\/p\u003e \u003cp\u003e9.2.2. Micropore Size Distribution 256\u003c\/p\u003e \u003cp\u003e9.2.3. Cation Exchange Capacity 258\u003c\/p\u003e \u003cp\u003e9.2.4. Adsorption Properties 260\u003c\/p\u003e \u003cp\u003e9.2.5. PILC and Acid-Treated Clay as Supports 262\u003c\/p\u003e \u003cp\u003e9.3. Polymeric Resins 264\u003c\/p\u003e \u003cp\u003e9.3.1. Pore Structure, Surface Properties, and Applications 266\u003c\/p\u003e \u003cp\u003e9.3.2. Comparisons of Resins and Activated Carbon 269\u003c\/p\u003e \u003cp\u003e9.3.3. Mechanism of Sorption and Gas-Phase Applications 271\u003c\/p\u003e \u003cp\u003eReferences 273\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Sorbents for Applications 280\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e10.1. Air Separation 280\u003c\/p\u003e \u003cp\u003e10.1.1. 5A and 13X Zeolites 282\u003c\/p\u003e \u003cp\u003e10.1.2. Li-LSX Zeolite 283\u003c\/p\u003e \u003cp\u003e10.1.3. Type X Zeolite with Alkaline Earth Ions 288\u003c\/p\u003e \u003cp\u003e10.1.4. LSX Zeolite Containing Ag (AgLiLSX) 289\u003c\/p\u003e \u003cp\u003e10.1.5. Oxygen-Selective Sorbents 296\u003c\/p\u003e \u003cp\u003e10.2. Hydrogen Purification 303\u003c\/p\u003e \u003cp\u003e10.3. Hydrogen Storage 305\u003c\/p\u003e \u003cp\u003e10.3.1. Metal Hydrides 306\u003c\/p\u003e \u003cp\u003e10.3.2. Carbon Nanotubes 308\u003c\/p\u003e \u003cp\u003e10.4. Methane Storage 321\u003c\/p\u003e \u003cp\u003e10.5. OlefinParaffin Separations 326\u003c\/p\u003e \u003cp\u003e10.5.1. Sorbents 326\u003c\/p\u003e \u003cp\u003e10.5.2. PSA Separations 328\u003c\/p\u003e \u003cp\u003e10.5.3. Other Sorbents 334\u003c\/p\u003e \u003cp\u003e10.6. NitrogenMethane Separation 334\u003c\/p\u003e \u003cp\u003e10.6.1. Clinoptilolites 336\u003c\/p\u003e \u003cp\u003e10.6.2. ETS-4 341\u003c\/p\u003e \u003cp\u003e10.6.3. PSA Simulation: Comparison of Sorbents 344\u003c\/p\u003e \u003cp\u003e10.7. Desulfurization of Transportation Fuels 344\u003c\/p\u003e \u003cp\u003e10.7.1. Fuel and Sulfur Compositions 347\u003c\/p\u003e \u003cp\u003e10.7.2. Sorbents Studied or Used 349\u003c\/p\u003e \u003cp\u003e10.7.3. π-Complexation Sorbent 350\u003c\/p\u003e \u003cp\u003e10.8. Removal of Aromatics from Fuels 361\u003c\/p\u003e \u003cp\u003e10.9. NOx Removal 363\u003c\/p\u003e \u003cp\u003eReferences 371\u003c\/p\u003e \u003cp\u003eAuthor Index 383\u003c\/p\u003e \u003cp\u003eSubject Index 403\u003c\/p\u003e\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\u003cp\u003e\u003cfont size=\"3\"\u003eSubject Areas: Chemistry [\u003ca title=\"See our other books on Chemistry\" href=\"https:\/\/freshlyprintedbooks.co.uk\/search?q=%22Chemistry%20%5BPN%5D%22\"\u003ePN\u003c\/a\u003e]\u003c\/font\u003e\u003c\/p\u003e\r\n\r\n\r\n\u003c\/font\u003e","brand":"Wiley-Interscience","offers":[{"title":"Brand New","offer_id":52286432968984,"sku":"9780471297413","price":109.77,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0730\/2037\/5320\/files\/9780471297413.jpg?v=1781551610","url":"https:\/\/freshlyprintedbooks.co.uk\/products\/adsorbents-fundamentals-and-applications-hardback-9780471297413","provider":"Freshly Printed Books","version":"1.0","type":"link"}